Skip to main content

2017 | OriginalPaper | Buchkapitel

Deactivation of Polybrominated Flame Retardants by Ultraviolet Radiation

verfasst von : Kahina Bentaleb, Zohra Bouberka, Abdelouahab Nadim, Ulrich Maschke, Yassine Agguine, Said Eddarir

Erschienen in: 3rd International Congress on Energy Efficiency and Energy Related Materials (ENEFM2015)

Verlag: Springer International Publishing

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The European directive RoHS (Restriction of the use of certain Hazardous Substances) limits the use of specific toxic substances for example a number of flame retardants. In the light of this context, this work handles with the implementation of a methodology of deactivation by radiative exposure of Tetrabromobisphenol A bis-(2,3-dibromopropylether) (TBBPA-DBPE), concerned by the RoHS directive. It has been shown that the photodegradation by UV-visible irradiation of TBBPA-DBPE in Tetrahydrofuran as organic environment generates less brominated thus less toxic congeners. Physico-chemical analyses were realized by means of a spectroscopic technique that allows to characterize products before and after irradiation under UV-visible light.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Covaci, A., Harrad, S., Abdallah, M.A.E., Ali, N., Law, R.J., Herzke, D., de Wit, C.A.: Novel brominated flame retardants: a review of their analysis, environmental fate and behaviour. Environ. Int. 37, 532–556 (2011). doi:10.1016/j.envint.2010.11.007 CrossRef Covaci, A., Harrad, S., Abdallah, M.A.E., Ali, N., Law, R.J., Herzke, D., de Wit, C.A.: Novel brominated flame retardants: a review of their analysis, environmental fate and behaviour. Environ. Int. 37, 532–556 (2011). doi:10.​1016/​j.​envint.​2010.​11.​007 CrossRef
3.
Zurück zum Zitat Covaci, A., Voorspoels, S., Abdallah, M.A.E., Geens, T., Harrad, S., Law, R.J.: Analytical and environmental aspects of the flame retardant tetrabromobisphenol-A and its derivatives. J. Chromatogr. A 1216, 346–363 (2009). doi:10.1016/j.chroma.2008.08.035 CrossRef Covaci, A., Voorspoels, S., Abdallah, M.A.E., Geens, T., Harrad, S., Law, R.J.: Analytical and environmental aspects of the flame retardant tetrabromobisphenol-A and its derivatives. J. Chromatogr. A 1216, 346–363 (2009). doi:10.​1016/​j.​chroma.​2008.​08.​035 CrossRef
4.
Zurück zum Zitat Haneke, K.E.: Tetrabromobisphenol A bis(2,3-dibromopropylether) review of the toxicological literature. Integrated Laboratory Systems, North Carolina (2002) Haneke, K.E.: Tetrabromobisphenol A bis(2,3-dibromopropylether) review of the toxicological literature. Integrated Laboratory Systems, North Carolina (2002)
5.
Zurück zum Zitat European Brominated Flame Retardant Industry Panel (EBFRIP), Statement June 4 (2007) European Brominated Flame Retardant Industry Panel (EBFRIP), Statement June 4 (2007)
6.
Zurück zum Zitat Lyubimov, A.V., Babin, V.V., Kartashov, A.I.: Developmental neurotoxicity and immunotoxicity of 2,4,6-tribromophenol in Wistar rats. Neurotoxicology 19, 303–312 (1998) Lyubimov, A.V., Babin, V.V., Kartashov, A.I.: Developmental neurotoxicity and immunotoxicity of 2,4,6-tribromophenol in Wistar rats. Neurotoxicology 19, 303–312 (1998)
8.
10.
Zurück zum Zitat Lin, K., Liu, W., Gan, J.: Reaction of tetrabromobisphenol A (TBBPA) with manganese dioxide: kinetics, products, and pathways. Environ. Sci. Technol. 43, 4480–4486 (2009). doi:10.1021/es803622t CrossRef Lin, K., Liu, W., Gan, J.: Reaction of tetrabromobisphenol A (TBBPA) with manganese dioxide: kinetics, products, and pathways. Environ. Sci. Technol. 43, 4480–4486 (2009). doi:10.​1021/​es803622t CrossRef
11.
Zurück zum Zitat Guo, Y., Chen, L., Ma, F., Zhang, S., Yang, Y., Yuan, X., Guo, Y.: Efficient degradation of tetrabromobisphenol A by heterostructured Ag/Bi5Nb3O15 material under the simulated sunlight irradiation. J. Hazard. Mater. 189, 614–618 (2011). doi:10.1016/j.jhazmat.2011.02.054 CrossRef Guo, Y., Chen, L., Ma, F., Zhang, S., Yang, Y., Yuan, X., Guo, Y.: Efficient degradation of tetrabromobisphenol A by heterostructured Ag/Bi5Nb3O15 material under the simulated sunlight irradiation. J. Hazard. Mater. 189, 614–618 (2011). doi:10.​1016/​j.​jhazmat.​2011.​02.​054 CrossRef
12.
Zurück zum Zitat Hamers, T., Kamstra, J.H., Sonneveld, E., Murk, A.J., Zegers, B.N., Boon, J.P., Brouwer, A.: In vitroscreening of the endocrine disrupting potency of brominated flame retardants and their metabolites. Organohalogen Compd. 66, 3016–3020 (2004) Hamers, T., Kamstra, J.H., Sonneveld, E., Murk, A.J., Zegers, B.N., Boon, J.P., Brouwer, A.: In vitroscreening of the endocrine disrupting potency of brominated flame retardants and their metabolites. Organohalogen Compd. 66, 3016–3020 (2004)
14.
Zurück zum Zitat Faust, B.: Modern chemical techniques. The Royal Society of Chemistry, London (1997) Faust, B.: Modern chemical techniques. The Royal Society of Chemistry, London (1997)
15.
Zurück zum Zitat Stuart, H., Ibarra, C., Abdallah, MA-E., Boon, R., Neels, H., Covaci, A.: Concentrations of brominated flame retardants in dust from United Kingdom cars, homes, and offices: causes of variability and implications for human exposure. Environ. Int. 34, 1170–1175 (2008). doi:10.1016/j.envint.2008.05.001 Stuart, H., Ibarra, C., Abdallah, MA-E., Boon, R., Neels, H., Covaci, A.: Concentrations of brominated flame retardants in dust from United Kingdom cars, homes, and offices: causes of variability and implications for human exposure. Environ. Int. 34, 1170–1175 (2008). doi:10.​1016/​j.​envint.​2008.​05.​001
16.
Zurück zum Zitat Guo, Y., Zhou, J., Lou, X., Liu, R., Xiao, D., Fang, C., Wang, Z., Liu, J.: Enhanced degradation of tetrabromobisphenol A in water by a UV/base/persulfate system: kinetics and intermediates. Chem. Eng. J. 254, 538–544 (2014). doi:10.1016/j.cej.2014.05.143 CrossRef Guo, Y., Zhou, J., Lou, X., Liu, R., Xiao, D., Fang, C., Wang, Z., Liu, J.: Enhanced degradation of tetrabromobisphenol A in water by a UV/base/persulfate system: kinetics and intermediates. Chem. Eng. J. 254, 538–544 (2014). doi:10.​1016/​j.​cej.​2014.​05.​143 CrossRef
17.
Zurück zum Zitat An, J., Zhu, L., Wang, N., Song, Z., Yang, Z., Du, D., Tang, H.: Photo-fenton like degradation of tetrabromobisphenol A with grapheme-BiFeO3 composite as a catalyst. Chem. Eng. J. 219, 225–237 (2013). doi:10.1016/j.cej.2013.01.013 CrossRef An, J., Zhu, L., Wang, N., Song, Z., Yang, Z., Du, D., Tang, H.: Photo-fenton like degradation of tetrabromobisphenol A with grapheme-BiFeO3 composite as a catalyst. Chem. Eng. J. 219, 225–237 (2013). doi:10.​1016/​j.​cej.​2013.​01.​013 CrossRef
18.
Zurück zum Zitat Zhong, Y., Liang, X., Zhong, Y., Zhu, J., Zhu, S., Yuan, P., He, H., Zhang, J.: Heterogeneous UV/Fenton degradation of TBBPA catalyzed by titanomagnetite: catalyst characterization, performance and degradation products. Water Res. 46, 4633–4644 (2012). doi:10.1016/j.watres.2012.06.025 CrossRef Zhong, Y., Liang, X., Zhong, Y., Zhu, J., Zhu, S., Yuan, P., He, H., Zhang, J.: Heterogeneous UV/Fenton degradation of TBBPA catalyzed by titanomagnetite: catalyst characterization, performance and degradation products. Water Res. 46, 4633–4644 (2012). doi:10.​1016/​j.​watres.​2012.​06.​025 CrossRef
Metadaten
Titel
Deactivation of Polybrominated Flame Retardants by Ultraviolet Radiation
verfasst von
Kahina Bentaleb
Zohra Bouberka
Abdelouahab Nadim
Ulrich Maschke
Yassine Agguine
Said Eddarir
Copyright-Jahr
2017
DOI
https://doi.org/10.1007/978-3-319-45677-5_14