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2011 | OriginalPaper | Buchkapitel

19. Conceptual Models for Sorption Under Batch Conditions

verfasst von : Vyacheslav G. Rumynin

Erschienen in: Subsurface Solute Transport Models and Case Histories

Verlag: Springer Netherlands

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Abstract

In equilibrium, the amount of a dissolved component, N, adsorbed on soil or aquifer material and the concentration of this component in the liquid phase, C, at a given temperature and pressure satisfy a unique relationship N = f(C), referred to as the (single-component) sorption isotherm (model). Empirical coefficients of the sorption isotherms are determined by the energy of the different adsorption sites and the nature of liquid/solid interactions (Venitcianov and Rubinshtein 1983). Under certain conditions, sorption processes are only partially reversible, so the desorption parameters may differ, in one direction or another, from the sorption parameters. This is a manifestation of sorption hysteresis (Sect. 19.1.3).

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Titel: Conceptual Models for Sorption Under Batch Conditions
verfasst von: Vyacheslav G. Rumynin
Verlag: Springer Netherlands
Buch: Subsurface Solute Transport Models and Case Histories
Print ISBN: 978-94-007-1305-5

Electronic ISBN: 978-94-007-1306-2

Copyright-Jahr: 2011
DOI: https://doi.org/10.1007/978-94-007-1306-2_19