Skip to main content
Erschienen in: Journal of Materials Science 1/2015

01.01.2015 | Original Paper

Composition dependence of some thermo-physical properties of multi-component Se78−x Te20Sn2Bi x (0 ≤ x ≤ 6) chalcogenide glasses

verfasst von: A. Sharma, N. Mehta

Erschienen in: Journal of Materials Science | Ausgabe 1/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

New multi-component glassy materials with composition of Se78−x Te20Sn2Bi x (0 ≤ x ≤ 6) have been synthesized by well-known melt quenching technique. The as-prepared glasses have been characterized by applying an advanced transient plane source technique to study their thermal transport properties (effective thermal conductivity, diffusivity, specific heat per unit volume) at room temperature. Density measurements have been done to correlate the obtained results. Using the experimental data of density measurements, the basic physical parameters, such as mean atomic volume, compactness, average coordination number etc., are evaluated for the synthesized glasses and the results are discussed as a function of glass composition. We have also determined the phonon mean free path (τ) using the experimental value of effective thermal diffusivity. The composition dependence of the thermal transport properties of aforesaid glassy system has also been discussed.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Wuttig M, Yamada N (2007) Phase-change materials for rewriteable data storage. Nat Mater 6:824CrossRef Wuttig M, Yamada N (2007) Phase-change materials for rewriteable data storage. Nat Mater 6:824CrossRef
2.
Zurück zum Zitat Satoh I, Yamada N (2001) DVD-RAM for all audio/ vedio, PC, and network applications. Proc SPIE 4085:283CrossRef Satoh I, Yamada N (2001) DVD-RAM for all audio/ vedio, PC, and network applications. Proc SPIE 4085:283CrossRef
3.
Zurück zum Zitat Borg HJ, van Schijndel M, Rijpers JCN, Lankhorst MHR, Zhou G, Dekker MJ, Ubbens IPD, Kuijper M (2001) Phase-change media for high-numerical-aperture and blue-wavelength recording. Jpn J Appl Phys Part 1(40):1592CrossRef Borg HJ, van Schijndel M, Rijpers JCN, Lankhorst MHR, Zhou G, Dekker MJ, Ubbens IPD, Kuijper M (2001) Phase-change media for high-numerical-aperture and blue-wavelength recording. Jpn J Appl Phys Part 1(40):1592CrossRef
4.
Zurück zum Zitat Oomachi N, Ashida S, Nakamura N, Yusu K, Ichihara K (2002) Recording characteristics of Ge doped eutectic SbTe phase change discs with various compositions and its potential for high density recording. Jpn J Appl Phys Part 1(41):1695CrossRef Oomachi N, Ashida S, Nakamura N, Yusu K, Ichihara K (2002) Recording characteristics of Ge doped eutectic SbTe phase change discs with various compositions and its potential for high density recording. Jpn J Appl Phys Part 1(41):1695CrossRef
5.
Zurück zum Zitat Hellmig J, Mijiritskii AV, Borg HJ, Musialkova K, Vromans P (2003) Dual-layer Blu-ray disc based on fast-growth phase-change materials. Jpn J Appl Phys Part 1(42):848CrossRef Hellmig J, Mijiritskii AV, Borg HJ, Musialkova K, Vromans P (2003) Dual-layer Blu-ray disc based on fast-growth phase-change materials. Jpn J Appl Phys Part 1(42):848CrossRef
6.
Zurück zum Zitat Seddon AB, Laine MJ (1997) Chalcogenide glasses for acousto-optic devices. II. As–Ge–Se systems. J Non Cryst Solids 213 & 214:168CrossRef Seddon AB, Laine MJ (1997) Chalcogenide glasses for acousto-optic devices. II. As–Ge–Se systems. J Non Cryst Solids 213 & 214:168CrossRef
7.
Zurück zum Zitat Abe K, Takebe H, Morinaga K (1997) Preparation and properties of Ge–Ga–S glasses for laser hosts. J Non Cryst Solids 212:143CrossRef Abe K, Takebe H, Morinaga K (1997) Preparation and properties of Ge–Ga–S glasses for laser hosts. J Non Cryst Solids 212:143CrossRef
8.
Zurück zum Zitat Simons DR, Faber AJ, De Waal H (1995) GeS x glass for Pr3+-doped fiber amplifiers at 1.3 μm. J Non Cryst Solids 185:283CrossRef Simons DR, Faber AJ, De Waal H (1995) GeS x glass for Pr3+-doped fiber amplifiers at 1.3 μm. J Non Cryst Solids 185:283CrossRef
9.
10.
Zurück zum Zitat Ling Z, Ling H, Cheng Shan Z (1995) New chalcohalide glasses from the Sb2S3–MXn system. J Non Cryst Solids 184:1CrossRef Ling Z, Ling H, Cheng Shan Z (1995) New chalcohalide glasses from the Sb2S3–MXn system. J Non Cryst Solids 184:1CrossRef
11.
Zurück zum Zitat Mitsa AV, Mitsa VM, Uhrin AM (2005) Modelling of spectral characteristics of inhomogeneous (gradient) anti-reflective coating, based on chalcogenide glasses. Chalcogenide Lett 2:5–7 Mitsa AV, Mitsa VM, Uhrin AM (2005) Modelling of spectral characteristics of inhomogeneous (gradient) anti-reflective coating, based on chalcogenide glasses. Chalcogenide Lett 2:5–7
12.
Zurück zum Zitat Cable M, Parker JM (eds) (1992) High-performance glasses. Blackie, Glasgow Cable M, Parker JM (eds) (1992) High-performance glasses. Blackie, Glasgow
13.
Zurück zum Zitat Ovshinsky SR (1968) Reversible electrical switching phenomena in disordered structures. Phys Rev Lett 21:1450–1453CrossRef Ovshinsky SR (1968) Reversible electrical switching phenomena in disordered structures. Phys Rev Lett 21:1450–1453CrossRef
14.
Zurück zum Zitat Horie M, Ohno T, Nobukuni N, Kioyo K, Hahizume T (2001) Material characterization and application of eutectic SbTe-based phase-change optical recording media. Tech Dig 37: ODS2001 MC1 Horie M, Ohno T, Nobukuni N, Kioyo K, Hahizume T (2001) Material characterization and application of eutectic SbTe-based phase-change optical recording media. Tech Dig 37: ODS2001 MC1
15.
Zurück zum Zitat Akiyama T, Uno M, Kitaura H, Narumi K, Kojima R, Nishiuchi K, Yamada N (2001) Rewritable dual-layer phase-change optical disk utilizing a blue-violet laser. Jpn J Appl Phys 40:1598–1603CrossRef Akiyama T, Uno M, Kitaura H, Narumi K, Kojima R, Nishiuchi K, Yamada N (2001) Rewritable dual-layer phase-change optical disk utilizing a blue-violet laser. Jpn J Appl Phys 40:1598–1603CrossRef
16.
Zurück zum Zitat Ohta T (2001) Phase-change optical memory promotes the DVD optical disk. Adv Mater 3:609–626 Ohta T (2001) Phase-change optical memory promotes the DVD optical disk. Adv Mater 3:609–626
17.
Zurück zum Zitat Kumar H, Mehta N, Singh K (2011) Calorimetric studies of glass transition phenomenon in glassy Se80−x Te20Sn x alloys. Phys Scripta 83:065602(1–5)CrossRef Kumar H, Mehta N, Singh K (2011) Calorimetric studies of glass transition phenomenon in glassy Se80−x Te20Sn x alloys. Phys Scripta 83:065602(1–5)CrossRef
18.
Zurück zum Zitat Sharma I, Tripathi SK, Barman PB (2008) Correlation between the physical and optical properties of the a-Ge–Se–In–Bi system. Philos Mag 88:3081–3092CrossRef Sharma I, Tripathi SK, Barman PB (2008) Correlation between the physical and optical properties of the a-Ge–Se–In–Bi system. Philos Mag 88:3081–3092CrossRef
19.
Zurück zum Zitat Modgil V, Kaistha A, Rangra VS (2013) Structural study of the quaternary Se68Te19−xSn13Bi x (x = 8, 9, 10, 11, 12) chalcogenide crystals through X-ray diffraction. Adv Appl Sci Res 4:254–263 Modgil V, Kaistha A, Rangra VS (2013) Structural study of the quaternary Se68Te19−xSn13Bi x (x = 8, 9, 10, 11, 12) chalcogenide crystals through X-ray diffraction. Adv Appl Sci Res 4:254–263
20.
Zurück zum Zitat Kumar A, Barman PB, Sharma R (2013) Crystallization kinetics of Ag-doped Se–Bi–Te chalcogenide glasses. J Therm Anal Calorim 114:1003–1013CrossRef Kumar A, Barman PB, Sharma R (2013) Crystallization kinetics of Ag-doped Se–Bi–Te chalcogenide glasses. J Therm Anal Calorim 114:1003–1013CrossRef
21.
Zurück zum Zitat El-Samanoudy MM (2002) Alternating-current conductivity and dielectric properties of Ge25Sb15−x Bi x S60 bulk and thin film glasses. J Phys Condens Matter 14:1199–1212CrossRef El-Samanoudy MM (2002) Alternating-current conductivity and dielectric properties of Ge25Sb15−x Bi x S60 bulk and thin film glasses. J Phys Condens Matter 14:1199–1212CrossRef
22.
Zurück zum Zitat Gustafsson SE (1991) Transient plane source techniques for thermal conductivity and thermal diffusivity measurements of solid materials. Rev Sci Instrum 62:797–804CrossRef Gustafsson SE (1991) Transient plane source techniques for thermal conductivity and thermal diffusivity measurements of solid materials. Rev Sci Instrum 62:797–804CrossRef
23.
Zurück zum Zitat Sharma A, Kumar H, Mehta N (2013) Calorimetric study of specific heat in glassy Se–Te–Sn–Bi system using MDSC technique: effect of Bi incorporation. Phase Transit 86:1–9CrossRef Sharma A, Kumar H, Mehta N (2013) Calorimetric study of specific heat in glassy Se–Te–Sn–Bi system using MDSC technique: effect of Bi incorporation. Phase Transit 86:1–9CrossRef
24.
Zurück zum Zitat Singhal V, Litke PJ, Black AF, Garimella SV (2005) An experimentally validated thermo-mechanical model for the prediction of thermal contact conductance. Int J Heat Mass Transf 48:5446–5459CrossRef Singhal V, Litke PJ, Black AF, Garimella SV (2005) An experimentally validated thermo-mechanical model for the prediction of thermal contact conductance. Int J Heat Mass Transf 48:5446–5459CrossRef
25.
Zurück zum Zitat Wolff EG, Schneider DA (1998) Prediction of thermal contact resistance between polished surfaces. Int J Heat Mass Transf 41:3469–3482CrossRef Wolff EG, Schneider DA (1998) Prediction of thermal contact resistance between polished surfaces. Int J Heat Mass Transf 41:3469–3482CrossRef
26.
Zurück zum Zitat Banhart J, Bellmann D, Clemens H (2001) Investigation of metal foam formation by microscopy and ultra small-angle neutron scattering. Acta Mater 49:3409–3420CrossRef Banhart J, Bellmann D, Clemens H (2001) Investigation of metal foam formation by microscopy and ultra small-angle neutron scattering. Acta Mater 49:3409–3420CrossRef
27.
Zurück zum Zitat Log T, Gustafsson SE (1995) Transient plane source (TPS) technique for measuring thermal transport properties of building materials. Fire Mater 19:43–49CrossRef Log T, Gustafsson SE (1995) Transient plane source (TPS) technique for measuring thermal transport properties of building materials. Fire Mater 19:43–49CrossRef
28.
Zurück zum Zitat Gustavsson M, Karawacki E, Gustafsson SE (1994) Thermal conductivity, thermal diffusivity and specific heat of thin samples from transient measurements with hot-disk sensors. Rev Sci Instrum 65:3856–3859CrossRef Gustavsson M, Karawacki E, Gustafsson SE (1994) Thermal conductivity, thermal diffusivity and specific heat of thin samples from transient measurements with hot-disk sensors. Rev Sci Instrum 65:3856–3859CrossRef
29.
Zurück zum Zitat Sreeram AN, Swiler DR, Varshneya AK (1991) Gibbs-DiMarzio equation to describe the glass transition temperature trends in multi-component chalcogenide glasses. J Non Cryst Solids 127:287–297CrossRef Sreeram AN, Swiler DR, Varshneya AK (1991) Gibbs-DiMarzio equation to describe the glass transition temperature trends in multi-component chalcogenide glasses. J Non Cryst Solids 127:287–297CrossRef
30.
Zurück zum Zitat Mott NF, Davis EA (1971) Electronic processes in non-crystalline materials. Clarendon, Oxford, p 37 Mott NF, Davis EA (1971) Electronic processes in non-crystalline materials. Clarendon, Oxford, p 37
31.
Zurück zum Zitat Kumar H, Mehta N (2013) Kinematical studies of thermal crystallization in glassy Se78−x Te20Sn2Bi x (0 ≤ x ≤ 6) alloys. J Adv Phys 2:163–169CrossRef Kumar H, Mehta N (2013) Kinematical studies of thermal crystallization in glassy Se78−x Te20Sn2Bi x (0 ≤ x ≤ 6) alloys. J Adv Phys 2:163–169CrossRef
32.
Zurück zum Zitat (1979) Properties of the elements and inorganic compounds. In: West RC (ed) CRC handbook of chemistry and physics, 60th edn. CRC Press, Inc., Florida (1979) Properties of the elements and inorganic compounds. In: West RC (ed) CRC handbook of chemistry and physics, 60th edn. CRC Press, Inc., Florida
33.
Zurück zum Zitat Velinov T, Gateshki M (1997) Thermal effusivity of Ge–As–Se(S) glasses. Phys Rev B 55:11014–11017CrossRef Velinov T, Gateshki M (1997) Thermal effusivity of Ge–As–Se(S) glasses. Phys Rev B 55:11014–11017CrossRef
34.
Zurück zum Zitat Savova E, Skordeva ER, Vateva E (1994) The topological phase transition in some Ge–Sb–S glasses and thin films. J Phys Chem Solids 55:575–758CrossRef Savova E, Skordeva ER, Vateva E (1994) The topological phase transition in some Ge–Sb–S glasses and thin films. J Phys Chem Solids 55:575–758CrossRef
35.
Zurück zum Zitat Skordeva ER, Arsova DD (1995) Topological phase transition in ternary chalcogenide films. J Non Cryst Solids 192 & 193:665–668CrossRef Skordeva ER, Arsova DD (1995) Topological phase transition in ternary chalcogenide films. J Non Cryst Solids 192 & 193:665–668CrossRef
36.
Zurück zum Zitat Tichy L, Ticha H (1995) Covalent bond approach to the glass-transition temperature of chalcogenide glasses. J Non Cryst Solids 189:141–146CrossRef Tichy L, Ticha H (1995) Covalent bond approach to the glass-transition temperature of chalcogenide glasses. J Non Cryst Solids 189:141–146CrossRef
37.
Zurück zum Zitat Ioffe AF, Regel AR (1960) Non-crystalline, amorphous and liquid electronic semiconductors. Prog Semicond 4:237–291 Ioffe AF, Regel AR (1960) Non-crystalline, amorphous and liquid electronic semiconductors. Prog Semicond 4:237–291
38.
Zurück zum Zitat Phillips JC (1979) Topology of covalent non-crystalline solids I: short-range order in chalcogenide alloys. J Non Cryst Solids 34:153–181CrossRef Phillips JC (1979) Topology of covalent non-crystalline solids I: short-range order in chalcogenide alloys. J Non Cryst Solids 34:153–181CrossRef
39.
Zurück zum Zitat Fouad SS, Fayek SA, Ali MH (1998) Physical evolution and glass forming tendency of Ge1−x Sn x Se2.5 amorphous system. Vacuum 49:25–30CrossRef Fouad SS, Fayek SA, Ali MH (1998) Physical evolution and glass forming tendency of Ge1−x Sn x Se2.5 amorphous system. Vacuum 49:25–30CrossRef
40.
Zurück zum Zitat Tichy L, Ticha H (1994) On the chemical threshold in chalcogenide glasses. Mater Lett 21:313–319CrossRef Tichy L, Ticha H (1994) On the chemical threshold in chalcogenide glasses. Mater Lett 21:313–319CrossRef
41.
Zurück zum Zitat Jozef B, Stanford O, Mahadevan S, Gridhar A, Singh AK (1985) Chemical bond approach to the structures of chalcogenide glasses with reversible switching properties. J Non Cryst Solids 74:75–84CrossRef Jozef B, Stanford O, Mahadevan S, Gridhar A, Singh AK (1985) Chemical bond approach to the structures of chalcogenide glasses with reversible switching properties. J Non Cryst Solids 74:75–84CrossRef
42.
Zurück zum Zitat Rao KJ, Mohan R (1981) Chemical bond approach to determining conductivity band gaps in amorphous chalcogenides and pnictides. Solid State Commun 39:1065–1068CrossRef Rao KJ, Mohan R (1981) Chemical bond approach to determining conductivity band gaps in amorphous chalcogenides and pnictides. Solid State Commun 39:1065–1068CrossRef
43.
Zurück zum Zitat Aniya M (1995) Chemical scaling of the ionic conductivity in AgI–Ag2O–M x O y glasses. Solid State Ionics 79:259–263CrossRef Aniya M (1995) Chemical scaling of the ionic conductivity in AgI–Ag2O–M x O y glasses. Solid State Ionics 79:259–263CrossRef
Metadaten
Titel
Composition dependence of some thermo-physical properties of multi-component Se78−x Te20Sn2Bi x (0 ≤ x ≤ 6) chalcogenide glasses
verfasst von
A. Sharma
N. Mehta
Publikationsdatum
01.01.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 1/2015
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-014-8580-x

Weitere Artikel der Ausgabe 1/2015

Journal of Materials Science 1/2015 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.