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2020 | OriginalPaper | Buchkapitel

41. Coordination Compounds of Calcium Ions (II) with the Biogenic Amino Acids: Their Stability, Kinetic and Thermodynamic Characteristics of the Formation

verfasst von : Ivan A. Tomashevskiy, Olga A. Golovanova, Svetlana V. Anisina

Erschienen in: Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature

Verlag: Springer International Publishing

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Abstract

The coordination compounds of calcium with a number of vital amino acids were studied by using the potentiometric titration with the application of mathematical methods of data processing. The ability of calcium ions as a complexing agent to coordinate amino acids as ligands has been shown. The regularity in the complexation of amino acids of various structures has been established. The stability constants of the coordination compounds were determined and their kinetic stability was estimated in aqueous solutions at 298 K.

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Vorheriges Kapitel Carbon Isotope Ratios in the Apatite-Protein Composites of Conodont Elements—Palaeobiological Proxy

Nächstes Kapitel Landscape Settings and Mineralogy of Some Geophagic Clay Occurrences in South Africa

Aghasyan PK, Nikolaeva ER (1986). Fundamentals of electrochemical analysis methods (potentiometric method) (In Russian)

Amerkhanova ShK, Golovanova OA, Shlyapov RM (2015) The relationship between the thermodynamic characteristics of the formation of calcium-containing substrate and sorption properties with respect to copper (II) glycinates. Her Omsk Univ 2:45–49 (In Russian)

Assimos DG, Holmes RP (2000) Role of diet in the therapy of urolithiasis. Urol Clin North Am 27:255–268CrossRef

Bailly GG, Norman RW, Thompson C (2000) Effects of dietary fat on the urinary risk factors of calcium stone disease. Urology 1:40–44CrossRef

Bak M, Thomsen JK, Jakobsen HJ, Petersen SE, Petersen TE, Nielsen NC (2000) Solid-state ¹³C and ³¹P NMR analysis of urinary stones. J Urol 164:856–863CrossRef

Batinic D, Milosevic D, Blau N, Konjevoda P, Stambuk N, Barbaric V, Subat-Dezulovic M, Votava-Raic A, Nizic L, Vrljicak K (2000) Value of the urinary stone promoters/inhibitors ratios in the estimation of the risk of urolithiasis. J Chem Inf Comput Sci 3:607–610CrossRef

Bolotin SN, Bukov NN, Volynkin VA (2008). The coordination chemistry of natural amino acids. Publishing House LCI, p 240 (in Russian)

Bottari E, Festa M (1996) The behaviour of asparagine as a ligand for cations. J Ann Chim 86:133

Bottari E, Porto R (1985) Serine as a ligand complex formation with calcium (II). J Ann Chim 75:393

Brown SA, Munver R, Delvecchio FC, Kuo RL, Zhong P, Preminger GN (2000) Microdialysis assessment of shock wave lithotripsy-induced renal injury. J Urol 56(3):364–368CrossRef

Burger K, Sipos P, Veber M (1998) Formation microequilibria of proton, calcium and magnesium complexes of the γ-carboxyglutamate ion and related compounds J Inorg Chim Acta 4:233CrossRef

Daniele P, De Robertis A, De Stefano C (1985) On the possibility of determining the thermodynamic parameters for the formation of weak complexes using a simple model for the dependence on ionic strength of activity coefficients: Na⁺, K⁺, and Ca²⁺ complexes of low molecular weight ligands in aqueous solution. J Chem Soc Dalton Trans 11:2353CrossRef

De Robertis A, De Stefano C, Gianguzza A (1991) Salt effects on the protonation of 1-histidine and 1-aspartic acid: a complex formation model. J Thermochim Acta 177:39CrossRef

Dobrynina NA (2007) Bioneorganic chemistry. Moscow State University, Moscow, p 36 (in Russian)

Dyatlova NM, Temkina VY, Popov KI (1988) Complexons and Complexes of Metals. M.: Chemistry, pp 48–50 (in Russian)

Gerk SA, Golovanova OA (2011) Bone apatite of the person—features of a chemical structure at a pathology. J Butlerov Commun 3:123–132

Golovanova OA, Korolkov VV (2016) Study of phase formation regularities in supersaturated systems of calcium oxalate in the presence of additives on the model unit. J Butlerov Commun 9:105–114 (in Russian)

Golovanova OA, Korolkov VV (2017) Thermodynamic and kinetic patterns of crystallization of calcium oxalate in the presence of amino acids. J Crystallography 5:819 (in Russian)

Golovanova OA, Solodyankina AA (2017) The main characteristics of the nucleation process in the model solution of blood plasma. J Crystallogr Rep 2:342 (in Russian)CrossRef

Golovanova OA, Tsepayev SA (2012) Phase, element, amino acid, structural composition of nephroliths minerals. J Butlerov Commun 12:96–103 (in Russian)

Golovanova OA, Rosseeva EV, Frank-Kamenetskaya OV (2006) J Herald St. Petersburg State Univ 2:123–127 (in Russian)

Golovanova OA, Korol’kov VV, Kuimova MV (2017) Kinetic Characteristics of Crystallization in Prototypes of Biological Fluids. Biogenic-abiogenic interactions in natural and anthropogenic systems. In: IOP conference series: materials science and engineering, p 168

Khalil MM, Attia AE (2000) Potentiometric studies on the binary and ternary complexes. J Chem Eng Data 45:1108–1111CrossRef

Kozhomuratova ZS, Mironov YV, Shestopalov MA (2007) Cluster compounds [Ca(DMF)₆] [Mo₆Cl₁₄] and [{Ca(OPPh₃)₄} {Mo₆Cl₁₄}] cluster compounds: synthesis, crystal structure and properties. J Coord Chem 33:1–3 (in Russian)CrossRef

Kurochkin VY (2011). Thermodynamics of complexation of calcium ions with amino acids in aqueous solution. Dissertation, Ivanovo (in Russian)

Larina TA, Kuznetsova TA, Koroleva LYu (2006) The scientific proceedings of the research center of pedagogy and psychology. J Sci Notes Orel State Univ 7:135–138 (in Russian)

Malovskaya EA, Golovanova OA, Panova TV, Gerk SA, Osintsev VA (2013) Crystallization of calcium phosphates from prototypes of biological fluids on bone samples. J Butlerov Commun 10:21–28 (in Russian)

Martell AE (2006) Stability constants (log K1) of various metal chelates. Sequestarants in Foods

Nikolsky BP, Materova EA (1980) Ion-selective electrodes. L.: Chemistry, pp 240 (in Russian)

Perisic O, Fong S, Lynch DE, Bycroft M, Williams RL (1998) Crystal structure of a calcium-phospholipid binding domain from cytosolic phospholipase. J Biol Chem 3:1596–1604CrossRef

Posypayko VI, Kozyreva NA, Logacheva YP (1989) Chemical methods of analysis. M.: High School, pp 42–45 (in Russian)

Rey F, Antelo J, Arce F (1990) Equilibrium constants of metal amino acid complexes. J Polyhedron 5:665CrossRef

Rhilassi AEl, Mourabet M, Bennani-Ziatni M, Hamri REl, Taitai A (2016) J Saudi Chem Soc 20:632

Selifonova EI, Chernova RK (2012) Selective electrophoretic separation of ionic forms—amino acids. Proc Saratov Univ New Epis Ser: Chem Biol Ecol 3:25–32 (in Russian)

Siddique JA, Naqvi S (2002) Volumetric behavior on interactions of r-amino acids with sodium acetate, potassium acetate, and calcium acetate in aqueous solutions, vol 8. Department of Chemistry, Aligarh Muslim University, pp 2930–2934

Tas AC (2000) Synthesis of biomimetic Ca-hydroxyapatite powders at 37 C in synthetic body fluids. Biomaterials 21:1429CrossRef

Yatsimirsky KB (1976) Introduction to bioneorganic chemistry. K.: Publishing House of Science Dumka, p 144 (in Russian)

Titel: Coordination Compounds of Calcium Ions (II) with the Biogenic Amino Acids: Their Stability, Kinetic and Thermodynamic Characteristics of the Formation
verfasst von: Ivan A. Tomashevskiy
Olga A. Golovanova
Svetlana V. Anisina
Verlag: Springer International Publishing
Buch: Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature
Print ISBN: 978-3-030-21613-9

Electronic ISBN: 978-3-030-21614-6

Copyright-Jahr: 2020
DOI: https://doi.org/10.1007/978-3-030-21614-6_41