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2019 | OriginalPaper | Buchkapitel

30. Design of Heterogeneities and Interfaces with Nanofibers in Fuel Cell Membranes

verfasst von : Marta Zatoń, Sara Cavaliere, Deborah J. Jones, Jacques Rozière

Erschienen in: Handbook of Nanofibers

Verlag: Springer International Publishing

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Abstract

Many fuel cell membranes are highly heterogeneous systems comprising mechanical and chemical reinforcing components, including porous polymer sheets, nanofibers or nanoparticles, as well as radical scavengers or hydrogen peroxide decomposition catalysts. In the last 10 years, great attention has been devoted to 1D nanomaterials obtained by electrospinning. Several chemistries and compositions from aliphatic or aromatic polymers to metal oxides and phosphates and morphologies from nanofibers to nanotubes have been employed to prepare nanocomposite membranes. Despite the significant advances realized, further improvements in ionomer membrane durability under operation are still required. In particular, it is crucial to control the heterogeneity induced by the nanofiber component and to strengthen the interface between them and the matrix. Specific interactions have been demonstrated to improve the fiber/matrix interface with overall improvement of dimensional and mechanical properties. In this chapter we review the different approaches to fuel cell membrane reinforcement based on electrospun polymers and inorganic nanofibers.

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Titel: Design of Heterogeneities and Interfaces with Nanofibers in Fuel Cell Membranes
verfasst von: Marta Zatoń
Sara Cavaliere
Deborah J. Jones
Jacques Rozière
Verlag: Springer International Publishing
Buch: Handbook of Nanofibers
Print ISBN: 978-3-319-53654-5

Electronic ISBN: 978-3-319-53655-2

Copyright-Jahr: 2019
DOI: https://doi.org/10.1007/978-3-319-53655-2_32

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