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Journal of Materials Science

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09.05.2017 | Polymers

Crystallization behavior and enhanced toughness of poly(ethylene terephthalate) composite with noncovalent modified graphene functionalized by pyrene-terminated molecules: a comparative study

verfasst von: Zaizai Tong, Wangqian Zhuo, Jie Zhou, Runsheng Huang, Guohua Jiang

Erschienen in: Journal of Materials Science | Ausgabe 17/2017

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Abstract

Noncovalent functionalization was used to modify the graphene nanosheets via π–π stacking of pyrene-terminated molecule (Py-LC), resulting in an intercalated layer structure incorporated with about 45 wt% of Py-LC. The organically modified graphene (Py-LC-rGO) has a better dispersion in the PET matrix compared with that without modification. Consequently, it remarkably accelerates the crystallization of PET. Moreover, the nucleation ability of Py-LC-rGO is even stronger than that of commercial nucleation agent, sodium benzoate, leading to a thicker lamellar crystals and denser stacking of lamellae. Accordingly, the impact toughness of such a composite is improved to be nine times as that of neat PET, which can be a promising candidate as nanofiller for PET.

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Titel: Crystallization behavior and enhanced toughness of poly(ethylene terephthalate) composite with noncovalent modified graphene functionalized by pyrene-terminated molecules: a comparative study
verfasst von: Zaizai Tong
Wangqian Zhuo
Jie Zhou
Runsheng Huang
Guohua Jiang
Publikationsdatum: 09.05.2017
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 17/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-017-1173-8

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