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Journal of Materials Science

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05.03.2018 | Ceramics

Dual relaxation behaviors and large electrostrictive properties of Bi_0.5Na_0.5TiO₃–Sr_0.85Bi_0.1TiO₃ ceramics

verfasst von: Jun Wang, Changrong Zhou, Qingning Li, Weidong Zeng, Jiwen Xu, Guohua Chen, Changlai Yuan, Guanghui Rao

Erschienen in: Journal of Materials Science | Ausgabe 12/2018

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Abstract

Lead-free ceramics (1 − x)Bi_0.5Na_0.5TiO₃–xSr_0.85Bi_0.1TiO₃ (BNT–xSBT, x = 0.4, 0.5, 0.6 and 0.7) were prepared by a solid-state reaction process. Coexistence of ferroelectric relaxation at low temperature and Maxwell–Wagner dielectric relaxation at high temperature was revealed for the first time in this system. Meanwhile, hysteresis-free P–E loops combined with a very high piezoelectric strain coefficient (d₃₃) of 1658 pC/N concurrently with large electrostrictive coefficient Q = 0.287 m⁴C⁻² were achieved. The ferroelectric relaxor behavior and large electrostrictive strain might be linked to easy reorientation and reversal of ergodic PNRs and the combined effect of Bi off-center position and lone pair electrons.

Vorheriger Artikel Studies of structural, optical, and electrical properties associated with defects in sodium-doped copper oxide (CuO/Na) nanostructures

Nächster Artikel Graphene/PANI hybrid film with enhanced thermal conductivity by in situ polymerization

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Titel: Dual relaxation behaviors and large electrostrictive properties of Bi0.5Na0.5TiO3–Sr0.85Bi0.1TiO3 ceramics
verfasst von: Jun Wang
Changrong Zhou
Qingning Li
Weidong Zeng
Jiwen Xu
Guohua Chen
Changlai Yuan
Guanghui Rao
Publikationsdatum: 05.03.2018
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 12/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-018-2186-7

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