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Recovery processes of secondary resources usually encounter problems because of the diverse compositions of wastes. To enhance the applicability of traditional hydrometallurgical process toward secondary resources, the adjustment of components is necessary. In traditional hydrometallurgical separation, precipitation and complexation are extensively used. However, their combination as a specific metal separation method has not yet been studied in detail. This approach is very promising for solving problems caused by changeable components during recycling processes of secondary resources. This paper reviews the effects of precipitation and complexation in metal separation processes, and a metal separation method system of “complexation–precipitation” developed to adjust the components of secondary resources is introduced.
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Li JH, Li XH, Hu QY, Wang ZX, Zheng JC, Wu L, Zhang LX. Study of extraction and purification of Ni, Co and Mn from spent battery material. Hydrometallurgy. 2009;99(1–2):7. CrossRef
Lee J, Pandey BD. Bio-processing of solid wastes and secondary resources for metal extraction—a review. Waste Manag. 2012;32(1):3. CrossRef
Belardi G, Lavecchia R, Medici F, Piga L. Thermal treatment for recovery of manganese and zinc from zinc–carbon and alkaline spent batteries. Waste Manag. 2012;32(10):1945. CrossRef
Zeng G, Deng X, Luo S, Luo X, Zou J. A copper-catalyzed bioleaching process for enhancement of cobalt dissolution from spent lithium-ion batteries. J Hazard Mater. 2012;199–200(15):164. CrossRef
Pinto Isabel SS, Soares Helena MVM. Microwave-assisted selective leaching of nickel from spent hydrodesulphurization catalyst: a comparative study between sulphuric and organic acids. Hydrometallurgy. 2013;140:20. CrossRef
Zhang SG, Yang M, Liu H, Pan DA, Tian JJ. Recovery of waste rare earth fluorescent powders by two steps acid leaching. Rare Met. 2013;32(6):609. CrossRef
Fernandes A, Afonso JC, Dutra AJB. Separation of nickel(II), cobalt(II) and lanthanides from spent Ni-MH batteries by hydrochloric acid leaching, solvent extraction and precipitation. Hydrometallurgy. 2013;133:37. CrossRef
Rácz R, Ilea P. Electrolytic recovery of Mn 3O 4 and Zn from sulphuric acid leach liquors of spent zinc–carbon–MnO 2 battery powder. Hydrometallurgy. 2013;139:116. CrossRef
Coman V, Robotin B, Ilea P. Nickel recovery/removal from industrial wastes: a review. Resour Conserv Recycl. 2013;73:229. CrossRef
Chen L, Tang X, Zhang Y, Li L, Zeng Z, Zhang Y. Process for the recovery of cobalt oxalate from spent lithium-ion batteries. Hydrometallurgy. 2011;108(1–2):80. CrossRef
Haghighi HK, Moradkhani D, Sedaghat B, Najafabadi MR, Behnamfard A. Production of copper cathode from oxidized copper ores by acidic leaching and two-step precipitation followed by electrowinning. Hydrometallurgy. 2013;133:111. CrossRef
Janin A, Zaviska F, Drogui P, Blais JF, Mercier G. Selective recovery of metals in leachate from chromated copper arsenate treated wastes using electrochemical technology and chemical precipitation. Hydrometallurgy. 2009;96(4):318. CrossRef
Huang JH, Kargl-Simard C, Oliazadeh M, Alfantazi AM. pH-controlled precipitation of cobalt and molybdenum from industrial waste effluents of a cobalt electrodeposition process. Hydrometallurgy. 2004;75(1):77. CrossRef
Giannopoulou I, Panias D. Differential precipitation of copper and nickel from acidic polymetallic aqueous solutions. Hydrometallurgy. 2008;90(2):137. CrossRef
Zhu Z, Pranolo Y, Zhang W, Wang W, Cheng CY. Precipitation of impurities from synthetic laterite leach solutions. Hydrometallurgy. 2010;104(1):81. CrossRef
Avila M, Grinbaum B, Carranza F, Mazuelos A, Romero R, Iglesias N, Lozano JL, Perez G, Valiente M. Zinc recovery from an effluent using Ionquest 290: from laboratory scale to pilot plant. Hydrometallurgy. 2011;107(3–4):63. CrossRef
Lu MN, Das RP, Li W, Peng JH, Zhang LB. Microwave mediated precipitation and aging of iron oxyhydroxides at low temperature for possible hydrometallurgical applications. Hydrometallurgy. 2013;134–135:110. CrossRef
Silva AM, Cunha EC, Silva FDR, Leão VA. Treatment of high-manganese mine water with limestone and sodium carbonate. J Clean Prod. 2012;29–30:11. CrossRef
Formanek J, Jandova J, Capek J. Iron removal from zinc liquors originating from hydrometallurgical processing of spent Zn/MnO 2 batteries. Hydrometallurgy. 2013;138:100. CrossRef
Lewis AE. Review of metal sulphide precipitation. Hydrometallurgy. 2010;104(2):222. CrossRef
Xie Y, Xu Y, Yan L, Yang R. Recovery of nickel, copper and cobalt from low-grade Ni–Cu sulfide tailings. Hydrometallurgy. 2005;80(1–2):54. CrossRef
Deniz U, Bekmezci OK, Kaksonen AH, Sahinkaya E. Sequential precipitation of Cu and Fe using a three-stage sulfidogenic fluidized-bed reactor system. Miner Eng. 2011;24(11):1100. CrossRef
Paulino JF, Busnardo NG, Afonso JC. Recovery of valuable elements from spent Li-batteries. J Hazard Mater. 2008;150(3):843. CrossRef
Chen X, Chen A, Zhao Z, Liu X, Shi Y, Wang D. Removal of Cu from the nickel electrolysis anolyte using nickel thiocarbonate. Hydrometallurgy. 2013;133:106. CrossRef
Rabah MA, Farghaly FE, Abd-El MMA. Recovery of nickel, cobalt and some salts from spent Ni-MH batteries. Waste Manag. 2008;28(7):1159. CrossRef
du Plessis CA, Slabbert W, Hallberg KB, Barrie JD. Ferredox: a biohydrometallurgical processing concept for limonitic nickel laterite. Hydrometallurgy. 2011;109(3–4):221. CrossRef
Song Y, Wang M, Liang J, Zhou L. High-rate precipitation of iron as jarosite by using a combination process of electrolytic reduction and biological oxidation. Hydrometallurgy. 2014;143:23. CrossRef
Wang M, Zhou L. Simultaneous oxidation and precipitation of iron using jarosite immobilized acidithiobacillus ferrooxidans and its relevance to acid mine drainage. Hydrometallurgy. 2012;125–126:152. CrossRef
Dutrizac JE, Chen TT. The behaviour of phosphate during jarosite precipitation. Hydrometallurgy. 2010;102(1):55. CrossRef
Mohapatra M, Anand S, Das RP. Behaviour of Co(II) in solutions obtained by dissolution of cobalto–cobaltic oxide in NH 3–SO 2–H 2O medium. Hydrometallurgy. 2001;61(3):169. CrossRef
Zhang W, Zhao Z, Chen X. The behaviour of phosphorus impurities in the novel selective precipitation process. Hydrometallurgy. 2013;139:111. CrossRef
Nathsarma KC, Rout PC, Sarangi K. Manganese precipitation kinetics and cobalt adsorption on MnO 2 from the ammoniacal ammonium sulfate leach liquor of Indian Ocean manganese nodule. Hydrometallurgy. 2013;133:133. CrossRef
Zhang W, Singh P, Muir D. Oxidative precipitation of manganese with SO 2/O 2 and separation from cobalt and nickel. Hydrometallurgy. 2002;63(2):127. CrossRef
Zhang W, Cheng CY, Pranolo Y. Investigation of methods for removal and recovery of manganese in hydrometallurgical processes. Hydrometallurgy. 2010;101(1–2):58. CrossRef
Zhao HP, Guo YF, Zhang XX. Electrolytic recovery of nickel powder from acid-washing solution containing nickel in artificial diamond production. Chin J Process Eng. 2004;4(4):310.
Nishimura T, Umetsu Y. Oxidative precipitation of arsenic(III)/with manganese(II)/and iron(II) in dilute acidic solution by ozone. Hydrometallurgy. 2001;62(2):83. CrossRef
Kim T-H, Senanayake G, Kang J-G, Sohn J-S, Rhee K-I, Lee S-W, Shin S-M. Reductive acid leaching of spent zinc–carbon batteries and oxidative precipitation of Mn–Zn ferrite nanoparticles. Hydrometallurgy. 2009;96(1–2):154. CrossRef
Yin Z, Ding Z, Hu H, Liu K, Chen Q. Dissolution of zinc silicate (hemimorphite) with ammonia–ammonium chloride solution. Hydrometallurgy. 2010;103(1–4):215. CrossRef
Park K-H, Mohapatra D, Reddy BR, Nam C-W. A study on the oxidative ammonia/ammonium sulphate leaching of a complex (Cu–Ni–Co–Fe) matte. Hydrometallurgy. 2007;86(3):164. CrossRef
Ma B, Wang C, Yang W, Yin F, Chen Y. Screening and reduction roasting of limonitic laterite and ammonia-carbonate leaching of nickel–cobalt to produce a high-grade iron concentrate. Miner Eng. 2013;50–51:106. CrossRef
Li L, Ge J, Chen RJ, Wu AF, Chen S, Zhang XX. Environmental friendly leaching reagent for cobalt and lithium recovery from spent lithium-ion batteries. Waste Manag. 2010;30(12):2615. CrossRef
Li L, Ge J, Wu F, Chen R, Chen S, Wu B. Recovery of cobalt and lithium from spent lithium ion batteries using organic citric acid as leachant. J Hazard Mater. 2010;176(1–3):288. CrossRef
Goel S, Gautam A. Effect of chelating agents on mobilization of metal from waste catalyst. Hydrometallurgy. 2010;101(3–4):120. CrossRef
Wang XF, Kong XH, Zhao ZY. Recovery of noble metal in lithium ion battery. Battery. 2001;31(1):14.
Zhang X, Ji L, Wang J, Li R, Liu Q, Zhang M, Liu L. Removal of uranium(VI) from aqueous solutions by magnetic Mg–Al layered double hydroxide intercalated with citrate: kinetic and thermodynamic investigation. Colloids Surf A Physicochem Eng Asp. 2012;414:220. CrossRef
Wang T, Liu W, Xiong L, Xu N, Ni J. Influence of pH, ionic strength and humic acid on competitive adsorption of Pb(II), Cd(II) and Cr(III) onto titanate nanotubes. Chem Eng J. 2013;215–216(1):366. CrossRef
Cao HZ, Zheng GQ, Zhi B, Tang MT. Cathodic process of zinc electrowinning in solution containing ammonia complex. Chin J Nonferr Met. 2005;15(4):655.
Zhang LJ, Tao HC, Wei XY, Lei T, Li JB, Wang AJ, Wu WM. Bioelectrochemical recovery of ammonia–copper(II) complexes from wastewater using a dual chamber microbial fuel cell. Chemosphere. 2012;89(10):1177. CrossRef
Almeida MRH, Barbano EP, Carvalho MF, Carlos IA, Siqueira JLP, Barbosa LL. Electrodeposition of copper–zinc from an alkaline bath based on EDTA. Surf Coat Technol. 2011;206(1):95. CrossRef
Liu ZX, Yin ZL, Xiong SF, Chen YG, Chen QY. Leaching and kinetic modeling of calcareous bornite in ammonia ammonium sulfate solution with sodium persulfate. Hydrometallurgy. 2014;144–145:86. CrossRef
Deutsch JL, Dreisinger DB. Silver sulfide leaching with thiosulfate in the presence of additives Part I: copper–ammonia leaching. Hydrometallurgy. 2013;137:156. CrossRef
Zhang W, Tsang DCW, Lo IMC. Removal of Pb and MDF from contaminated soils by EDTA- and SDS-enhanced washing. Chemosphere. 2007;66(11):2025. CrossRef
Hernández CMF, Banza AN, Gock E. Recovery of metals from Cuban nickel tailings by leaching with organic acids followed by precipitation and magnetic separation. J Hazard Mater. 2007;139(1):25. CrossRef
Senanayake G. Catalytic role of ammonia in the anodic oxidation of gold in copper-free thiosulfate solutions. Hydrometallurgy. 2005;77(3–4):287. CrossRef
Pedersen AJ, Ottosen LM, Villumsen A. Electrodialytic removal of heavy metals from municipal solid waste incineration fly ash using ammonium citrate as assisting agent. J Hazard Mater. 2005;122(1–2):103. CrossRef
Zhang W, Cheng CY. Manganese metallurgy review. Part II: manganese separation and recovery from solution. Hydrometallurgy. 2007;89(3–4):160. CrossRef
Shen QF, Yang XW. Solubility of Fe 2+/Mn 2+/Zn 2+ in NH 3–H 2O system. Nonferr Met. 2003;55(4):65.
Nadirov RK, Syzdykova LI, Zhussupova AK, Usserbaev MT. Recovery of value metals from copper smelter slag by ammonium chloride treatment. Int J Miner Process. 2013;124:145. CrossRef
Chen L, Tang XC, Zhang Y, Qu Y, Wang ZM. Separation and recovery of Ni, Co and Mn from spent lithium-ion batteries. Chin J Nonferr Met. 2011;21(5):1192.
Zhao ZW, Wang DD, Chen AL, Huo GS, Chen XY. Application and prospect of leaching processes of cobalt from Cu–Co alloy and slag. Hydrometall China. 2008;27(4):195.
Dean JA, Wei J (Translator). Lange’s Handbook of Chemistry. 2nd edition. Beijing: Science Press; 2003. 8.80.
Zhang P. Advanced Chemistry for Engineering. Changsha: Hunan Educational Press; 2002. 337.
Zhang CF, Yao YL, Zhan J. Thermodynamics of precipitation–coordination equilibrium in Fe 2+–Ni 2+–NH 3–NH 4+–C 2O 42−–H 2O system. Chin J Nonferr Met. 2012;22(10):2938.
Chai LY, Chang H, Wang YY, Shu YD, Li J, Yuan L, Wang P, Fang Y, Zhao K. Equilibrium of hydroxyl complex ions in Cd 2+–H 2O system. Chin J Nonferr Met. 2007;17(3):487.
Su JT, Su YC, Lai ZG, Yu P, He XD. Thermodynamic analysis of preparation of multiple carbonate of Ni, Co and Mn by coprecipitation method. J Chin Ceram Soc. 2006;34(6):695.
Ma LW, Nie ZR, Xi XL, Han XG. Thermodynamic equilibrium in Co–Ni–Fe–Mn complexation–precipitation system. Chin J Nonferr Met. 2013;23(2):516.
Ma LW, Nie ZR, Xi XL, Li XK. Theoretical simulation and experimental study on nickel, cobalt, manganese separation in complexation–precipitation system. Sep Purif Technol. 2013;108(19):124. CrossRef
Ma LW, Nie ZR, Xi XL, Han XG. Cobalt recovery from cobalt-bearing waste in sulphuric and citric acid systems. Hydrometallurgy. 2013;136:1. CrossRef
Zhu ZY, Zhu LW. Synthesis of layered cathode material 0.5Li 2MnO 3 0.5LiMn 1/3Ni 1/3Co 1/3O 2 by an improved co-precipitation method for lithium-ion battery. J Power Sources. 2014;256(6):178. CrossRef
- “Complexation–precipitation” metal separation method system and its application in secondary resources
- Nonferrous Metals Society of China
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