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Journal of Materials Science
Erschienen in: Journal of Materials Science 19/2018

22.06.2018 | Chemical routes to materials

Controllable synthesis of magnetic Fe3O4 encapsulated semimetal Bi nanospheres with excellent stability and catalytic activity

verfasst von: Wei Wei, Wei Sun, Huihui Hu, Zhifeng Jiang, Lirong Ma, Jimin Xie

Erschienen in: Journal of Materials Science | Ausgabe 19/2018

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Abstract

Novel core–shell magnetic Bi@Fe3O4 nanostructures with excellent stability and catalytic activity were prepared by depositing magnetic Fe3O4 onto the surface of semimetal Bi nanospheres. X% Bi@Fe3O4 nanocomposites were prepared with proportions of 5, 15, 30, 50% by varying the content of the added element Bi. The nanocomposites were characterized by XRD, TEM, EDS, XPS, BET, and UV–Vis DRS. The results of the experiments indicated that the diameters of the nanospheres were controlled within approximately 100–300 nm. With increasing of Bi content, the size of the nanosphere was more uniform and the surface smoother. The 30% Bi@Fe3O4 nanocomposite showed the highest photocatalytic activity based on the degradation of rhodamine B under visible light irradiation. Moreover, Bi@Fe3O4 could be separated and collected easily using an external magnetic field. The catalyst retained its high activity after four photoreaction cycles. Given the excellent stability and catalytic activity of the Bi@Fe3O4 nanocomposite, it displays high potential for a broad range of applications.
Vorheriger Artikel Low-temperature treatment for preservation and separation of graphene dispersions
Nächster Artikel Reversible ratiometric silver ion and pH probe constructed from a quinoline-containing diphenylsulfone derivative with AIEE effect

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Literatur
1.
Liu Y, Wang R, Yang Z, Du H, Jiang Y, Shen C, Liang K, Xu AW (2015) Enhanced visible-light photocatalytic activity of Z-scheme graphitic carbon nitride/oxygen vacancy-rich zinc oxide hybrid photocatalysts. Chin J Catal 36:2135–2144CrossRef
2.
Yu W, Xu D, Peng T (2015) Enhanced photocatalytic activity of gC3N4 for selective CO2 reduction to CH3OH via facile coupling of ZnO: a direct Z-scheme mechanism. J Mater Chem A 3:19936–19947CrossRef
3.
Zhuang L, Li P, Liu C, Yang J, Wang M, Wang L (2014) A highly efficient and recyclable Fe3O4 magnetic nanoparticle immobilized palladium catalyst for the direct C-2 arylation of indoles with arylboronic acids. Catal Sci Technol 4:1979–1988CrossRef
4.
Shiri L, Zarei S, Kazemi M, Sheikh D (2018) Sulfuric acid heterogenized on magnetic Fe3O4 nanoparticles: a new and efficient magnetically reusable catalyst for condensation reactions. Appl Organomet Ch 32
5.
Zhang X, Li P, Ji Y, Zhang L, Wang L (2011) An efficient and recyclable magnetic-nanoparticle-supported palladium catalyst for the suzuki coupling reactions of organoboronic acids with alkynyl bromides. Synthesis 2011:2975–2983CrossRef
6.
Zhang L, Li P, Li H, Wang L (2012) A recyclable magnetic nanoparticles supported palladium catalyst for the Hiyama reaction of aryltrialkoxysilanes with aryl halides. Catal Sci Technol 2:1859–1864CrossRef
7.
Shiri L, Ghorbani-Choghamarani A, Kazemi M (2017) Synthesis and characterization of tribenzyl ammonium–tribromide supported on magnetic Fe3O4 nanoparticles: a robust magnetically recoverable catalyst for the oxidative coupling of thiols and oxidation of sulfides. Res Chem Intermed 43:2707–2724CrossRef
8.
Tian S, Tu Y, Chen D, Chen X, Xiong Y (2011) Degradation of acid orange II at neutral pH using Fe2(MoO4)3 as a heterogeneous Fenton-like catalyst. Chem Eng J 169:31–37CrossRef
9.
10.
Shiri L, Ghorbani-Choghamarani A, Kazemi M (2016) Sulfides synthesis: nanocatalysts in C–S cross-coupling reactions. Aust J Chem 69:585–600CrossRef
11.
Shiri L, Ghorbani-Choghamarani A, Kazemi M (2017) S–S bond formation: nanocatalysts in the oxidative coupling of thiols. Aust J Chem 70:9–25CrossRef
12.
13.
Ge Y, Xiang Y, He Y, Ji M, Song G (2016) Preparation of Zn–TiO2/RH/Fe3O4 composite material and its photocatalytic degradation for the dyes in wastewater. Desalin Water Treat 57:9837–9844CrossRef
14.
Chin K, Chong G, Poh C, Van L, Sow C, Lin J, Wee A (2007) Large-scale synthesis of Fe3O4 nanosheets at low temperature. J Phys Chem C 111:9136–9141CrossRef
15.
Zhang D, Liu Z, Han S, Li C, Lei B, Stewart M, Touret J, Zhou C (2004) Magnetite (Fe3O4) core–shell nanowires: synthesis and magnetoresistance. Nano Lett 4:2151–2155CrossRef
16.
Lu A, Salabas E, Schüth F (2007) Magnetic nanoparticles: synthesis, protection, functionalization, and application. Angew Chem Int Ed 46:1222–1244CrossRef
17.
Liu X, Hu Q, Zhang X, Fang Z, Wang Q (2008) Generalized and facile synthesis of Fe3O4/MS (M = Zn, Cd, Hg, Pb Co, and Ni) Nanocomposites. J Phys Chem C 112:12728–12735CrossRef
18.
Zhang D, Gao G, Ma W, Zhu J, Qiu G, Liu X (2013) Facile synthesis and properties of bifunctional magnetic-optical Fe3O4@ ZnS nanocomposites with core-shell structure. Appl Mech Mater Trans Tech Publ 320:92–98
19.
Wang J, Song D, Zhang H, Zhang G, Jin Y, Zhang H, Zhou H, Sun Y (2013) Studies of Fe3O4/Ag/Au composites for immunoassay based on surface plasmon resonance biosensor. Colloid Surface B 102:165–170CrossRef
20.
Rajamani A, Jothi S, Kumar M, Srikaanth S, Singe M, Otero-Irurueta G, Ramasamy D, Datta M, Rangarajan M (2016) Effects of additives on kinetics, morphologies and lead-sensing property of electrodeposited bismuth films. J Phys Chem C 120:22398–22406CrossRef
21.
Shao Y, Gu M, Li X, Nie Z, Zhuo P, Li G, Liu T, Xiao J, Cheng Y, Wang C, Zhang J, Liu J (2013) Highly reversible Mg insertion in nanostructured Bi for Mg ion batteries. Nano Lett 14:255–260CrossRef
22.
Zhang Q, Zhou Y, Wang F, Dong F, Li W, Li H, Patzke G (2014) From semiconductors to semimetals: bismuth as a photocatalyst for NO oxidation in air. J Mater Chem A 2:11065–11072CrossRef
23.
Lin YM, Sun X, Dresselhaus M (2000) Theoretical investigation of thermoelectric transport properties of cylindrical Bi nanowires. Phys Rev B 62:4610CrossRef
24.
Kim J, Shim W, Lee W (2015) Bismuth nanowire thermoelectrics. J Phys Chem C 3:11999–12013
25.
Xia F, Xu X, Li X, Zhang L, Zhang L, Qiu H, Wang W, Liu Y, Gao J (2014) Preparation of bismuth nanoparticles in aqueous solution and its catalytic performance for the reduction of 4-nitrophenol. Ind Eng Chem Res 53:10576–10582CrossRef
26.
Roy B, Chattopadhyay A, Samadder A, Khuda-Bukhsh A (2016) Target synthesis of biocompatible spherical bismuth sulphide nanoparticles for biological application. J Sol–Gel Sci Technol 77:446–452CrossRef
27.
Gao Y, Niu H, Zeng C, Chen Q (2003) Preparation and characterization of single-crystalline bismuth nanowires by a low-temperature solvothermal process. Chem Phys Lett 367:141–144CrossRef
28.
Wang Y, Hong B, Kim K (2005) Size control of semimetal bismuth nanoparticles and the UV–visible and IR absorption spectra. J Phys Chem B 109:7067–7072CrossRef
29.
Li J, Fan H, Chen J, Liu L (2009) Synthesis and characterization of poly (vinyl pyrrolidone)-capped bismuth nanospheres. Colloid Surface A 340:66–69CrossRef
30.
Shylesh S, Schünemann V, Thiel W (2010) Magnetically separable nanocatalysts: bridges between homogeneous and heterogeneous catalysis. Angew Chem Int Ed 49:3428–3459CrossRef
31.
Wang J, Liu J, Chao D, Yan J, Lin J, Shen Z (2014) Self-assembly of honeycomb-like MoS2 nanoarchitectures anchored into graphene foam for enhanced lithium–ion storage. Adv Mater 26:7162–7169CrossRef
32.
Zhang C, Chen Z, Guo Z, Lou X (2013) Additive-free synthesis of 3D porous V2O5 hierarchical microspheres with enhanced lithium storage properties. Energ Environ Sci 6:974–978CrossRef
33.
Ge J, Zhang Q, Zhang T, Yin Y (2008) Core–satellite nanocomposite catalysts protected by a porous silica shell: controllable reactivity, high stability, and magnetic recyclability. Angew Chem 120:9056–9060CrossRef
34.
Dahlberg KA, Schwank JW (2012) Synthesis of Ni@ SiO2 nanotube particles in a water-in-oil microemulsion template. Chem Mater 24:2635–2644CrossRef
35.
Li W, Yang J, Wu Z, Wang J, Li B, Feng S, Deng Y, Zhang F, Zhao D (2012) A versatile kinetics-controlled coating method to construct uniform porous TiO2 shells for multifunctional core–shell structures. J Am Chem Soc 134:11864–11867CrossRef
36.
Lee S, Hoffman D, Jacobson A, Randall Lee T (2013) Transparent, homogeneous tin oxide (SnO2) thin films containing SnO2-coated gold nanoparticles. Chem Mater 25:4697–4702CrossRef
37.
38.
Can K, Ozmen M, Ersoz M (2009) Immobilization of albumin on aminosilane modified superparamagnetic magnetite nanoparticles and its characterization. Colloid Surface B 71:154–159CrossRef
39.
Hasanpour A, Gheisari M, Amighian J, Niyaifar M, Darabi M (2013) Dielectric behavior of Bi–Fe3O4 nanocomposite and Fe3O4 nanoparticles prepared via mechanochemical processing. J Magn Magn Mater 346:38–43CrossRef
40.
Berger P, Adelman NB, Beckman KJ, Campbell DJ, Ellis AB (1999) Preparation and properties of an aqueous ferrofluid. J Chem Educ 76:943CrossRef
41.
Wang X, Xia F, Li X, Xu X, Wang H, Yang N, Gao J (2015) Fabrication of Bi-Fe3O4@RGO hybrids and their catalytic performance for the reduction of 4-nitrophenol. J Nanopart Res 17:436CrossRef
42.
Xu X, Shen X, Zhu G, Jing L, Liu X, Chen K (2012) Magnetically recoverable Bi2WO6–Fe3O4 composite photocatalysts: fabrication and photocatalytic activity. Chem Eng J 200:521–531CrossRef
43.
Ye H, Lin H, Cao J, Chen S, Chen Y (2015) Enhanced visible light photocatalytic activity and mechanism of BiPO4 nanorods modified with AgI nanoparticles. J Mol Catal A-Chem 397:85–92CrossRef
44.
Han Q, Liu Z, Xu Y, Zhang H (2007) Growth and properties of single-crystalline λ-Fe2O3 nanowires. J Phys Chem C 111:5034–5038CrossRef
45.
Guo JF, Ma B, Yin A, Fan K, Dai W (2011) Photodegradation of rhodamine B and 4-chlorophenol using plasmonic photocatalyst of Ag–AgI/Fe3O4@SiO2 magnetic nanoparticle under visible light irradiation. Appl Catal B-Environ 101:580–586CrossRef
46.
Mobinikhaledi A, Foroughifar N, Khajeh-Amiri A (2016) N-Propylcarbamothioyl benzamide complex of Bi(III) supported on superparamagnetic Fe3O4/SiO2 nanoparticles as a highly efficient and magnetically recoverable heterogeneous nanocatalyst for the one-pot synthesis of 3,4-dihydropyrimidin-2(1H)-ones/thiones (DHPMs) via the Biginelli reaction. React Kinet Mech Catal 117:59–75CrossRef
47.
Yan L, Gu Z, Zheng X, Zhang C, Li X, Zhao L, Zhao Y (2017) Elemental bismuth-graphene heterostructures for photocatalysis from ultraviolet to infrared light. ACS Catal 7:7043–7050CrossRef
48.
Cai K, Liu Y, Xu Y, Zhou H, Zhang L, Cui Y (2017) One-pot synthesis of Bi/Fe3O4 and its catalytic performances for 4-nitrophenol reduction. BCREC 12:89–95CrossRef
49.
Qin F, Wang R, Li G, Tian F, Zhao H, Chen R (2013) Highly efficient photocatalytic reduction of Cr(VI) by bismuth hollow nanospheres. Catal Commun 42:14–19CrossRef
50.
Dong F, Li Q, Sun Y, Ho W (2014) Noble metal-like behavior of plasmonic Bi particles as a cocatalyst deposited on (BiO)2CO3 microspheres for efficient visible light photocatalysis. ACS Catal 4:4341–4350CrossRef
Metadaten
Titel
Controllable synthesis of magnetic Fe3O4 encapsulated semimetal Bi nanospheres with excellent stability and catalytic activity
verfasst von
Wei Wei
Wei Sun
Huihui Hu
Zhifeng Jiang
Lirong Ma
Jimin Xie
Publikationsdatum
22.06.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 19/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2585-9

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