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Erschienen in:
Electrochemical Study of the Cobalt-Containing and Non-Cobalt-Containing AB5 Alloys Used as Negative Electrodes in Nickel–Metal Hydride Batteries Kapitel lesen Erstes Kapitel lesen

2015 | OriginalPaper | Buchkapitel

4. Cr- and V-Substituted LiMn2O4 Cathode Electrode Materials for High-Rate Battery Applications

verfasst von : Ahsen Akbulut Uludag, Aslıhan Erdaş, Şeyma Özcan, Deniz Nalci, Mehmet Oğuz Güler, Tuğrul Çetinkaya, Mehmet Uysal, Hatem Akbulut

Erschienen in: Progress in Clean Energy, Volume 2

Verlag: Springer International Publishing

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Abstract

Spinel Cr- and V-substituted LiMn2O4 cathode materials were prepared by facile sol–gel process, which used lithium carbonate and manganese carbonate as starting materials and citric acid as a chelating agent. In order to increase electronic conductivity and prevent the Mn ion dissolution into the electrolyte, surfaces of the as-synthesized powders were coated with Cu via electroless deposition technique. The structure and physicochemical properties of the obtained Cr- and V-substituted LiMn2O4 powders were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), galvanostatic charge discharge tests, and electrochemical impedance spectroscopy (EIS). The results have shown that the successful formation of Cr- and V-substituted LiMn2O4 product was highly dependent on its second-stage calcination temperature.

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Vorheriges Kapitel A Novel Battery System for Electric Vehicles
Nächstes Kapitel An Overview of Science Teachers’ Knowledge of Bioenergy and the Need for Future Research: A Case from India
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Metadaten
Titel
Cr- and V-Substituted LiMn2O4 Cathode Electrode Materials for High-Rate Battery Applications
verfasst von
Ahsen Akbulut Uludag
Aslıhan Erdaş
Şeyma Özcan
Deniz Nalci
Mehmet Oğuz Güler
Tuğrul Çetinkaya
Mehmet Uysal
Hatem Akbulut
Copyright-Jahr
2015
Buch
Progress in Clean Energy, Volume 2

Print ISBN: 978-3-319-17030-5

Electronic ISBN: 978-3-319-17031-2

Copyright-Jahr: 2015

DOI
https://doi.org/10.1007/978-3-319-17031-2_4