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2017 | OriginalPaper | Buchkapitel

Crystallization of Cyclic Polymers

verfasst von : Ricardo A. Pérez-Camargo, Agurtzane Mugica, Manuela Zubitur, Alejandro J. Müller

Erschienen in: Polymer Crystallization I

Verlag: Springer International Publishing

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Abstract

The effect of chain topology (ring versus linear polymer chains) on polymer crystallization is reviewed. Recent advances in ring closure and ring expansion synthetic techniques have made available a range of well-characterized samples with higher levels of purity than available decades ago. Cyclic molecules are fascinating because the structural difference between them and linear chains is relatively small, yet their behavior can be completely different from that of their linear analogs of identical chain length. The effect of having no chain ends can dramatically change the polymer coil conformation and diffusion rate, as well as the chain entanglement density in the melt. These changes are reflected in different nucleation and crystallization kinetics for cyclic and linear polymeric chains. However, the results published so far seem to be dependent on the type of polymer employed. Therefore, a careful look at the literature and evidence reported for each group of materials has been assembled and compared. The possible reasons for some of the contradictions in the evidence are also discussed.

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Vorheriges Kapitel Molecular View of Properties of Random Copolymers of Isotactic Polypropylene

Nächstes Kapitel Crystallization of Precision Ethylene Copolymers

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Titel: Crystallization of Cyclic Polymers
verfasst von: Ricardo A. Pérez-Camargo
Agurtzane Mugica
Manuela Zubitur
Alejandro J. Müller
Verlag: Springer International Publishing
Buch: Polymer Crystallization I
Print ISBN: 978-3-319-49201-8

Electronic ISBN: 978-3-319-49203-2

Copyright-Jahr: 2017
DOI: https://doi.org/10.1007/12_2015_326

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