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Topics in Catalysis
Erschienen in: Topics in Catalysis 15-16/2017

13.04.2017 | Original Paper

Comparison of the Activity of Pd–M (M: Ag, Co, Cu, Fe, Ni, Zn) Bimetallic Electrocatalysts for Oxygen Reduction Reaction

verfasst von: Georgios Bampos, Symeon Bebelis, Dimitris I. Kondarides, Xenophon Verykios

Erschienen in: Topics in Catalysis | Ausgabe 15-16/2017

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Abstract

Carbon-supported 7.5 wt% Pd–2.5 wt% M (M: Ag, Co, Cu, Fe, Ni, Zn) bimetallic catalysts were synthesized via wet impregnation and assessed as electrocatalysts for the oxygen reduction reaction (ORR) in acidic solution at room temperature, using the thin-film rotating disk electrode technique. Monometallic 10 wt% Pt/C and 10 wt% Pd/C catalysts, prepared via the same method, were used as reference materials. The highest activity for ORR among the tested electrocatalysts was exhibited by PdZn/C and the lowest by Pd/C and PdCu/C. The activity of the rest Pd-based electrocatalysts followed the descending order: PdNi/C > PdAg/C ≥ PdCo/C > PdFe/C. The specific activity of PdZn/C was higher than that of Pt/C (more than 3 times higher for potentials 0.35–0.5 V versus Ag/AgCl), whereas their mass activities were similar. PdNi/C and PdAg/C also exhibited higher specific activity than Pt/C for potentials lower than ca. 0.4 V versus Ag/AgCl, but their mass activity was lower. The high ORR activity of PdZn/C, which renders it a promising alternative to Pt-based cathodic electrocatalysts in PEMFCs, was associated with the presence of Pd–Zn alloy in the active phase, as revealed via XRD and TEM.
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Metadaten
Titel
Comparison of the Activity of Pd–M (M: Ag, Co, Cu, Fe, Ni, Zn) Bimetallic Electrocatalysts for Oxygen Reduction Reaction
verfasst von
Georgios Bampos
Symeon Bebelis
Dimitris I. Kondarides
Xenophon Verykios
Publikationsdatum
13.04.2017
Verlag
Springer US
Erschienen in
Topics in Catalysis / Ausgabe 15-16/2017
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-017-0795-z

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