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Erschienen in: Journal of Materials Science 13/2020

13.01.2020 | Materials for life sciences

Composites of thiol-grafted PEDOT with N-doped graphene or graphitic carbon nitride as an electrochemical sensor for the detection of paracetamol

verfasst von: Yinqiang Yan, Ruxangul Jamal, Zongna Yu, Ruanye Zhang, Wenli Zhang, Yi Ge, Yingcheng Liu, Tursun Abdiryim

Erschienen in: Journal of Materials Science | Ausgabe 13/2020

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Abstract

A novel electrochemical sensor with thiol-grafted PEDOT/N-doped graphene (N-Gr/PEDOT-MeSH) and thiol-grafted PEDOT/graphitic carbon nitride (g-C3N4/PEDOT-MeSH) composites was fabricated for the detection of paracetamol (PAR). The formation mechanism of the obtained structure was thoroughly studied. And from the electrochemical results, the synergistic effect between the PEDOT-MeSH and g-C3N4 or N-Gr improved the electron transfer and conductivity of the modified electrodes and enhanced the sensing responses toward the electrochemical oxidation of PAR. The calibration curve of N-Gr/PEDOT-MeSH and g-C3N4/PEDOT-MeSH composites exhibited the wider linear responses for PAR, ranging from 2 to 1680 µM and 0.4 to 1280 µM, and the detection limits (S/N = 3) were 1.42 µM and 1.0 µM, respectively. Furthermore, the obtained composites exhibited the excellent reproducibility, lower detection limit and good stability. And it was capable of detecting PAR in real samples with a satisfying result.

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Literatur
3.
Zurück zum Zitat Deng C, Deng Y, Wang B, Yang X (2002) Gas chromatography–mass spectrometry method for determination of phenylalanine and tyrosine in neonatal blood spots. J Chromatogr B 780(2):407–413CrossRef Deng C, Deng Y, Wang B, Yang X (2002) Gas chromatography–mass spectrometry method for determination of phenylalanine and tyrosine in neonatal blood spots. J Chromatogr B 780(2):407–413CrossRef
14.
16.
20.
21.
Zurück zum Zitat Liu Y-N, Zhou X, Shen C-C, Zhao Z-W, Jiang Y-F, Ma L-B, Fang X-X, Akif Z, Cheag T-Y, Xu A-W (2018) Hydrogen-bonding-assisted charge transfer: significantly enhanced photocatalytic H2 evolution over g-C3N4 anchored with ferrocene-based hole relay. Catal Sci Technol 8(11):2853–2859. https://doi.org/10.1039/c8cy00488a CrossRef Liu Y-N, Zhou X, Shen C-C, Zhao Z-W, Jiang Y-F, Ma L-B, Fang X-X, Akif Z, Cheag T-Y, Xu A-W (2018) Hydrogen-bonding-assisted charge transfer: significantly enhanced photocatalytic H2 evolution over g-C3N4 anchored with ferrocene-based hole relay. Catal Sci Technol 8(11):2853–2859. https://​doi.​org/​10.​1039/​c8cy00488a CrossRef
26.
29.
Zurück zum Zitat Martin DJ, Qiu K, Shevlin SA, Handoko AD, Chen X, Guo Z, Tang J (2014) Highly efficient photocatalytic H2 evolution from water using visible light and structure-controlled graphitic carbon nitride. Angew Chem 126(35):9394–9399CrossRef Martin DJ, Qiu K, Shevlin SA, Handoko AD, Chen X, Guo Z, Tang J (2014) Highly efficient photocatalytic H2 evolution from water using visible light and structure-controlled graphitic carbon nitride. Angew Chem 126(35):9394–9399CrossRef
31.
52.
56.
Zurück zum Zitat Gholizadeh A, Shahrokhian S, Irajizad A, Mohajerzadeh S, Vosoughi M, Darbari S, Koohsorkhi J, Mehran M (2012) Fabrication of sensitive glutamate biosensor based on vertically aligned CNT nanoelectrode array and investigating the effect of CNTs density on the electrode performance. Anal Chem 84(14):5932–5938. https://doi.org/10.1021/ac300463x CrossRef Gholizadeh A, Shahrokhian S, Irajizad A, Mohajerzadeh S, Vosoughi M, Darbari S, Koohsorkhi J, Mehran M (2012) Fabrication of sensitive glutamate biosensor based on vertically aligned CNT nanoelectrode array and investigating the effect of CNTs density on the electrode performance. Anal Chem 84(14):5932–5938. https://​doi.​org/​10.​1021/​ac300463x CrossRef
60.
61.
Zurück zum Zitat Liu R, Zeng X, Liu J, Luo J, Zheng Y, Liu X (2016) A glassy carbon electrode modified with an amphiphilic, electroactive and photosensitive polymer and with multi-walled carbon nanotubes for simultaneous determination of dopamine and paracetamol. Microchim Acta 183(5):1543–1551. https://doi.org/10.1007/s00604-016-1763-1 CrossRef Liu R, Zeng X, Liu J, Luo J, Zheng Y, Liu X (2016) A glassy carbon electrode modified with an amphiphilic, electroactive and photosensitive polymer and with multi-walled carbon nanotubes for simultaneous determination of dopamine and paracetamol. Microchim Acta 183(5):1543–1551. https://​doi.​org/​10.​1007/​s00604-016-1763-1 CrossRef
Metadaten
Titel
Composites of thiol-grafted PEDOT with N-doped graphene or graphitic carbon nitride as an electrochemical sensor for the detection of paracetamol
verfasst von
Yinqiang Yan
Ruxangul Jamal
Zongna Yu
Ruanye Zhang
Wenli Zhang
Yi Ge
Yingcheng Liu
Tursun Abdiryim
Publikationsdatum
13.01.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 13/2020
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-020-04351-w

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