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Adsorption
Erschienen in: Adsorption 1-2/2015

01.02.2015

Chromium-based metal–organic framework/mesoporous carbon composite: synthesis, characterization and CO2 adsorption

verfasst von: Zhongzheng Zhang, Hui Wang, Xinqing Chen, Chenming Zhu, Wei Wei, Yuhan Sun

Erschienen in: Adsorption | Ausgabe 1-2/2015

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Abstract

New composites of a water-stable chromium-based metal organic framework MIL-101 and mesoporous carbon CMK-3 were in situ synthesized with different ratios of MIL-101 and CMK-3 using the hydrothermal method. The composites as well as the parent materials were characterized by X-ray diffraction, thermo gravimetric analysis, scanning electron microscope, transmission electron microscope and nitrogen/carbon dioxide adsorption isotherms. The hybrid material possesses the same crystal structure and morphology as its parent MIL-101, and exhibits an enhancement in CO2 adsorption uptakes when compared to MIL-101 and CMK-3. The increase in CO2 uptakes was attributed to the combined effect of the formation of additional micropores, the enhancement of micropore volume and the activation of unsaturated metal sites by CMK-3 incorporation.
Vorheriger Artikel Experimental and numerical study on water sorption over modified mesoporous silica
Nächster Artikel Adsorption characteristics of propan-2-ol vapours on activated carbon Sorbonorit 4 in electrothermal temperature swing adsorption process

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Literatur
Arstad, B., Fjellvag, H., Kongshaug, K.O., Swang, O., Blom, R.: Amine functionalized metal organic frameworks (MOFs) as adsorbents for carbon dioxide. Adsorption 14, 755–762 (2008)CrossRef
Buso, D., Nairn, K.M., Gimona, M., Hill, A.J., Falcaro, P.: Fast synthesis of MOF-5 microcrystals using sol-gel SiO2 nanoparticles. Chem. Mater. 23, 929–934 (2011)CrossRef
Chang, F., Chao, K., Cheng, H., Tan, C.: Adsorption of CO2 onto amine-grafted mesoprous silicas. Sep. Purif. Technol. 70, 87–95 (2009)CrossRef
Férey, G., Mellot-Draznieks, C., Serre, C., Millange, F., Dutour, J., Surblé, S., Margiolaki, I.A.: A chromium terephthalate-based solid with unusually large pore volumes and surface area. Science 309, 2040–2042 (2005)CrossRef
Furukawa, H., Ko, N., Go, Y.B., Aratani, N., Choi, S.B., Choi, E., Yazaydin, A.O., Snurr, R.Q., Keeffe, M.O., Kim, J., Yaghi, O.M.: Ultra-high porosity in metal-organic frameworks. Science 329, 424–428 (2010)CrossRef
Govindasamy, C., Won, J.S., Wha, S.A.: Synthesis of mesoporous materials SBA-15 and CMK-3 from fly ash and their application for CO2 adsorption. J. Porous Mater. 16, 545–551 (2009)CrossRef
Guo, B., Chang, L., Xiel, K.: Adsorption of carbon dioxide on activated carbon. J. Nat. Gas Chem. 15, 223–229 (2006)CrossRef
Jun, S., Joo, S.H., Ryoo, R., Kruk, M., Jaroniec, M., Liu, Z., Ohsuna, T., Terasaki, O.: Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure. J. Am. Chem. Soc. 122, 10712–10713 (2000)CrossRef
Kaye, S.S., Dailly, A., Yaghi, O.M., Long, J.R.: Impact of preparation and handing on the hydrogen storage properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5). J. Am. Chem. Soc. 129, 14176–14177 (2007)CrossRef
Krungleviciute, V., Lask, K., Heroux, L., Migone, D., Lee, J.Y., Skoulidas, A.: Argon adsorption on Cu3(benzene-1,3,5-tricarboxylate)2(H2O)3 metal-organic. Langmuir 23, 3106–3109 (2007)CrossRef
Kumar, R., Jayaramule, K., Maji, T.K., Rao, C.N.R.: Hybrid nanocomposites of ZIF-8 with grapheme oxide exhibiting tunable morphology, significant CO2 uptake and other novel properties. Chem. Commun. 49, 4947–4949 (2013)CrossRef
Li, L., Wen, X., Fu, X., Wang, F., Zhao, N., Xiao, F.K., Wei, W., Sun, Y.H.: MgO/Al2O3 sorbent for CO2 capture. Energy Fuels 24, 5773–5780 (2010)CrossRef
Li, Y., Sun, N.N., Li, L., Zhao, N., Xiao, F.K., Wei, W., Sun, Y.H., Huang, W.: Grafting of amines on ethanol-extracted SBA-15 for CO2 adsorption. Materials 6, 981–999 (2013)CrossRef
Liewellyn, P.L., Bourrelly, S., Serre, C., Vimont, A., Daturi, M., Iiamon, L.: High uptakes of CO2 and CH4 in mesoporous metal-orfanic frameworks MIL-100 and MIL-101. Langmuir 24, 7245–7250 (2008)CrossRef
Liu, Y.Y., Zeng, J.L., Zhang, J., Xu, F., Sun, L.X.: Improved hydrogen strorage in the modified metal-organic frameworks by hydrogen spillover effect. Int. J. Hydrogen Energy 32, 4005–4010 (2007)CrossRef
Liu, J., Wang, Y., Benin, A.I., Jakubczak, P., Willis, R.R., Levan, M.D.: CO2/H2O adsorption equilibrium and rates on metal-organic frameworks: HKUST-1 and Ni/DOBDC. Langmuir 26, 14301–14307 (2010)CrossRef
Liu, J., Thallapally, P.K., McGrail, B.P., Brown, D.R., Liu, J.: Process in adsorption-based CO2 capture by metal-organic frameworks. Chem. Soc. Rev. 41, 2308–2322 (2012)CrossRef
Maksimchuk, N.V., Timofeeva, M.N., Melgunov, M.S., Shmakov, A.N., Chesalov, Y.A., Dybtsev, D.N., Fedin, V.P., Kholdeeva, O.A.: Heterogeneous selective oxidation catalysts based on coordination polymer MIL-101 and transition metal-substituted polyoxometalates. J. Catal. 257, 315–323 (2008)CrossRef
Martacaltzi, C.S., Lemonidou, A.A.: Development of new CaO based sorbent materials for CO2 removal at high temperature. Microporous Mesoporous Mater. 110, 119–127 (2008)CrossRef
Millwar, A.R., Yaghi, O.M.: Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature. J. Am. Chem. Soc. 127, 17998–17999 (2005)CrossRef
Miyamoto, M., Fujiokax, Y., Yogo, K.: Pure silica CHA type zeolite for CO2 separation using pressure swing adsorption at high pressure. J. Mater. Chem. 22, 20186–20189 (2012)CrossRef
Pachfule, P., Balan, B.K., Kurungot, S., Banerjee, R.: One-dimensional confinement of a nanosized metal-organic framework in carbon nanofibers for improved gas adsorption. Chem. Comm. 48, 2009–2011 (2012)CrossRef
Petit, C., Bandosz, T.J.: MOF-graphite oxide nanocomposites: surface characteriazation and ecaluation as adsorbents of ammonia. J. Mater. Chem. 19, 6521–6528 (2009a)CrossRef
Petit, C., Bandosz, T.J.: MOF-graphite oxide composites: combing the uniqueness of grapheme layers and metal-organic frameworks. Adv. Mater. 21, 4753–4757 (2009b)
Petit, C., Bandosz, T.J.: Enhanced adsorption of ammonia on metal-organic framework/graphite oxide composites: analysis of surface interactions. Adv. Funct. Mater. 20, 111–118 (2010)CrossRef
Petit, C., Mendoza, B., Bandoza, T.: Reactive adsorption of ammonia on Cu-based MOF/grapheme composites. Langmuir 26, 15302–15309 (2010)CrossRef
Petit, C., Burress, J., Bandosz, T.J.: The synthesis and characterization of copper-based metal-organic framework/graphite oxide composites. Carbon 49, 563–572 (2011)CrossRef
Policicchio, A., Zhao, Y.X., Zhong, Q., Agostino, R.G., Bandosz, T.J.: Cu-BTC/aminated graphite oxide composites as high-efficiency CO2 capture media. ACS Appl. Mater. Interfaces 6, 101–108 (2014)CrossRef
Prasanth, K.P., Rallapalli, P., Raj, M.C., Bajaj, H.C., Jasra, R.V.: Enhanced hydrogen sorption in single walled carbon nanotube incorporated MIL-101 composite metal-organic framework. Int. J. Hydrogen Energy 36, 7594–7601 (2011)CrossRef
Rallapalli, P.B.S., Raj, M.C., Patil, D.V., Prasanth, P.K., Somani, R.S., Bajaj, H.C.: Activated carbon@MIL-101(Cr): a potential metal-organic framework composite material for hydrogen strorage. Int. J. Energy Res. 37, 746–753 (2013)CrossRef
Shao, W., Zhang, L.Z., Li, L.X., Lee, R.L.: Adsorption of CO2 and N2 on synthesized NaY zeolite at high temperatures. Adsorption 15, 497–505 (2009)CrossRef
Suddik, A.C., Cote, A.P., Wong-Foy, A.G., O’Keeffe, M., Yaghi, O.M.: A metal-organic framework with a hierarchical system of pores and tetrahedral building blocks. Angew. Chem. Int. Ed. 45, 2528–2533 (2006)CrossRef
Sun, Y., Liu, X.W., Su, W., Zhou, Y.P., Zhou, L.: Studies on ordered mesoporous materials for potential environmnental and clean energy applications. Appl. Surf. Sci. 253, 5650–5655 (2007)CrossRef
Wong, S., Bioletti, R.: Carbon dioxide separation technologies. Carbon & Energy Management, Alberta Research Council, Edmonton, Alberta, Canada (2002)
Wu, H., Simmons, J.M., Srinivas, G., Zhou, W., Yildirim, T.: Adsorption sites and binding nature of CO2 in prototypical metal-organic frameworks: a combined neutron diffraction and first-principles study. J. Phys. Chem. Lett. 1, 1946–1951 (2010)CrossRef
Wu, C.M., Rathi, M., Ahrenkiel, S.P., Koodali, R.T., Wang, Z.Q.: Facile synthesis of MOF-5 confined in SBA-15 hybrid material with enhanced hydrostability. Chem. Comm. 49, 1223–1225 (2013)CrossRef
Yang, S.J., Choi, J.Y., Chae, H.K., Cho, J.H., Nahm, K.S., Park, C.R.: Preparation and enhanced hydrostability and hydrogen storage capacity of CNT@MOF-5 hybrid composite. Chem. Mater. 21, 1893–1897 (2009)CrossRef
Yang, H., Gong, M., Chen, Y.: Preparation of activated carbons and their adsorption properties for greenhouse gases: CH4 and CO2. J. Nat. Gas Chem. 20, 460–464 (2011)CrossRef
Yazaydin, A.O., Snurr, R.Q., Park, T.H., Koh, K., Liu, J., Levan, M.D., Benin, A.I., Jakubazak, P., Lanuza, M., Galloway, D.B., Low, J.J., Willis, R.R.: Screening of metal-organic frameworks for carbon dioxide capture from flue gas using a combined experimental and modeling approach. J. Am. Chem. Soc. 131, 18198–18199 (2009)CrossRef
Zhang, Z.Z., Ruan, H.Z., Zhou, Y.P., Su, W., Sun, Y., Zhou, L.: A research note on the adsorption of CO2 and N2. Chin. J. Chem. Eng. 19, 733–737 (2011)CrossRef
Zhang, Z.Z., Tang, J.D., Sun, Y., Su, W.: Water effect on amine-modification of adsorbents for separation of CO2/N2. Trans. Tianjin Univ. 19, 313–318 (2013)CrossRef
Zhao, D.Y., Feng, J.L., Huo, Q.S., Melosh, N., Fredrickson, G.H., Chmelka, B.F., Stucky, G.D.: Triblock copolymer synthesis of mesoporous silica with periodic 50 to 300 Angstrom pores. Science 279, 548–552 (1998)CrossRef
Zhao, Y.X., Seredych, M., Zhong, Q., Bandosz, T.J.: Superior performance of copper based MOF and aminated graphite oxide composites as CO2 adsorbents at room temperature. ACS Appl. Mater. Interfaces 5, 4951–4959 (2013)CrossRef
Zhao, Y.X., Seredych, M., Jagiello, J., Zhong, Q., Bandosz, T.J.: Insight into the mechanism of CO2 adsorption on Cu-BTC and its composites with graphite oxide or aminated graphite oxide. Chem. Eng. J. 239, 399–407 (2014)CrossRef
Metadaten
Titel
Chromium-based metal–organic framework/mesoporous carbon composite: synthesis, characterization and CO2 adsorption
verfasst von
Zhongzheng Zhang
Hui Wang
Xinqing Chen
Chenming Zhu
Wei Wei
Yuhan Sun
Publikationsdatum
01.02.2015
Verlag
Springer US
Erschienen in
Adsorption / Ausgabe 1-2/2015
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI
https://doi.org/10.1007/s10450-015-9651-2

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