Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Engineering and Performance
Erschienen in: Journal of Materials Engineering and Performance 12/2015

01.12.2015

Corrosion Investigations of Black Chromite Films on Zn and Zn-Co Coatings with Low Cobalt Content

verfasst von: Nikolai Boshkov, Neli Boshkova, Vasil Bachvarov, Miglena Peshova, Ludmil Lutov

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 12/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The corrosion resistance and protective ability of black-colored chromite (Cr3+ based) and chromium-free conversion films (CFs) on electrodeposited zinc and Zn-Co alloy coatings having low cobalt content in a neutral model medium of 3% NaCl solution have been investigated and characterized. Test methods such as polarization resistance measurements, scanning electron microscopy, EDS, x-ray diffraction analysis, and x-ray photoelectron spectroscopy analyses have been applied in order to scrutinize the actual protective characteristics of these films as well as to determine the composition of the corrosion products appearing as a result of the treatment in the corrosion medium. The experimental results revealed better protective characteristics, consequently superior performance of the electrodeposits with chromite films compared to these with chromium free or without any additional CF. The processes occurring on the sample’s surface during the immersion in the chemical conversion solutions as well as the influence of the H3PO4 in the course of the treatment are also commented on and discussed.
Vorheriger Artikel An Investigation into Hot Deformation Characteristics and Processing Maps of High-Strength Armor Steel
Nächster Artikel Investigation of the Microstructure and the Mechanical Properties of Cu-NiC Composite Produced by Accumulative Roll Bonding and Coating Processes

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
P. De Lima-Neto, A.N. Correia, P. Colares, P. Regilany, and W.S. Araujo, Corrosion Study of Electrodeposited Zn and Zn-Co Coatings in Chloride Medium, J. Braz. Chem. Soc., 2007, 18(6), p 1164–1175CrossRef
2.
N. Boshkov, K. Petrov, S. Vitkova, S. Nemska, and G. Raichevski, Composition of the Corrosion Products of Galvanic Coatings Zn-Co and Their Influence on the Protective Ability, Surf. Coat. Technol., 2002, 157, p 171–178CrossRef
3.
N. Boshkov, K. Petrov, D. Kovacheva, S. Vitkova, and S. Nemska, Influence of the Alloying Component on the Protective Ability of Some Zinc Galvanic Coatings, Electrochem. Acta, 2005, 51, p 77–84CrossRef
4.
A. Brenner, Electrodeposition of Alloys. Principles and Practice, Academic Press, New York, 1963, p 123–152
5.
Z.I. Ortiz, P. Diaz-Arista, Y. Meas, R. Ortega-Borges, and G. Trejo, Characterization of the Corrosion Products of Electrodeposited Zn, Zn-Co and Zn-Mn Alloys Coatings, Corros. Sci., 2009, 51(11), p 2703–2715CrossRef
6.
D. Koleva, N. Boshkov, G. Raichevski, and L. Veleva, Electrochemical Corrosion Behavior and Surface Morphology of Electrodeposited Zinc, Zinc-Cobalt and Their Composite Coatings, Trans. Inst. Met. Finish., 2005, 83(4), p 188–193CrossRef
7.
M. Mouanga, L. Ricq, J. Douglade, and P. Bercot, Corrosion Behavior of Zinc Deposits Obtained Under Pulse Current Electrodeposition: Effects of Coumarion as Additive, Corros. Sci., 2009, 51, p 690–698CrossRef
8.
A.H. Whitehead, M. Poelzler, and B. Gollas, Zinc Electrodeposition from a Deep Eutectic System Containing Choline Chloride and Ethylene Glycol, J. Electrochem. Soc., 2010, 157(6), p D328–D334CrossRef
9.
A. Gomes and M.I. Da Silva Pereira, Pulsed Electrodeposition of Zn in the Presence of Surfactants, Electrochem. Acta, 2006, 51, p 1342–1350CrossRef
10.
R. Ramanauskas, L. Gudaviciute, R. Juskenas, and O. Scit, Structural and Corrosion Characterization of Pulse Plated Nano-crystalline Zinc Coatings, Electrochem. Acta, 2007, 53, p 1801–1810CrossRef
11.
P. Ganesan, S.P. Kumaraguru, and B.N. Popov, Development of Compositionally Modulated Zn-Ni Deposits as Replacement for Cadmium, Surf. Coat. Technol., 2007, 201, p 7896–7904CrossRef
12.
A. Conde, M.A. Arenas, and J.D. Damborenea, Electrodeposition of Zn-Ni Coatings as Cadmium Replacement for Corrosion Protection of High Strength Steel, Corros. Sci., 2011, 53(4), p 1489–1497CrossRef
13.
C.R. Tomachuk, C.I. Elsner, A.R. Di Sarli, and O.B. Ferraz, Corrosion Resistance of Cr(III) Conversion Treatments Applied on Electrogalvanised Steel and Subjected to Chloride, Mater. Chem. Phys., 2010, 119, p 19–29CrossRef
14.
J. Hadley, W. Verberne, L. Wing, and J. O’Grady, Corrosion Resistance Without Hexavalent Chromium: New Zinc Plating Systems, Met. Finish., 2002, 100(5), p 33–36CrossRef
15.
R.L. Twite and G.P. Bierwagen, Review of Alternatives to Chromate for Corrosion Protection of Aluminum Aerospace Alloys, Prog. Org. Coat., 1998, 33, p 91–100CrossRef
16.
S.A.M. Rafaey, S.S.A. El-Rehim, F. Taha, M.B. Saleh, and R.A. Ahmed, Inhibition of Chloride Localized Corrosion of Mild Steel by PO4 3−, CrO4 2−, MoO4 2−, and NO2− anions, Appl. Surf. Sci., 2000, 158, p 190–196CrossRef
17.
C. Muller, M. Sarret, E. Garcia, and J.A. Ortega, Cr-free Passivation on ZnNi Alloys, Electrochem. Soc., 2004, 149, p 151–157
18.
D. Weng, P. Jokiel, A. Uebleis, and H. Boehni, Corrosion and Protection Characteristics of Zinc and Manganese Phosphate Coatings, Surf. Coat. Technol., 1996, 88, p 147–152CrossRef
19.
T.S.N. Sankaranarayana and M. Subbaiyan, Influence of Hexadecyl-Dithiocarbamate on Phosphate Surface Chemical Conversion Coatings on Mild Steel, Surf. Coat. Technol., 1990, 43(44), p 543–549CrossRef
20.
W.E. John, Method of Coating Zinc or Cadmium Base Metals, USA Patent 2,035,380, 1936.
21.
D.M. Johnson, Zink and Cadmium Passivating Bath, USA Patent 2,559,878, 1948.
22.
C.V. Bishop, Iridescent Chromium Coatings and Method, USA Patent 5,393,354, 1995.
23.
C.V. Bishop, Iridescent Chromium Coatings and Method, USA Patent 5,407,749, 1995.
24.
C.V. Bishop, M. J. Thomay, B. J. Page, Black Chromium-Containing Conversion Coatings on Zinc-Nickel and Zinc-Iron Alloys, USA Patent 5,415,702, 1995.
25.
N. Diban, R. Mediavilla, A. Urtiaga, and I. Ortiz, Zinc Recovery and Waste Sludge Minimization from Chromium Passivation Baths, J. Hazard. Mater., 2011, 192, p 801–807CrossRef
26.
P. Huelser, R. Jansen, Chrom(VI)freie Chromatschicht sowie Verfahren zu ihrer Herstellung, German Patent 19,615,664 A1, 1997
27.
C. Gabrielli, M. Keddam, F. Minoutlet-Laurent, K. Ogle, and H. Perrot, Investigation of Zinc Chromatation. I. Application of QCM-ICP Coupling, Electrochim. Acta, 2003, 48, p 965–976CrossRef
28.
C.R. Tomachuk, A.R. Di Sarli, and C.I. Elsner, Anti-corrosion Performance of Cr(VI)-Free Passivating Layers Applied on Electrogalvanised Steel, Mater. Sci. Appl., 2010, 1, p 202–209
29.
T. Bellezze, G. Roventi, and R. Fratesi, Electrochemical Study on the Corrosion Resistance of Cr(III)-Based Conversion Layers on Zinc Coatings, Surf. Coat. Technol., 2002, 155, p 221–230CrossRef
30.
C.R. Tomachuk, A.R. Di Sarli, and C.I. Elsner, Behavior of Electrogalvanized Steel Pre-treated with Cr(III)-Based Baths and Exposed to 0.5 M Na2SO4 Solution, Port. Electrochim. Acta, 2012, 30(3), p 145–162CrossRef
31.
K.W. Cho, V.S. Rao, and H.S. Kwon, Microstructure and Electrochemical Characterization of Trivalent Chromium-Based Conversion Coating on Zinc, Electrochim. Acta, 2007, 52, p 4449–4456CrossRef
32.
X. Zhang, C. Van den Bos, W.G. Sloof, A. Hovestad, H. Terryn, and J.H.W. De Wit, Comparison of the Morphology and Corrosion Performance of Cr(VI)- and Cr(III)-Based Conversion Coatings on Zinc, Surf. Coat. Technol., 2005, 199, p 92–104CrossRef
33.
X. Zhang, W.G. Sloof, A. Hovestad, E.P.M. Van Westing, H. Terryn, and J.H.W. De Wit, Characterization Chromate Conversion Coatings on Zinc Using XPS and SKPFM, Surf. Coat. Technol., 2005, 197, p 168–176CrossRef
34.
M. Hosseini, H. Ashassi-Sorkhabi, and H.A.Y. Ghiasvand, Corrosion Protection of Electrogalvanized Steel by Green Conversion Coatings, J. Rare Earths, 2007, 25, p 537–543CrossRef
35.
Z.L. Long, Y.C. Zhou, and L. Xiao, Characterization of Black Chromate Conversion Coating on the Electrodeposited Zn-Fe Alloy, Appl. Surf. Sci., 2003, 218, p 123–136CrossRef
36.
H.J. Kim, J. Zhang, R.H. Yoon, and R. Gandour, Development of Environmentally Friendly Non-chrome Conversion Coating for Electrogalvanized Steel, Surf. Coat. Technol., 2004, 188-189, p 762–767CrossRef
37.
R. Berger, U. Bexell, T.M. Grekh, and S.E. Hornstrom, A Comparative Study of the Corrosion Protective Properties of Chromium and Chromium Free Passivation Methods, Surf. Coat. Technol., 2007, 202, p 391–397CrossRef
38.
Directive RoHS, Directive 2002/95/CE of the European Parliament and of the Council of the EU, Restriction of Hazardous Substances (RoHS), Off. J. Eur. Union, 2003, 13, p L37/19
39.
O.A. Kirichenko, V.D. Nissenbaum, G.I. Kapustin, and L.M. Kustov, Thermal Analysis of Ammonium Trioxalatometallate Complexes Supported on Titania and Reducibility of Their Decomposition Products, Thermochim. Acta, 2009, 494, p 35–39CrossRef
40.
J.N. Van Niekerk and F.R.L. Schoening, The Crystal Structure of Potassium Trioxalatochromate (III), K3[Cr(C2O4)3]·3H2O, Acta Cryst., 1952, 5, p 196CrossRef
41.
V. Dafinova, R. Radkov, E. Manev, and S. Pelova, Laboratory Exercises in the Inorganic Chemistry, Sofia University Publisher “Sv. Kl. Ohridsky”, Palo Alto, 2007
42.
M. Stern and A.L. Geary, Electrochemical Polarization: A Theoretical Analysis of the Shape of Polarization Curves, J. Electrochem. Soc., 1957, 104, p 56–61CrossRef
43.
S.-I. Pyun and J.W. Lee, Progress in Corrosion Science and Engineering II, Springer, New York, 2012CrossRef
Metadaten
Titel
Corrosion Investigations of Black Chromite Films on Zn and Zn-Co Coatings with Low Cobalt Content
verfasst von
Nikolai Boshkov
Neli Boshkova
Vasil Bachvarov
Miglena Peshova
Ludmil Lutov
Publikationsdatum
01.12.2015
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 12/2015
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-015-1794-5

Weitere Artikel der Ausgabe 12/2015

Journal of Materials Engineering and Performance 12/2015 Zur Ausgabe

OriginalPaper

A DNA-Assembled Fe3O4@Ag Nanorod in Silica Matrix for Cholesterol Biosensing

OriginalPaper

Combustion Synthesis of TiB2-TiC/42CrMo4 Composites with Gradient Joint Prepared in Different High-Gravity Fields

OriginalPaper

Inhibitive Performance of Benzotriazole for Steel Corrosion Studied by Electrochemical and AFM Characterization

OriginalPaper

Oxidation Behavior of Zr43Cu45Al12 Bulk Metallic Glass at 400-525 °C in Air Atmosphere

OriginalPaper

Effect of Pulse Current on the Tensile Deformation of SUS304 Stainless Steel

OriginalPaper

Ultrathin to Nano Thickness TiN Coatings: Processing, Structural, Mechanical Behavior

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise