Skip to main content
Erschienen in: Journal of Materials Science: Materials in Electronics 4/2019

12.01.2019

CoFe2O4 nanoparticles directly grown on carbon nanotube with coralline structure as anodes for lithium ion battery

verfasst von: Meng Yu, Zhenhe Feng, Ying Huang, Ke Wang, Liu Liu

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 4/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In this work, tiny CoFe2O4 nanoparticles with a diameter of several nanometers were firmly grown on carbon nanotube (CNT) through a solvothermal process followed with calcination step. The composite shows a coralline structure, where CoFe2O4 nanoparticles are dispersed finely on the surface of CNT. The coralline CoFe2O4–CNT composite electrode can deliver initial discharge/charge capacities of 1183.6/876.1 mAh g−1 at 100 mA g−1, with a Coulombic efficiency reaching up to 74.0%. The capacity drops first but ascends latter when the electrode is cycled 220 times at 200 mA g−1, giving a value of 747.5 mAh g−1 at 220th discharge process. Besides, the composite displays a capacity of 620.8 mAh g−1 even at a high rate of 1600 mA g−1, larger than commercialized graphite (372 mAh g−1). Thus, coralline CoFe2O4–CNT composite of remarkable electrochemical properties makes it a promising anode for lithium ion batteries.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat M. Armand, J.M. Tarascon, Building better batteries. Nature 451, 652–657 (2008)CrossRef M. Armand, J.M. Tarascon, Building better batteries. Nature 451, 652–657 (2008)CrossRef
2.
Zurück zum Zitat J.M. Tarascon, M. Armand, Issues and challenges facing rechargeable lithium batteries. Nature 414, 359–367 (2001)CrossRef J.M. Tarascon, M. Armand, Issues and challenges facing rechargeable lithium batteries. Nature 414, 359–367 (2001)CrossRef
3.
Zurück zum Zitat J.B. Goodenough, Y. Kim, Challenges for rechargeable Li batteries. Chem. Mater. 22, 587–603 (2010)CrossRef J.B. Goodenough, Y. Kim, Challenges for rechargeable Li batteries. Chem. Mater. 22, 587–603 (2010)CrossRef
4.
Zurück zum Zitat T.H. Kim, J.S. Park, S.K. Chang, S. Choi, H.R. Ji, H.K. Song, The current move of lithium ion batteries towards the next phase. Adv. Energy Mater. 2, 860–872 (2012)CrossRef T.H. Kim, J.S. Park, S.K. Chang, S. Choi, H.R. Ji, H.K. Song, The current move of lithium ion batteries towards the next phase. Adv. Energy Mater. 2, 860–872 (2012)CrossRef
5.
Zurück zum Zitat P.L. Taberna, S. Mitra, P. Poizot, P. Simon, J.M. Tarascon, High rate capabilities Fe3O4-based Cu nano-architectured electrodes for lithium-ion battery applications. Nat. Mater. 5, 567–573 (2006)CrossRef P.L. Taberna, S. Mitra, P. Poizot, P. Simon, J.M. Tarascon, High rate capabilities Fe3O4-based Cu nano-architectured electrodes for lithium-ion battery applications. Nat. Mater. 5, 567–573 (2006)CrossRef
6.
Zurück zum Zitat D. Bresser, E. Paillard, R. Kloepsch, S. Krueger, M. Fiedler, R. Schmitz, D. Baither, M. Winter, S. Passerini, Carbon coated ZnFe2O4 nanoparticles for advanced lithium-ion anodes. Adv. Energy Mater. 3, 513–523 (2013)CrossRef D. Bresser, E. Paillard, R. Kloepsch, S. Krueger, M. Fiedler, R. Schmitz, D. Baither, M. Winter, S. Passerini, Carbon coated ZnFe2O4 nanoparticles for advanced lithium-ion anodes. Adv. Energy Mater. 3, 513–523 (2013)CrossRef
7.
Zurück zum Zitat Y. Fu, Y. Wan, H. Xia, X. Wang, Nickel ferrite-graphene heteroarchitectures: toward high-performance anode materials for lithium-ion batteries. J. Power Sources 213, 338–342 (2012)CrossRef Y. Fu, Y. Wan, H. Xia, X. Wang, Nickel ferrite-graphene heteroarchitectures: toward high-performance anode materials for lithium-ion batteries. J. Power Sources 213, 338–342 (2012)CrossRef
8.
Zurück zum Zitat D. Pasero, N. Reeves, A.R. West, Co-doped Mn3O4: a possible anode material for lithium batteries. J. Power Sources 141, 156–158 (2005)CrossRef D. Pasero, N. Reeves, A.R. West, Co-doped Mn3O4: a possible anode material for lithium batteries. J. Power Sources 141, 156–158 (2005)CrossRef
9.
Zurück zum Zitat Y. Wang, J. Park, B. Sun, H. Ahn, G. Wang, Wintersweet-flower-like CoFe2O4/MWCNTs hybrid material for high-capacity reversible lithium storage. Chemistry 43, 1940–1946 (2012) Y. Wang, J. Park, B. Sun, H. Ahn, G. Wang, Wintersweet-flower-like CoFe2O4/MWCNTs hybrid material for high-capacity reversible lithium storage. Chemistry 43, 1940–1946 (2012)
10.
Zurück zum Zitat M.V. Reddy, G.V. Subba Rao, B.V. Chowdari, Metal oxides and oxysalts as anode materials for Li ion batteries. Chem. Rev. 113, 5364–5457 (2013)CrossRef M.V. Reddy, G.V. Subba Rao, B.V. Chowdari, Metal oxides and oxysalts as anode materials for Li ion batteries. Chem. Rev. 113, 5364–5457 (2013)CrossRef
11.
Zurück zum Zitat X. Hui, D. Zhu, Y. Fu, W. Xin, CoFe2O4-graphene nanocomposite as a high-capacity anode material for lithium-ion batteries. Electrochim. Acta 83, 166–174 (2012)CrossRef X. Hui, D. Zhu, Y. Fu, W. Xin, CoFe2O4-graphene nanocomposite as a high-capacity anode material for lithium-ion batteries. Electrochim. Acta 83, 166–174 (2012)CrossRef
12.
Zurück zum Zitat Z. Zhou, Y. Zhang, Z. Wang, W. Wei, W. Tang, J. Shi, R. Xiong, Electronic structure studies of the spinel CoFe2O4 by X-ray photoelectron spectroscopy. Appl. Surf. Sci. 254, 6972–6975 (2008)CrossRef Z. Zhou, Y. Zhang, Z. Wang, W. Wei, W. Tang, J. Shi, R. Xiong, Electronic structure studies of the spinel CoFe2O4 by X-ray photoelectron spectroscopy. Appl. Surf. Sci. 254, 6972–6975 (2008)CrossRef
13.
Zurück zum Zitat Y. Xiang, H. Wu, K.H. Zhang, M. Coto, T. Zhao, S. Chen, B. Dong, S. Lu, A. Abdelkader, Y. Guo, Quick one-pot synthesis of amorphous carbon-coated cobalt-ferrite twin elliptical frustums for enhanced lithium storage capability. J. Mater. Chem. A 5, 8062–8069 (2017)CrossRef Y. Xiang, H. Wu, K.H. Zhang, M. Coto, T. Zhao, S. Chen, B. Dong, S. Lu, A. Abdelkader, Y. Guo, Quick one-pot synthesis of amorphous carbon-coated cobalt-ferrite twin elliptical frustums for enhanced lithium storage capability. J. Mater. Chem. A 5, 8062–8069 (2017)CrossRef
14.
Zurück zum Zitat X. Fu, D. Chen, M. Wang, Y. Yang, Q. Wu, J. Ma, X. Zhao, Synthesis of porous CoFe2O4 octahedral structures and studies on electrochemical Li storage behavior. Electrochim. Acta 116, 164–169 (2014)CrossRef X. Fu, D. Chen, M. Wang, Y. Yang, Q. Wu, J. Ma, X. Zhao, Synthesis of porous CoFe2O4 octahedral structures and studies on electrochemical Li storage behavior. Electrochim. Acta 116, 164–169 (2014)CrossRef
15.
Zurück zum Zitat A.K. Rai, J. Gim, T.V. Thi, D. Ahn, S.J. Cho, J. Kim, High rate capability and long cycle stability of Co3O4/CoFe2O4 nanocomposite as an anode material for high-performance secondary lithium ion batteries. J. Phys. Chem. C 118, 11234–11243 (2014)CrossRef A.K. Rai, J. Gim, T.V. Thi, D. Ahn, S.J. Cho, J. Kim, High rate capability and long cycle stability of Co3O4/CoFe2O4 nanocomposite as an anode material for high-performance secondary lithium ion batteries. J. Phys. Chem. C 118, 11234–11243 (2014)CrossRef
16.
Zurück zum Zitat X. Yao, J. Kong, X. Tang, D. Zhou, C. Zhao, R. Zhou, X. Lu, Facile synthesis of porous CoFe2O4 nanosheets for lithium-ion battery anodes with enhanced rate capability and cycling stability. Rsc Adv. 4, 27488–27492 (2014)CrossRef X. Yao, J. Kong, X. Tang, D. Zhou, C. Zhao, R. Zhou, X. Lu, Facile synthesis of porous CoFe2O4 nanosheets for lithium-ion battery anodes with enhanced rate capability and cycling stability. Rsc Adv. 4, 27488–27492 (2014)CrossRef
17.
Zurück zum Zitat Z. Zhang, Y. Wang, M. Zhang, Q. Tan, X. Lv, Z. Zhong, F. Su, Mesoporous CoFe2O4 nanospheres cross-linked by carbon nanotubes as high-performance anodes for lithium-ion batteries. J. Mater. Chem. A 1, 7444–7450 (2013)CrossRef Z. Zhang, Y. Wang, M. Zhang, Q. Tan, X. Lv, Z. Zhong, F. Su, Mesoporous CoFe2O4 nanospheres cross-linked by carbon nanotubes as high-performance anodes for lithium-ion batteries. J. Mater. Chem. A 1, 7444–7450 (2013)CrossRef
18.
Zurück zum Zitat Z.H. Li, T.P. Zhao, X.Y. Zhan, D.S. Gao, Q.Z. Xiao, G.T. Lei, High capacity three-dimensional ordered macroporous CoFe2O4 as anode material for lithium ion batteries. Electrochim. Acta 55, 4594–4598 (2010)CrossRef Z.H. Li, T.P. Zhao, X.Y. Zhan, D.S. Gao, Q.Z. Xiao, G.T. Lei, High capacity three-dimensional ordered macroporous CoFe2O4 as anode material for lithium ion batteries. Electrochim. Acta 55, 4594–4598 (2010)CrossRef
19.
Zurück zum Zitat N. Li, M. Zheng, X. Chang, G. Ji, H. Lu, L. Xue, L. Pan, J. Cao, Preparation of magnetic CoFe2O4-functionalized graphene sheets via a facile hydrothermal method and their adsorption properties. J. Solid State Chem. 184, 953–958 (2011)CrossRef N. Li, M. Zheng, X. Chang, G. Ji, H. Lu, L. Xue, L. Pan, J. Cao, Preparation of magnetic CoFe2O4-functionalized graphene sheets via a facile hydrothermal method and their adsorption properties. J. Solid State Chem. 184, 953–958 (2011)CrossRef
20.
Zurück zum Zitat H. Fu, Z.J. Du, W. Zou, H.Q. Li, C. Zhang, Simple fabrication of strongly coupled cobalt ferrite/carbon nanotube composite based on deoxygenation for improving lithium storage. Carbon 65, 112–123 (2013)CrossRef H. Fu, Z.J. Du, W. Zou, H.Q. Li, C. Zhang, Simple fabrication of strongly coupled cobalt ferrite/carbon nanotube composite based on deoxygenation for improving lithium storage. Carbon 65, 112–123 (2013)CrossRef
21.
Zurück zum Zitat Y. Sharma, N. Sharma, G.V.S. Rao, B.V.R. Chowdari, Li-storage and cyclability of urea combustion derived ZnFe2O4 as anode for Li-ion batteries. Electrochim. Acta 53, 2380–2385 (2008)CrossRef Y. Sharma, N. Sharma, G.V.S. Rao, B.V.R. Chowdari, Li-storage and cyclability of urea combustion derived ZnFe2O4 as anode for Li-ion batteries. Electrochim. Acta 53, 2380–2385 (2008)CrossRef
22.
Zurück zum Zitat Y. Deng, Q. Zhang, S. Tang, L. Zhang, S. Deng, Z. Shi, G. Chen, One-pot synthesis of ZnFe2O4/C hollow spheres as superior anode materials for lithium ion batteries. Chem. Commun. 47, 6828–6830 (2011)CrossRef Y. Deng, Q. Zhang, S. Tang, L. Zhang, S. Deng, Z. Shi, G. Chen, One-pot synthesis of ZnFe2O4/C hollow spheres as superior anode materials for lithium ion batteries. Chem. Commun. 47, 6828–6830 (2011)CrossRef
23.
Zurück zum Zitat H. Xia, Y. Qian, Y. Fu, X. Wang, Graphene anchored with ZnFe2O4 nanoparticles as a high-capacity anode material for lithium-ion batteries. Solid State Sci. 17, 67–71 (2013)CrossRef H. Xia, Y. Qian, Y. Fu, X. Wang, Graphene anchored with ZnFe2O4 nanoparticles as a high-capacity anode material for lithium-ion batteries. Solid State Sci. 17, 67–71 (2013)CrossRef
24.
Zurück zum Zitat H. Duncan, F.M. Courtel, Y. Abu-Lebdeh, A study of the solid-electrolyte-interface (SEI) of ZnMn2O4: a conversion-type anode material for Li-ion batteries. J. Electrochem. Soc. 162, A7110–A7117 (2015)CrossRef H. Duncan, F.M. Courtel, Y. Abu-Lebdeh, A study of the solid-electrolyte-interface (SEI) of ZnMn2O4: a conversion-type anode material for Li-ion batteries. J. Electrochem. Soc. 162, A7110–A7117 (2015)CrossRef
25.
Zurück zum Zitat X. Guo, X. Lu, X. Fang, Y. Mao, Z. Wang, L. Chen, X. Xu, H. Yang, Y. Liu, Lithium storage in hollow spherical ZnFeO as anode materials for lithium ion batteries. Electrochem. Commun. 12, 847–850 (2010)CrossRef X. Guo, X. Lu, X. Fang, Y. Mao, Z. Wang, L. Chen, X. Xu, H. Yang, Y. Liu, Lithium storage in hollow spherical ZnFeO as anode materials for lithium ion batteries. Electrochem. Commun. 12, 847–850 (2010)CrossRef
26.
Zurück zum Zitat J. Liu, J. Xiao, X. Zeng, P. Dong, J. Zhao, Y. Zhang, X. Li, Combustion synthesized macroporous structure MFe2O4 (M = Zn, Co) as anode materials with excellent electrochemical performance for lithium ion batteries. J. Alloys Compds. 699, 401–407 (2017)CrossRef J. Liu, J. Xiao, X. Zeng, P. Dong, J. Zhao, Y. Zhang, X. Li, Combustion synthesized macroporous structure MFe2O4 (M = Zn, Co) as anode materials with excellent electrochemical performance for lithium ion batteries. J. Alloys Compds. 699, 401–407 (2017)CrossRef
27.
Zurück zum Zitat L. Yao, X. Hou, Q. Ru, X. Tang, L. Zhao, D. Sun, A facile bubble-assisted synthesis of porous Zn ferrite hollow microsphere and their excellent performance as an anode in lithium ion battery. J. Solid State Electron. 17, 2055–2060 (2013)CrossRef L. Yao, X. Hou, Q. Ru, X. Tang, L. Zhao, D. Sun, A facile bubble-assisted synthesis of porous Zn ferrite hollow microsphere and their excellent performance as an anode in lithium ion battery. J. Solid State Electron. 17, 2055–2060 (2013)CrossRef
28.
Zurück zum Zitat X. Zhang, Y. Xie, Y. Sun, Q. Zhang, Q. Zhu, D. Hou, J. Guo, Self-template synthesis of CoFe2O4 nanotubes for high-performance lithium storage. Rsc Adv. 5, 29837–29841 (2015)CrossRef X. Zhang, Y. Xie, Y. Sun, Q. Zhang, Q. Zhu, D. Hou, J. Guo, Self-template synthesis of CoFe2O4 nanotubes for high-performance lithium storage. Rsc Adv. 5, 29837–29841 (2015)CrossRef
29.
Zurück zum Zitat Z.S. Wu, W. Ren, L. Wen, L. Gao, J. Zhao, Z. Chen, G. Zhou, F. Li, H.M. Cheng, Graphene anchored with Co3O4 nanoparticles as anode of lithium ion batteries with enhanced reversible capacity and cyclic performance. Acs Nano 4, 3187–3194 (2010)CrossRef Z.S. Wu, W. Ren, L. Wen, L. Gao, J. Zhao, Z. Chen, G. Zhou, F. Li, H.M. Cheng, Graphene anchored with Co3O4 nanoparticles as anode of lithium ion batteries with enhanced reversible capacity and cyclic performance. Acs Nano 4, 3187–3194 (2010)CrossRef
30.
Zurück zum Zitat J. Wang, Q. Zhang, X. Li, B. Zhang, L. Mai, K. Zhang, Smart construction of three-dimensional hierarchical tubular transition metal oxide core/shell heterostructures with high-capacity and long-cycle-life lithium storage. Nano Energy 12, 437–446 (2015)CrossRef J. Wang, Q. Zhang, X. Li, B. Zhang, L. Mai, K. Zhang, Smart construction of three-dimensional hierarchical tubular transition metal oxide core/shell heterostructures with high-capacity and long-cycle-life lithium storage. Nano Energy 12, 437–446 (2015)CrossRef
31.
Zurück zum Zitat J. Wang, J. Wu, Z. Wu, L. Han, T. Huang, H.L. Xin, D. Wang, High-rate and long-life lithium-ion battery performance of hierarchically hollow-structured NiCo2O4/CNT nanocomposite. Electrochim. Acta 244, 8–15 (2017)CrossRef J. Wang, J. Wu, Z. Wu, L. Han, T. Huang, H.L. Xin, D. Wang, High-rate and long-life lithium-ion battery performance of hierarchically hollow-structured NiCo2O4/CNT nanocomposite. Electrochim. Acta 244, 8–15 (2017)CrossRef
32.
Zurück zum Zitat S. Abouali, M.A. Garakani, Z.L. Xu, J.K. Kim, NiCo2O4/CNT nanocomposites as bi-functional electrodes for Li ion batteries and supercapacitors. Carbon 102, 262–272 (2016)CrossRef S. Abouali, M.A. Garakani, Z.L. Xu, J.K. Kim, NiCo2O4/CNT nanocomposites as bi-functional electrodes for Li ion batteries and supercapacitors. Carbon 102, 262–272 (2016)CrossRef
33.
Zurück zum Zitat Q. Ru, X. Song, Y. Mo, L. Guo, S. Hu, Carbon nanotubes modified for ZnCo2O4 with a novel porous polyhedral structure as anodes for lithium ion batteries with improved performances. J. Alloys Compds. 654, 586–592 (2016)CrossRef Q. Ru, X. Song, Y. Mo, L. Guo, S. Hu, Carbon nanotubes modified for ZnCo2O4 with a novel porous polyhedral structure as anodes for lithium ion batteries with improved performances. J. Alloys Compds. 654, 586–592 (2016)CrossRef
34.
Zurück zum Zitat M.D.L. And, D. Aurbach, Simultaneous measurements and modeling of the electrochemical impedance and the cyclic voltammetric characteristics of graphite electrodes doped with lithium. J. Phys. Chem. B 101, 4630–4640 (1997)CrossRef M.D.L. And, D. Aurbach, Simultaneous measurements and modeling of the electrochemical impedance and the cyclic voltammetric characteristics of graphite electrodes doped with lithium. J. Phys. Chem. B 101, 4630–4640 (1997)CrossRef
Metadaten
Titel
CoFe2O4 nanoparticles directly grown on carbon nanotube with coralline structure as anodes for lithium ion battery
verfasst von
Meng Yu
Zhenhe Feng
Ying Huang
Ke Wang
Liu Liu
Publikationsdatum
12.01.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 4/2019
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-00709-2

Weitere Artikel der Ausgabe 4/2019

Journal of Materials Science: Materials in Electronics 4/2019 Zur Ausgabe

Neuer Inhalt