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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 19/2020

12.09.2020

Copper oxide nanosheets prepared by facile microplasma electrochemical technique with photocatalytic and bactericidal activities

verfasst von: Tariq Iqbal, Atique ur Rehman, M. A. Khan, M. Shafique, Pervaiz Ahmad, Hasan Mahmood, Muhammad Naeem, Javed Iqbal

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 19/2020

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Abstract

Copper oxide (CuO) nanostructures are synthesized via a simple and novel atmospheric pressure microplasma technique without using any surfactant. The effect of electrolyte concentration on structure, size, and morphology of CuO nanostructures has been investigated by X-ray diffraction (XRD), laser-induced breakdown spectroscopy (LIBS), scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR). The results revealed the formation of highly crystalline single phase CuO, exhibiting a monoclinic structure. SEM images have shown an interpenetrating self-assembled nanosheets (NS) with varying sizes. The energy bandgap of the samples is estimated between 2.0 and 2.73 eV. The antibacterial activity of CuO NS demonstrates significant bactericidal efficiency against gram-negative bacteria. In addition, these NS are checked for the degradation of organic dyes such as Rhodamine B and methyl orange under sunlight irradiation which showed significant degradation, indicating excellent photocatalytic activity. It has been found that CuO NS are promising material for pharmaceutical and biomedical applications because of its attractive photocatalytic and antibacterial properties.
Vorheriger Artikel Effect of annealing temperature on the structural, optical, magnetic and electrochemical properties of NiO thin films prepared by sol–gel spin coating
Nächster Artikel Excellent microwave absorption performance from matched magnetic-dielectric properties of LSMO@RGO Nanocomposites

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Literatur
1.
R.S. Devan, R.A. Patil, J.H. Lin, Y.R. Ma, One-dimensional metal-oxide nanostructures: recent developments in synthesis. Charact. Appl. Adv. Funct. Mater. 22, 3326–3370 (2012)
2.
Z. Chen, Z. Jiao, D. Pan, Z. Li, M. Wu, C.-H. Shek, C.L. Wu, J.K. Lai, Recent advances in manganese oxide nanocrystals: fabrication, characterization, and microstructure. Chem. Rev. 112, 3833–3855 (2012)
3.
Q. Zhang, K. Zhang, D. Xu, G. Yang, H. Huang, F. Nie, C. Liu, S. Yang, CuO nanostructures: synthesis, characterization, growth mechanisms, fundamental properties, and applications. Prog. Mater. Sci. 60, 208–337 (2014)
4.
Q.-X. Zeng, G.-C. Xu, L. Zhang, H. Lin, Y. Lv, D.-Z. Jia, Porous CuO nanofibers derived from a Cu-based coordination polymer as a photocatalyst for the degradation of rhodamine B. New J. Chem. 42, 7016–7024 (2018)
5.
M. Vaseem, A. Umar, Y. Hahn, D. Kim, K. Lee, J. Jang, J.S. Lee, Flower-shaped CuO nanostructures: structural, photocatalytic and XANES studies. Catal. Commun. 10, 11–16 (2008)
6.
H. Zheng, J.Z. Ou, M.S. Strano, R.B. Kaner, A. Mitchell, K. Kalantar-zadeh, Nanostructured tungsten oxide—properties, synthesis, and applications. Adv. Funct. Mater. 21, 2175–2196 (2011)
7.
Z.-Y. Zhou, N. Tian, J.-T. Li, I. Broadwell, S.-G. Sun, Nanomaterials of high surface energy with exceptional properties in catalysis and energy storage. Chem. Soc. Rev. 40, 4167–4185 (2011)
8.
G. Filipič, U. Cvelbar, Copper oxide nanowires: a review of growth. Nanotechnology 23, 194001 (2012)
9.
S.L. Candelaria, Y. Shao, W. Zhou, X. Li, J. Xiao, J.-G. Zhang, Y. Wang, J. Liu, J. Li, G. Cao, Nanostructured carbon for energy storage and conversion. Nano Energy 1, 195–220 (2012)
10.
M. Yang, J. He, X. Hu, C. Yan, Z. Cheng, Y. Zhao, G. Zuo, Copper oxide nanoparticle sensors for hydrogen cyanide detection: unprecedented selectivity and sensitivity. Sens. Actuators B: Chem. 155, 692–698 (2011)
11.
X. Gou, G. Wang, J. Yang, J. Park, D. Wexler, Chemical synthesis, characterisation and gas sensing performance of copper oxide nanoribbons. J. Mater. Chem. 18, 965–969 (2008)
12.
R. Sankar, P. Manikandan, V. Malarvizhi, T. Fathima, K.S. Shivashangari, V. Ravikumar, Green synthesis of colloidal copper oxide nanoparticles using Carica papaya and its application in photocatalytic dye degradation. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 121, 746–750 (2014)
13.
F. Teng, W. Yao, Y. Zheng, Y. Ma, Y. Teng, T. Xu, S. Liang, Y. Zhu, Synthesis of flower-like CuO nanostructures as a sensitive sensor for catalysis. Sens. Actuators B: Chem. 134, 761–768 (2008)
14.
Y. Li, S. Chang, X. Liu, J. Huang, J. Yin, G. Wang, D. Cao, Nanostructured CuO directly grown on copper foam and their supercapacitance performance. Electrochim. Acta 85, 393–398 (2012)
15.
Y. Zhu, C. Sow, J. Thong, Enhanced field emission from CuO nanowire arrays by in situ laser irradiation. J. Appl. Phys. 102, 114302 (2007)
16.
P. Shao, S. Deng, J. Chen, J. Chen, N. Xu, Study of field emission, electrical transport, and their correlation of individual single CuO nanowires. J. Appl. Phys. 109, 023710 (2011)
17.
A. Martínez-García, V.K. Vendra, S. Sunkara, P. Haldankar, J. Jasinski, M.K. Sunkara, Tungsten oxide-coated copper oxide nanowire arrays for enhanced activity and durability with photoelectrochemical water splitting. J. Mater. Chem. A 1, 15235–15241 (2013)
18.
J. Han, X. Zong, X. Zhou, C. Li, Cu2O/CuO photocathode with improved stability for photoelectrochemical water reduction. RSC Adv. 5, 10790–10794 (2015)
19.
W. Zhang, M. Li, Q. Wang, G. Chen, M. Kong, Z. Yang, S. Mann, Hierarchical self-assembly of microscale cog-like superstructures for enhanced performance in lithium-ion batteries. Adv. Funct. Mater. 21, 3516–3523 (2011)
20.
M. Umadevi, A.J. Christy, Synthesis, characterization and photocatalytic activity of CuO nanoflowers. Spectrochim. Acta Part A Mol. Biomol. Spectrosc. 109, 133–137 (2013)
21.
T. Oku, R. Motoyoshi, K. Fujimoto, T. Akiyama, B. Jeyadevan, J. Cuya, Structures and photovoltaic properties of copper oxides/fullerene solar cells. J. Phys. Chem. Solids 72, 1206–1211 (2011)
22.
T. Pandiyarajan, R. Udayabhaskar, S. Vignesh, R.A. James, B. Karthikeyan, Synthesis and concentration dependent antibacterial activities of CuO nanoflakes. Mater. Sci. Eng. C 33, 2020–2024 (2013)
23.
A. Ananth, S. Dharaneedharan, M.-S. Heo, Y.S. Mok, Copper oxide nanomaterials: synthesis, characterization and structure-specific antibacterial performance. Chem. Eng. J. 262, 179–188 (2015)
24.
Y. Wang, F. Yang, H. Zhang, X. Zi, X. Pan, F. Chen, W. Luo, J. Li, H. Zhu, Y. Hu, Cuprous oxide nanoparticles inhibit the growth and metastasis of melanoma by targeting mitochondria. Cell Death Dis 4, e783 (2013)
25.
A. Goswami, P. Raul, M. Purkait, Arsenic adsorption using copper (II) oxide nanoparticles. Chem. Eng. Res. Des. 90, 1387–1396 (2012)
26.
27.
A.K. Chatterjee, R. Chakraborty, T. Basu, Mechanism of antibacterial activity of copper nanoparticles. Nanotechnology 25, 135101 (2014)
28.
M.J. Hajipour, K.M. Fromm, A.A. Ashkarran, D.J. de Aberasturi, I.R. de Larramendi, T. Rojo, V. Serpooshan, W.J. Parak, M. Mahmoudi, Antibacterial properties of nanoparticles. Trends Biotechnol. 30, 499–511 (2012)
29.
H.-F. Zhai, A.-D. Li, J.-Z. Kong, X.-F. Li, J. Zhao, B.-L. Guo, J. Yin, Z.-S. Li, D. Wu, Preparation and visible-light photocatalytic properties of BiNbO4 and BiTaO4 by a citrate method. J. Solid State Chem. 202, 6–14 (2013)
30.
A. Bhattacharjee, M. Ahmaruzzaman, CuO nanostructures: facile synthesis and applications for enhanced photodegradation of organic compounds and reduction of p-nitrophenol from aqueous phase. RSC Adv. 6, 41348–41363 (2016)
31.
R. Katwal, H. Kaur, G. Sharma, M. Naushad, D. Pathania, Electrochemical synthesized copper oxide nanoparticles for enhanced photocatalytic and antimicrobial activity. J. Ind. Eng. Chem. 31, 173–184 (2015)
32.
G. Ren, D. Hu, E.W. Cheng, M.A. Vargas-Reus, P. Reip, R.P. Allaker, Characterisation of copper oxide nanoparticles for antimicrobial applications. Int. J. Antimicrob. Agents 33, 587–590 (2009)
33.
T. Ito, H. Yamaguchi, K. Okabe, T. Masumi, Single-crystal growth and characterization of Cu2O and CuO. J. Mater. Sci. 33, 3555–3566 (1998)
34.
M. Heinemann, B. Eifert, C. Heiliger, Band structure and phase stability of the copper oxides Cu2O, CuO, and Cu4O3. Phys. Rev. B 87, 115111 (2013)
35.
F. Bayansal, H. Çetinkara, S. Kahraman, H. Çakmak, H. Güder, Nano-structured CuO films prepared by simple solution methods: plate-like, needle-like and network-like architectures. Ceram. Int. 38, 1859–1866 (2012)
36.
H.-B. Jiang, L.-F. Pan, P.-F. Liu, W.-Q. Fang, H.-G. Yang, Synthesis of well-defined functional crystals by high temperature gas-phase reactions. Chin. Sci. Bull. 59, 2135–2143 (2014)
37.
J.P. Joshua, S. Krishnan, D. Raj, R. Uthrakumar, S. Laxmi, S. Das, Novel synthesis of Tenorite (CuO) nanoparticles by wet chemical method. Int. J. ChemTech Res. 6, 22–33 (2014)
38.
K. Becker, K. Schoenbach, J. Eden, Microplasmas and applications. J. Phys. D Appl. Phys. 39, R55 (2006)
39.
R.M. Sankaran, K.P. Giapis, M. Moselhy, K.H. Schoenbach, Argon excimer emission from high-pressure microdischarges in metal capillaries. Appl. Phys. Lett. 83, 4728–4730 (2003)
40.
S.-J. Park, J. Eden, 13–30 micron diameter microdischarge devices: atomic ion and molecular emission at above atmospheric pressures. Appl. Phys. Lett. 81, 4127–4129 (2002)
41.
P. Kurunczi, N. Abramzon, M. Figus, K. Becker, Measurement of rotational temperatures in high-pressure microhollow cathode (MHC) and capillary plasma electrode (CPE) discharges. acta physica slovaca 54, 115–124 (2004)
42.
C. Penache, M. Miclea, A. Bräuning-Demian, O. Hohn, S. Schössler, T. Jahnke, K. Niemax, H. Schmidt-Böcking, Characterization of a high-pressure microdischarge using diode laser atomic absorption spectroscopy. Plasma Sources Sci. Technol. 11, 476 (2002)
43.
A. Schutze, J.Y. Jeong, S.E. Babayan, J. Park, G.S. Selwyn, R.F. Hicks, The atmospheric-pressure plasma jet: a review and comparison to other plasma sources. IEEE Trans. Plasma Sci. 26, 1685–1694 (1998)
44.
T. Iqbal, M. Mukhtar, M. Khan, R. Khan, R. Zaman, H. Mahmood, M. Zaka-ul-Islam, Atmospheric pressure microplasma assisted growth of silver nanosheets and their inhibitory action against bacteria of clinical interest. Mater. Res. Express 3, 125019 (2016)
45.
T. Iqbal, A. Aziz, M. Khan, S. Andleeb, H. Mahmood, A.A. Khan, R. Khan, M. Shafique, M. Zaka-ul-Islam, Surfactant assisted synthesis of ZnO nanostructures using atmospheric pressure microplasma electrochemical process with antibacterial applications. Mater. Sci. Eng. B 228, 153–159 (2018)
46.
K. Chandrappa, T. Venkatesha, Electrochemical bulk synthesis and characterisation of hexagonal-shaped CuO nanoparticles. J. Exp. Nanosci. 8, 516–532 (2013)
47.
P.K. Diwakar, K.H. Loper, A.-M. Matiaske, D.W. Hahn, Laser-induced breakdown spectroscopy for analysis of micro and nanoparticles. J. Anal. At. Spectrom. 27, 1110–1119 (2012)
48.
R. Azimirad, S. Safa, Photocatalytic and antifungal activity of flower-like copper oxide nanostructures. Synth. React. Inorg. Met.-Org. Nano-Met. Chem. 44, 798–803 (2014)
49.
E.J. Hart, J. Boag, Absorption spectrum of the hydrated electron in water and in aqueous solutions. J. Am. Chem. Soc. 84, 4090–4095 (1962)
50.
J. Tauc, R. Grigorovici, A. Vancu, Optical properties and electronic structure of amorphous germanium. physica status solidi (b) 15, 627–637 (1966)
51.
T. Jiang, Y. Wang, D. Meng, D. Wang, One-step hydrothermal synthesis and enhanced photocatalytic performance of pine-needle-like Zn-doped CuO nanostructures. J. Mater. Sci.: Mater. Electron. 27, 12884–12890 (2016)
52.
N. Dhineshbabu, V. Rajendran, N. Nithyavathy, R. Vetumperumal, Study of structural and optical properties of cupric oxide nanoparticles. Appl. Nanosci. 6, 933–939 (2016)
53.
C. Yang, X. Su, J. Wang, X. Cao, S. Wang, L. Zhang, Facile microwave-assisted hydrothermal synthesis of varied-shaped CuO nanoparticles and their gas sensing properties. Sens. Actuators B: Chem. 185, 159–165 (2013)
54.
Y. Lu, X. Liu, K. Qiu, J. Cheng, W. Wang, H. Yan, C. Tang, J.-K. Kim, Y. Luo, Facile synthesis of graphene-like copper oxide nanofilms with enhanced electrochemical and photocatalytic properties in energy and environmental applications. ACS Appl. Mater. Interfaces. 7, 9682–9690 (2015)
55.
J.T. Kloprogge, L. Hickey, R.L. Frost, FT-Raman and FT-IR spectroscopic study of synthetic Mg/Zn/Al-hydrotalcites. J. Raman Spectrosc. 35, 967–974 (2004)
56.
57.
Y.-N. Chang, M. Zhang, L. Xia, J. Zhang, G. Xing, The toxic effects and mechanisms of CuO and ZnO nanoparticles. Materials 5, 2850–2871 (2012)
58.
G. Applerot, J. Lellouche, A. Lipovsky, Y. Nitzan, R. Lubart, A. Gedanken, E. Banin, Understanding the antibacterial mechanism of CuO nanoparticles: revealing the route of induced oxidative stress. Small 8, 3326–3337 (2012)
59.
O. Bondarenko, A. Ivask, A. Käkinen, A. Kahru, Sub-toxic effects of CuO nanoparticles on bacteria: kinetics, role of Cu ions and possible mechanisms of action. Environ. Pollut. 169, 81–89 (2012)
60.
K. Mageshwari, R. Sathyamoorthy, Flower-shaped CuO nanostructures: synthesis, characterization and antimicrobial activity. J. Mater. Sci. Technol. 29, 909–914 (2013)
61.
F. Nishino, M. Jeem, L. Zhang, K. Okamoto, S. Okabe, S. Watanabe, Formation of CuO nano-flowered surfaces via submerged photo-synthesis of crystallites and their antimicrobial activity. Sci. Rep. 7, 1063 (2017)
62.
T.A. Saleh, V.K. Gupta, Photo-catalyzed degradation of hazardous dye methyl orange by use of a composite catalyst consisting of multi-walled carbon nanotubes and titanium dioxide. J. Colloid Interface Sci. 371, 101–106 (2012)
63.
P. Nethravathi, M.P. Kumar, D. Suresh, K. Lingaraju, H. Rajanaika, H. Nagabhushana, S. Sharma, Tinospora cordifolia mediated facile green synthesis of cupric oxide nanoparticles and their photocatalytic, antioxidant and antibacterial properties. Mater. Sci. Semicond. Process. 33, 81–88 (2015)
Metadaten
Titel
Copper oxide nanosheets prepared by facile microplasma electrochemical technique with photocatalytic and bactericidal activities
verfasst von
Tariq Iqbal
Atique ur Rehman
M. A. Khan
M. Shafique
Pervaiz Ahmad
Hasan Mahmood
Muhammad Naeem
Javed Iqbal
Publikationsdatum
12.09.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 19/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-04219-4

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