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2020 | OriginalPaper | Buchkapitel

Deoxidation of TiAl Alloy Scraps with Metallic Yttrium and Calcium Fluoride Slag

verfasst von : Lina Jiao, Shihua Wang, Fuhao Xiong, Guangyao Chen, Zhihe Dou, Xionggang Lu, Chonghe Li

Erschienen in: TMS 2020 149th Annual Meeting & Exhibition Supplemental Proceedings

Verlag: Springer International Publishing

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Abstract

Recently, the recycle of TiAl scrap becomes an important issue; however, its high oxygen content, which deteriorates mechanical properties, should be deoxidized. In this study, the scrap of TiAl alloy is melted using the water-cooling copper crucible, then the metallic yttrium and calcium fluoride slag are added on this melt. The deoxidation behavior of scrap is investigated, and the change of oxygen concentration is measured to evaluate the performance of this novel deoxidation technology. The results showed that the oxygen content of TiAl alloys under atmospheric pressure varied between 0.169 and 0.182 wt%. When the sample cell was vacuumed, the oxygen content varied between 0.131 and 0.167 wt%. In addition, the TiAl alloy contains a certain amount of element Y after deoxidation. This fact shows that the metallic yttrium and calcium fluoride slag exhibit a good deoxidation for the TiAl alloy melts. It may be one of the promising deoxidation processes of scrap of TiAl alloy.

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Literatur
1.
Zurück zum Zitat Zhang D, Dehm G, Clemens H (2000) Effect of heat-treatments and hot-isostatic pressing on phase transformation and microstructure in a β/B2 containing γ-TiAl based alloy. Scripta Mater 42:1065CrossRef Zhang D, Dehm G, Clemens H (2000) Effect of heat-treatments and hot-isostatic pressing on phase transformation and microstructure in a β/B2 containing γ-TiAl based alloy. Scripta Mater 42:1065CrossRef
2.
Zurück zum Zitat Campbell JP, Ritchie RO, Venkateswara KT (1999) The effect of microstructure on fracture toughness and fatigue crack growth behavior in γ-titanium aluminide based intermetallics. Metall Mater Trans A 30(3):563 Campbell JP, Ritchie RO, Venkateswara KT (1999) The effect of microstructure on fracture toughness and fatigue crack growth behavior in γ-titanium aluminide based intermetallics. Metall Mater Trans A 30(3):563
3.
Zurück zum Zitat Liu Z, Li P, Xiong L et al (2017) High-temperature tensile deformation behavior and microstructure evolution of Ti55 titanium alloy. Mater Sci Eng, A 680:259–269CrossRef Liu Z, Li P, Xiong L et al (2017) High-temperature tensile deformation behavior and microstructure evolution of Ti55 titanium alloy. Mater Sci Eng, A 680:259–269CrossRef
4.
Zurück zum Zitat Su Y, Wang L, Luo L et al (2009) Deoxidation of titanium alloy using hydrogen. Int J Hydrogen Energy 34(21):8958–8963CrossRef Su Y, Wang L, Luo L et al (2009) Deoxidation of titanium alloy using hydrogen. Int J Hydrogen Energy 34(21):8958–8963CrossRef
5.
Zurück zum Zitat Rao BT, Kaul R, Tiwari P et al (2005) Inert gas cutting of titanium sheet with pulsed mode CO2 laser. Opt Lasers Eng 43(12):1330–1348CrossRef Rao BT, Kaul R, Tiwari P et al (2005) Inert gas cutting of titanium sheet with pulsed mode CO2 laser. Opt Lasers Eng 43(12):1330–1348CrossRef
6.
Zurück zum Zitat Fu R, Selph S, McDonagh M et al (2013) Effectiveness and harms of recombinant human bone morphogenetic protein-2 in spine fusion: a systematic review and meta-analysis. Ann Intern Med 158(12):890–902CrossRef Fu R, Selph S, McDonagh M et al (2013) Effectiveness and harms of recombinant human bone morphogenetic protein-2 in spine fusion: a systematic review and meta-analysis. Ann Intern Med 158(12):890–902CrossRef
7.
Zurück zum Zitat Kawabata T, Abumiya T, Kanai T (1990) Mechanical properties and dislocation structures of TiAl single crystals deformed at 4.2–293 K. Acta Metall Mater 38(8):1381–1393 Kawabata T, Abumiya T, Kanai T (1990) Mechanical properties and dislocation structures of TiAl single crystals deformed at 4.2–293 K. Acta Metall Mater 38(8):1381–1393
8.
Zurück zum Zitat Okabe TH, Hirota K, Kasai E et al (1998) Thermodynamic properties of oxygen in RE–O (RE=Gd, Tb, Dy, Er) solid solutions. J Alloys Compd 279:184–191CrossRef Okabe TH, Hirota K, Kasai E et al (1998) Thermodynamic properties of oxygen in RE–O (RE=Gd, Tb, Dy, Er) solid solutions. J Alloys Compd 279:184–191CrossRef
9.
Zurück zum Zitat Okabe TH, Oishi T (1992) Deoxidization of titanium aluminide by Ca–Al alloy under controlled aluminum activity. Metall Mater Trans B 23B(10):583–590CrossRef Okabe TH, Oishi T (1992) Deoxidization of titanium aluminide by Ca–Al alloy under controlled aluminum activity. Metall Mater Trans B 23B(10):583–590CrossRef
10.
Zurück zum Zitat Fu R, Selph S, McDonagh M, Peterson K et al (2013) Effectiveness and harms of recombinant human bone morphogenetic protein-2 in spine fusion: a systematic review and meta-analysis. Ann Intern Med 158:890–902CrossRef Fu R, Selph S, McDonagh M, Peterson K et al (2013) Effectiveness and harms of recombinant human bone morphogenetic protein-2 in spine fusion: a systematic review and meta-analysis. Ann Intern Med 158:890–902CrossRef
11.
Zurück zum Zitat Okabe TH, Jacob KT, Waseda Y (2001) Removal of oxygen in reactive metals. Purification process and characterization of ultra high purity metals. Springer, Berlin, pp 1–30 Okabe TH, Jacob KT, Waseda Y (2001) Removal of oxygen in reactive metals. Purification process and characterization of ultra high purity metals. Springer, Berlin, pp 1–30
12.
Zurück zum Zitat Bartosinski M, Hassan-Pour S, Friedrich B et al (2016) Deoxidation limits of titanium alloys during pressure electro slag remelting. Mater Sci Eng 143:1–10 Bartosinski M, Hassan-Pour S, Friedrich B et al (2016) Deoxidation limits of titanium alloys during pressure electro slag remelting. Mater Sci Eng 143:1–10
13.
Zurück zum Zitat Okabe TH, Hamanaka Y, Taninouchi Y (2016) Direct oxygen removal technique for recycling titanium using molten MgCl2 salt. The R Soc Chem 2016 Faraday Discuss 190:109–126 Okabe TH, Hamanaka Y, Taninouchi Y (2016) Direct oxygen removal technique for recycling titanium using molten MgCl2 salt. The R Soc Chem 2016 Faraday Discuss 190:109–126
14.
Zurück zum Zitat Kobayashi Y, Tsukihashi F (1998) Thermodynamics of yttrium and oxygen in molten Ti, Ti3Al, and TiAl. Metall Mater Trans B 29B:1037–1042CrossRef Kobayashi Y, Tsukihashi F (1998) Thermodynamics of yttrium and oxygen in molten Ti, Ti3Al, and TiAl. Metall Mater Trans B 29B:1037–1042CrossRef
15.
Zurück zum Zitat Waseda Y, Isshiki M (eds) (2001) Purification process and characterization of ultra high purity metals, 3rd edn. Springer, Berlin, pp 3–37 Waseda Y, Isshiki M (eds) (2001) Purification process and characterization of ultra high purity metals, 3rd edn. Springer, Berlin, pp 3–37
16.
Zurück zum Zitat Guo JJ, Jia J, Liu Y et al (2000) Evaporation behavior of aluminum during the cold crucible induction skull melting of titanium aluminum alloys. Metall Mater Trans B 31(4):837–844 (in Chinese)CrossRef Guo JJ, Jia J, Liu Y et al (2000) Evaporation behavior of aluminum during the cold crucible induction skull melting of titanium aluminum alloys. Metall Mater Trans B 31(4):837–844 (in Chinese)CrossRef
17.
Zurück zum Zitat Zevin L, Kimmel G (1995) Quantitative X-ray diffractometry. Springer, New YorkCrossRef Zevin L, Kimmel G (1995) Quantitative X-ray diffractometry. Springer, New YorkCrossRef
18.
Zurück zum Zitat Wang K (2009) Phase diagram calculation of oxides for designing refractories for melting titanium and its alloys. Master thesis, Shanghai University (in Chinese) Wang K (2009) Phase diagram calculation of oxides for designing refractories for melting titanium and its alloys. Master thesis, Shanghai University (in Chinese)
19.
Zurück zum Zitat Kong F, Xu X, Chen Y et al (2012) Microstructure and mechanical properties of large size as-cast Ti–43Al–9V–0.2Y (at.%) alloy ingot from brim to centre. Mater Des 33:485–490CrossRef Kong F, Xu X, Chen Y et al (2012) Microstructure and mechanical properties of large size as-cast Ti–43Al–9V–0.2Y (at.%) alloy ingot from brim to centre. Mater Des 33:485–490CrossRef
20.
Zurück zum Zitat Bu MJ, Wang PS, Xu HH et al (2010) Experimental investigation and thermodynamic modeling of the Zr-Y system. J Min Metall, Sect B: Metall 46(2):181–192 Bu MJ, Wang PS, Xu HH et al (2010) Experimental investigation and thermodynamic modeling of the Zr-Y system. J Min Metall, Sect B: Metall 46(2):181–192
21.
Zurück zum Zitat Chen YY, Li BH, Kong FT (2008) Microstructural refinement and mechanical properties of Y-bearing TiAl alloys. J Alloy Compd 457:265–269CrossRef Chen YY, Li BH, Kong FT (2008) Microstructural refinement and mechanical properties of Y-bearing TiAl alloys. J Alloy Compd 457:265–269CrossRef
22.
Zurück zum Zitat Li Q, Yang ZD, Xia CQ et al (2019) Effects of Y addition on microstructure and mechanical properties of Ti-25Zr alloys. Mater Sci Eng, A 748:236–243CrossRef Li Q, Yang ZD, Xia CQ et al (2019) Effects of Y addition on microstructure and mechanical properties of Ti-25Zr alloys. Mater Sci Eng, A 748:236–243CrossRef
23.
Zurück zum Zitat Aninat R, Valle N, Chemin J-B et al (2019) Addition of Ta and Y in a hard Ti-Al-N PVD coating: Individual and conjugated effect on the oxidation and wear properties. Corros Sci 156:171–180 Aninat R, Valle N, Chemin J-B et al (2019) Addition of Ta and Y in a hard Ti-Al-N PVD coating: Individual and conjugated effect on the oxidation and wear properties. Corros Sci 156:171–180
24.
Zurück zum Zitat Zhou F, Wang KL, Lu SQ et al (2019) Effect of adding rare earth element Y on high temperature deformation behavior and hot working process of Ti2AlNb based alloy. J Plast Eng 26(3):153–160 (in Chinese) Zhou F, Wang KL, Lu SQ et al (2019) Effect of adding rare earth element Y on high temperature deformation behavior and hot working process of Ti2AlNb based alloy. J Plast Eng 26(3):153–160 (in Chinese)
25.
Zurück zum Zitat Zhang DD (2016) Dissertation for the Master Degree in Engineering. Master thesis, Harbin Institute of Technology (in Chinese) Zhang DD (2016) Dissertation for the Master Degree in Engineering. Master thesis, Harbin Institute of Technology (in Chinese)
Metadaten
Titel
Deoxidation of TiAl Alloy Scraps with Metallic Yttrium and Calcium Fluoride Slag
verfasst von
Lina Jiao
Shihua Wang
Fuhao Xiong
Guangyao Chen
Zhihe Dou
Xionggang Lu
Chonghe Li
Copyright-Jahr
2020
DOI
https://doi.org/10.1007/978-3-030-36296-6_156

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