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01.06.2020 | Research paper

Double carbon-embedded Na₃V₂(PO₄)₃ as a superior anode for sodium ion batteries

verfasst von: Meng Li, Qi Zhang, Zonglin Zuo, Xuan-Wen Gao, Qingrong Yao, Zhongmin Wang, Wen-Bin Luo, Huaiying Zhou, Jianqiu Deng

Erschienen in: Journal of Nanoparticle Research | Ausgabe 6/2020

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Abstract

Double carbon-embedded Na₃V₂(PO₄)₃ (DC-NVP) nanocomposites were prepared via in situ growth of NVP@C nanoparticles on carbon nanotubes (CNTs). Beneficial of a high electronic conductivity network and structure stability, the DC-NVP nanocomposite as an anode of sodium ion batteries (SIBs) reveals outstanding electrochemical properties, delivering ultra-long cycle life with a first charge capacity of 78 mA h g⁻¹ at 50 C and a capacity loss of 0.006%/cycle over 8000 cycles. The NVP//NVP full cells, fabricated by the DC-NVP nanocomposites as bipolar electrode, exhibit a discharge capacity of 72.1 mA h g⁻¹ at 20 C after 5000 cycles and a corresponding capacity retention of 81%. The remarkable performance of DC-NVP nanocomposites is ascribed to that of the unique double carbon-embedded nanostructure, which possesses good electronic conductivity, larger electrode-electrolyte contact area, fast electron and ion transportation, and structural stability.

Vorheriger Artikel Preparation of Ni1 − xFex nanoparticles with a composition gradient and a proposed formation mechanism

Nächster Artikel Atomic-scale insights into structural and thermodynamic stability of spherical Al@Ni and Ni@Al core–shell nanoparticles

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Titel: Double carbon-embedded Na3V2(PO4)3 as a superior anode for sodium ion batteries
verfasst von: Meng Li
Qi Zhang
Zonglin Zuo
Xuan-Wen Gao
Qingrong Yao
Zhongmin Wang
Wen-Bin Luo
Huaiying Zhou
Jianqiu Deng
Publikationsdatum: 01.06.2020
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 6/2020
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-020-04853-3

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