nach oben

Polymer Bulletin

Erschienen in:

20.02.2019 | Original Paper

D.C. conductivity behaviour of poly(vinyl alcohol)-based ferrogels: role of borax and carbonyl iron

verfasst von: Mathias B. Lawrence, Jaison Joseph, Karesh Phondekar, Kiran Moodi

Erschienen in: Polymer Bulletin | Ausgabe 12/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

The d.c. conductivity of poly(vinyl alcohol) hydrogels and ferrogels, cross-linked with borax, has been studied using two-probe resistance measurement method as a function of cross-linker and dopant concentrations. The availability of charge carriers (i.e. unbound borate ions and free sodium ions) in these matrices is seen to vary with cross-linker and dopant concentrations. Increase in borax concentration leads to the rise in d.c. conductivity values. Enhancement in the carbonyl iron dopant proportions, at unchanged borax concentrations, causes a decrease in the conductivity. This behaviour is explained on the basis of structural modifications introduced within the network matrix owing to the variations in cross-linker and dopant concentrations.

Vorheriger Artikel Effect of clay type on the properties of hybrid latexes of poly(vinyl acetate) and montmorillonite prepared via surfactant-free emulsion polymerization

Nächster Artikel Linear polyurethanes with imidazoquinazoline rings: preparation and properties evaluation

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Zhang J, Huang Q, Du J (2016) Recent advances in magnetic hydrogels. Polym Int 65(12):1365–1372. https://doi.org/10.1002/pi.5170 CrossRef

Osada Y, Gong J-P (1998) Soft and wet materials: polymer gels. Adv Mater 10(11):827–837. https://doi.org/10.1002/(SICI)1521-4095(199808)10:11%3c827:AID-ADMA827%3e3.0.CO;2-L CrossRef

Zrinyi M, Szabo D (2001) Muscular contraction mimicked by magnetic gels. Int J Mod Phys B 15(6&7):557–563. https://doi.org/10.1142/S0217979201005015 CrossRef

Hernandez R, Sarafian A, Lopez D, Mijangos C (2004) Viscoelastic properties of poly(vinyl alcohol) hydrogels and ferrogels obtained through freezing-thawing cycles. Polymer 46:5543–5549. https://doi.org/10.1016/j.polymer.2004.05.061 CrossRef

Hernandez R, Lopez G, Lopez D, Vazquez M, Mijangos C (2007) Magnetic characterisation of polyvinyl alcohol ferrogels and films. J Mater Res 22(8):2211–2216. https://doi.org/10.1557/jmr.2007.0298 CrossRef

Babincova M, Lesozczynska D, Sourivong P, Cicimanec P, Babinec P (2001) Superparamagnetic gel as a novel material for electromagnetically induced hyperthermia. J Magn Magn Mater 225:109–112. https://doi.org/10.1016/S0304-8853(00)01237-3 CrossRef

Krumova M, López D, Benavente R, Mijangos C, Pereña JM (2000) Effect of crosslinking on the mechanical and thermal properties of poly(vinyl alcohol). Polymer 41:9265–9272. https://doi.org/10.1016/S0032-3861(00)00287-1 CrossRef

Shafee EE, Naguib HF (2003) Water sorption in cross-linked poly(vinyl alcohol) networks. Polymer 44:1647–1653. https://doi.org/10.1016/S0032-3861(02)00865-0 CrossRef

Manna U, Patil S (2009) Borax mediated layer-by-layer self-assembly of neutral poly(vinyl alcohol) and chitosan. J Phys Chem B 113:9137–9142. https://doi.org/10.1021/jp9025333 CrossRefPubMed

10.

Langer R, Peppas NA (2003) Advances in biomaterials, drug delivery and bionanotechnology. AlChE J Bioeng Food Nat Prod 49(12):2990–3006. https://doi.org/10.1002/aic.690491202 CrossRef

11.

Ricciardi R, Mangiapia G, Lo Celso F, Paduano L, Triolo R, Aurienma F, De Rosa C, Lauprétre F (2005) Structural organization of poly(vinyl alcohol) hydrogels obtained by freezing and thawing techniques: a SANS study. Chem Mater 17:1183–1189. https://doi.org/10.1021/cm048632y CrossRef

12.

Han J, Lei T, Wu Q (2014) High water-content mouldable poly(vinyl alcohol-borax hydrogels reinforced by well-dispersed cellulose nanoparticles: dynamic rheological properties and hydrogel formation mechanism. Carbohydr Polym 102:306–316. https://doi.org/10.1016/j.carbpol.2013.11.045 CrossRefPubMed

13.

Carretti E, Grassi S, Cossalter M, Natali I, Caminati G, Weiss RG, Baglioti P, Dei L (2009) Poly(vinyl alcohol)-borate hydro/cosolvent gels: viscoelastic properties, solubilizing power, and application to art conservation. Langnuir 25(15):8656–8662. https://doi.org/10.1021/la804306w CrossRef

14.

Kale SN, Mona J, Dhobale S, Thite T, Laware SL (2011) Intramolecular and intermolecular crosslinked poly(vinyl alcohol)-borate complexes for the sustained release of fertilisers and enzymes. J Appl Polym Sci 121:2450–2457. https://doi.org/10.1002/app.33776 CrossRef

15.

Ochiai H, Shimuzu S, Tadokoru Y, Murakami I (1981) Complex formation between poly(vinyl alcohol) and borate ion. Polymer 22:1456–1458. https://doi.org/10.1016/0032-3861(81)90310-4 CrossRef

16.

Kurokawa H, Shibayama M, Ilshimaru T, Nomura S, Wu W (1992) Phase behaviour and sol-gel transition of poly(vinyl alcohol)-borate complex in aqueous solution. Polymer 33:2182–2188. https://doi.org/10.1016/0032-3861(92)90886-2 CrossRef

17.

Park G, McLaurin EJ, Faidley LE (2008) Characterisation of the actuator behaviour of blended-system ferrogels. In: Proceedings of SPIE smart structures and materials: behavior and mechanics of multifunctional and composite materials. https://doi.org/10.1117/12/776352

18.

Faidley L, Macias D, Harrington E (2008) Cyclic actuator behaviour of ferrogels. In: Proceedings of the ASME conference on smart materials, adaptive structures and intelligent systems, SMAS1808, Ellicot City, USA, vol 6929, pp 69292C1–69292C10. https://doi.org/10.1115/SMASIS2008-530

19.

Faidley LE, McLaurin EJ (2009) Lumped parameter modeling of the actuator behaviour of ferrogels. In: Proceedings of SPIE—The International Society of Optical Engineering, vol 7289, pp 72891T-1–72891T-9. https://doi.org/10.1117/12.816040

20.

Faidley LE, Han Y, Tucker K, Timmons S, Hong W (2010) Axial strain of ferrogels under cyclic magnetic fields. Smart Mater Struct 19:075001. https://doi.org/10.1088/0964-1726/19/7/075001 CrossRef

21.

Zrinyi M (2000) Intelligent polymer gels controlled by magnetic fields. Colloid Polym Sci 278:98–103. https://doi.org/10.1007/s003960050017 CrossRef

22.

Bar-cohen Y (ed) (2004) Electroactive polymer actuators (EAP) as artificial muscles, 2nd edn. SPIE Press, Bellingham

23.

Lawrence MB, Abbas S, Aswal VK (2018) Structure of polyvinyl alcohol-borax ferrogels: a small angle neutron scattering study. J Polym Res 25:36. https://doi.org/10.1007/s10965-017-1435-9 CrossRef

24.

Komiyama J, Fuoss RM (1972) Conductance in water-poly(vinyl alcohol) mixtures. Proc Natl Acad Sci USA 69(4):829–833. https://doi.org/10.1073/pnas.69.4.829 CrossRefPubMed

25.

Abdullah OG, Hussen SA, Alami A (2011) Electrical characterization of polyvinyl alcohol films doped with sodium iodide. Asian Trans Sci Technol 1(4):1–4

26.

Lin H-L, Liu W-H, Liu Y-F, Cheng C-H (2002) Complexation equilibrium constants of poly(vinyl alcohol)-borax dilute aqueous solutions—consideration of electrostatic charge repulsion and free ions charge shielding effect. J Polym Res 9:233–238. https://doi.org/10.1023/A:1021351701568 CrossRef

27.

Park H-O, Hong JS, Ahu KH, Lee SJ (2005) Influence of preparation parameters on rheological behavior and microstructure of aqueous mixtures of hyaluronic acid/poly(vinyl alcohol). Korea Aust Rheol J 17(2):79–85

28.

Ochiai H, Fujino Y, Tadokoro Y, Murakami I (1982) Polyelectrolyte behaviour of poly(vinyl alcohol) in aqueous borax solutions. Polym J 14(5):423–426. https://doi.org/10.1295/polymj.14.423 CrossRef

29.

Lin H-L, Yu TL, Cheng C-H (2000) Reentrant behaviour of poly(vinyl alcohol)-borax semidilute aqueous solutions. Colloid Polym Sci 278:187–194. https://doi.org/10.1007/s003960050031 CrossRef

30.

Keita G, Ricard A, Audebert R, Pezron E, Leibler L (1996) The poly(vinyl alcohol)-borate system: influence of polyelectrolyte effects on phase diagrams. Polymer 36(1):49–54. https://doi.org/10.1016/0032-3861(95)90674-Q CrossRef

31.

Sekhon SS (2003) Conductivity behaviour of polymer gel electrolytes: role of polymer. Bull Mater Sci 26(3):321–328CrossRef

32.

Lim ST, Cho MS, Jang IB, Choi HJ, Jhou MS (2004) Magnetorheology of carbonyl-iron suspensions with submicron-sized filler. IEEE Trans Magn 40(4):3033–3035. https://doi.org/10.1109/TMAG.2004.830400 CrossRef

33.

Teixeira AV, Morfin I, Ehrburger-Dolle F, Rochas C, Panina P, Licinio P, Gcissler E (2003) Structure and magnetic properties of dilute ferrofluids suspended in gels. Compos Sci Technol 63:1105–1111. https://doi.org/10.1016/S0266-3538(03)00031-9 CrossRef

34.

Jayathilake YMCD, Perera KS, Vidanapathirana KP, Bandara LRAK (2014) Ionic conductivity of PMMA based gel polymer electrolyte and its performance in solid state electrochemical cells. Sri Lanka J Phys 15:11–17. https://doi.org/10.4038/sljp.v15i0.6638 CrossRef

Titel: D.C. conductivity behaviour of poly(vinyl alcohol)-based ferrogels: role of borax and carbonyl iron
verfasst von: Mathias B. Lawrence
Jaison Joseph
Karesh Phondekar
Kiran Moodi
Publikationsdatum: 20.02.2019
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 12/2019
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-019-02719-w

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 12/2019

Radiation crosslinking of acrylic acid/acrylonitrile–silver nitrate hydrogel as a sensitive glucose nanosensor

Effect of plasticizer on the conductivity of carboxymethyl cellulose-based solid polymer electrolyte

The preparation of hydrogel-like polyurethane using the graft polymerization of N,N-dimethylaminoethyl methacrylate and acrylic acid

Investigating mechanical properties of leather treated with Aloe barbadensis Miller and Carrageenan using existing theoretical models

Viscoelastic evaluation of epoxy nanocomposite based on carbon nanofiber obtained from electrospinning processing

Understanding the effect of silane crosslinking reaction on the properties of PP/POE blends

Premium Partner

Marktübersichten