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Erschienen in: Journal of Materials Science: Materials in Electronics 14/2020

10.06.2020

Comparative studies of BaBi0.05Zr0.1Co0.85−xNbxO3−δ (x = 0 and 0.05) as cathodes for intermediate-temperature solid oxide fuel cells

verfasst von: Qingjun Zhou, Yong He, Fanxing Bu, Ting Zhang, Mingchao Wang, Yan Li, Dongmin An

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 14/2020

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Abstract

Multi-element-doped BaBi0.05Zr0.1Co0.85–xNbxO3–δ (x = 0 or 0.05, and denoted as BBZC, BBZCN, respectively) perovskite oxides are fabricated and the phase composition, electrical conductivity, thermal expansion, and electrochemical performance are investigated. With 5% Nb substitution, BBZCN exhibits improved phase structure and a reduced thermal expansion coefficient. The BBZC and BBZCN cathodes exhibited chemical compatibility with the La0.9Sr0.1Ga0.8Mg0.2O3–δ (LSGM) electrolyte. The area-specific resistances of the BBZC and BBZCN cathodes are 0.021 and 0.023 Ω cm2 with LSGM electrolyte at 800 °C. The peak power densities of 515 and 566 mW cm–2 are obtained from single cell with BBZC and BBZCN cathodes at 800 °C, respectively. These results indicate that BBZC and BBZCN perovskite oxides will be a promising candidate as a cathode material for intermediate-temperature solid oxide fuel cells (IT-SOFCs).

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Metadaten
Titel
Comparative studies of BaBi0.05Zr0.1Co0.85−xNbxO3−δ (x = 0 and 0.05) as cathodes for intermediate-temperature solid oxide fuel cells
verfasst von
Qingjun Zhou
Yong He
Fanxing Bu
Ting Zhang
Mingchao Wang
Yan Li
Dongmin An
Publikationsdatum
10.06.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 14/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-03734-8

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