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Erschienen in: Adsorption 6/2013

01.12.2013

Dynamic desorption of CO2 and CH4 from amino-MIL-53(Al) adsorbent

verfasst von: Sunil A. Peter, Gino V. Baron, Jorge Gascon, Freek Kapteijn, Joeri F. M. Denayer

Erschienen in: Adsorption | Ausgabe 6/2013

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Abstract

Dynamic adsorption–desorption measurements of CO2 and CH4 in amino-MIL-53(Al) were carried out in an adsorption breakthrough setup at different temperatures (303, 318, and 333 K) and pressures (1, 5, and 30 bar) to study the desorption dynamics of CO2 in amino-MIL(Al) as it plays an important role in the design of pressure swing adsorption (PSA) process for the upgrading of biogas. 13X zeolite was used as a reference material. The dynamic adsorption selectivity as well as the desorption efficiency of CO2 in both amino-MIL-53(Al) and 13X zeolite were calculated to evaluate the potential of amino-MIL-53(Al) for the upgrading of biogas by PSA process.

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Literatur
Zurück zum Zitat Ackley, M.W.: Multilayer adsorbent beds for PSA gas separation. U. S. Patent 6,152,991 (2000) Ackley, M.W.: Multilayer adsorbent beds for PSA gas separation. U. S. Patent 6,152,991 (2000)
Zurück zum Zitat Bao, Z., Yu, L., Ren, Q., Lu, X., Deng, S.: Adsorption of CO2 and CH4 on a magnesium-based metal organic framework. J. Colloid Interface Sci. 353, 549–556 (2011)CrossRef Bao, Z., Yu, L., Ren, Q., Lu, X., Deng, S.: Adsorption of CO2 and CH4 on a magnesium-based metal organic framework. J. Colloid Interface Sci. 353, 549–556 (2011)CrossRef
Zurück zum Zitat Biswas, S., Rémy, T., Couck, S., Denysenko, D., Rampelberg, G., Denayer, J.F.M., Volkmer, D., Detavernier, C., Voort, P.V.D.: Partially fluorinated MIL-47 and Al-MIL-53 frameworks: influence of functionalization on sorption and breathing properties. Phys. Chem. Chem. Phys. 15, 3552–3561 (2013)CrossRef Biswas, S., Rémy, T., Couck, S., Denysenko, D., Rampelberg, G., Denayer, J.F.M., Volkmer, D., Detavernier, C., Voort, P.V.D.: Partially fluorinated MIL-47 and Al-MIL-53 frameworks: influence of functionalization on sorption and breathing properties. Phys. Chem. Chem. Phys. 15, 3552–3561 (2013)CrossRef
Zurück zum Zitat Boutin, A., Couck, S., Coudert, F.X., Serra-Crespo, P., Gascon, J., Kapteijn, F., Fuchs, A.H., Denayer, J.F.M.: Thermodynamic analysis of the breathing of amino-functionalized MIL-53(Al) upon CO2 adsorption. Microporous Mesoporous Mater. 140, 108–113 (2011)CrossRef Boutin, A., Couck, S., Coudert, F.X., Serra-Crespo, P., Gascon, J., Kapteijn, F., Fuchs, A.H., Denayer, J.F.M.: Thermodynamic analysis of the breathing of amino-functionalized MIL-53(Al) upon CO2 adsorption. Microporous Mesoporous Mater. 140, 108–113 (2011)CrossRef
Zurück zum Zitat Cavenati, S., Carlos, A., Rodrigues, A.: Upgrade of methane from landfill gas by pressure swing adsorption. Energy Fuels 19, 2545–2555 (2005)CrossRef Cavenati, S., Carlos, A., Rodrigues, A.: Upgrade of methane from landfill gas by pressure swing adsorption. Energy Fuels 19, 2545–2555 (2005)CrossRef
Zurück zum Zitat Cavenati, S., Grande, C.A., Rodrigues, A.E.: Adsorption equilibrium of methane, carbon dioxide, and nitrogen on zeolite 13× at high pressures. J. Chem. Eng. Data 49, 1095–1101 (2004)CrossRef Cavenati, S., Grande, C.A., Rodrigues, A.E.: Adsorption equilibrium of methane, carbon dioxide, and nitrogen on zeolite 13× at high pressures. J. Chem. Eng. Data 49, 1095–1101 (2004)CrossRef
Zurück zum Zitat Couck, S., Denayer, J.F.M., Baron, G.V., Rémy, T., Gascon, J., Kapteijn, F.: An amine-functionalized MIL-53 metal–organic framework with large separation power for CO2 and CH4. J. Am. Chem. Soc. 131, 6326–6327 (2009)CrossRef Couck, S., Denayer, J.F.M., Baron, G.V., Rémy, T., Gascon, J., Kapteijn, F.: An amine-functionalized MIL-53 metal–organic framework with large separation power for CO2 and CH4. J. Am. Chem. Soc. 131, 6326–6327 (2009)CrossRef
Zurück zum Zitat Couck, S., Gobechiya, E., Kirschhock, C.E.A., Serra-Crespo, P., Juan-Alcañiz, J., Martinez Joaristi, A., Stavitski, E., Gascon, J., Kapteijn, F., Baron, G.V., Denayer, J.F.M.: Adsorption and separation of light gases on an amino-functionalized metal–organic framework: an adsorption and in situ XRD study. ChemSusChem 5, 740–750 (2012)CrossRef Couck, S., Gobechiya, E., Kirschhock, C.E.A., Serra-Crespo, P., Juan-Alcañiz, J., Martinez Joaristi, A., Stavitski, E., Gascon, J., Kapteijn, F., Baron, G.V., Denayer, J.F.M.: Adsorption and separation of light gases on an amino-functionalized metal–organic framework: an adsorption and in situ XRD study. ChemSusChem 5, 740–750 (2012)CrossRef
Zurück zum Zitat Couck, S., Rémy, T., Baron, G.V., Gascon, J., Kapteijn, F., Denayer, J.F.M.: A pulse chromatographic study of the adsorption properties of the amino-MIL-53 (Al) metal–organic framework. Phys. Chem. Chem. Phys. 12, 9413–9418 (2010)CrossRef Couck, S., Rémy, T., Baron, G.V., Gascon, J., Kapteijn, F., Denayer, J.F.M.: A pulse chromatographic study of the adsorption properties of the amino-MIL-53 (Al) metal–organic framework. Phys. Chem. Chem. Phys. 12, 9413–9418 (2010)CrossRef
Zurück zum Zitat D’Alessandro, D.M., Smit, B., Long, J.R.: Carbon dioxide capture: prospects for new materials. Angew. Chem. Int. Ed. 49, 6058–6082 (2010)CrossRef D’Alessandro, D.M., Smit, B., Long, J.R.: Carbon dioxide capture: prospects for new materials. Angew. Chem. Int. Ed. 49, 6058–6082 (2010)CrossRef
Zurück zum Zitat Delgado, J.A., Uguina, M.A., Sotelo, J.L., Ruiz, B., Rosario, M.: Carbon dioxide/methane separation by adsorption on sepiolite. J. Nat. Gas Chem. 16, 235–243 (2007)CrossRef Delgado, J.A., Uguina, M.A., Sotelo, J.L., Ruiz, B., Rosario, M.: Carbon dioxide/methane separation by adsorption on sepiolite. J. Nat. Gas Chem. 16, 235–243 (2007)CrossRef
Zurück zum Zitat Figueroa, J.D., Fout, T., Plasynski, S., McIlvried, H., Srivastava, R.D.: Advances in CO2 capture technology—The U.S. Department of Energy’s Carbon Sequestration Program. Int. J. Greenh. Gas Control 2, 9–20 (2008)CrossRef Figueroa, J.D., Fout, T., Plasynski, S., McIlvried, H., Srivastava, R.D.: Advances in CO2 capture technology—The U.S. Department of Energy’s Carbon Sequestration Program. Int. J. Greenh. Gas Control 2, 9–20 (2008)CrossRef
Zurück zum Zitat Finsy, V., Ma, L., Alaerts, L., De Vos, D.E., Baron, G.V., Denayer, J.F.M.: Separation of CO2/CH4 mixtures with the MIL-53(Al) metal–organic framework. Microporous Mesoporous Mater. 120, 221–227 (2009)CrossRef Finsy, V., Ma, L., Alaerts, L., De Vos, D.E., Baron, G.V., Denayer, J.F.M.: Separation of CO2/CH4 mixtures with the MIL-53(Al) metal–organic framework. Microporous Mesoporous Mater. 120, 221–227 (2009)CrossRef
Zurück zum Zitat Hamon, L., Jolimaître, E., Pirngruber, G.: CO2 and CH4 separation by adsorption using Cu–BTC metal–organic framework. Ind. Eng. Chem. Res. 49, 7497–7503 (2010)CrossRef Hamon, L., Jolimaître, E., Pirngruber, G.: CO2 and CH4 separation by adsorption using Cu–BTC metal–organic framework. Ind. Eng. Chem. Res. 49, 7497–7503 (2010)CrossRef
Zurück zum Zitat Hamon, L., Llewellyn, P.L., Devic, T., Ghoufi, A., Clet, G., Guillerm, V., Pirngruber, G.D., Maurin, G., Serre, C., Driver, G., Beek, W.V., Jolimaître, E., Vimont, A., Daturi, M., Férey, G.: Co-adsorption and separation of CO2–CH4 mixtures in the highly flexible MIL-53(Cr) MOF. J. Am. Chem. Soc. 53, 17490–17499 (2009)CrossRef Hamon, L., Llewellyn, P.L., Devic, T., Ghoufi, A., Clet, G., Guillerm, V., Pirngruber, G.D., Maurin, G., Serre, C., Driver, G., Beek, W.V., Jolimaître, E., Vimont, A., Daturi, M., Férey, G.: Co-adsorption and separation of CO2–CH4 mixtures in the highly flexible MIL-53(Cr) MOF. J. Am. Chem. Soc. 53, 17490–17499 (2009)CrossRef
Zurück zum Zitat Harlick, P.J.E., Tezel, F.H.: An experimental adsorbent screening study for CO2 removal from N2. Microporous Mesoporous Mater. 76, 71–79 (2004)CrossRef Harlick, P.J.E., Tezel, F.H.: An experimental adsorbent screening study for CO2 removal from N2. Microporous Mesoporous Mater. 76, 71–79 (2004)CrossRef
Zurück zum Zitat Herm, Z.R., Krishna, R., Long, J.R.: Reprint of: CO2/CH4, CH4/H2 and CO2/CH4/H2 separations at high pressures using Mg2(dobdc). Microporous Mesoporous Mater. 157, 94–100 (2012)CrossRef Herm, Z.R., Krishna, R., Long, J.R.: Reprint of: CO2/CH4, CH4/H2 and CO2/CH4/H2 separations at high pressures using Mg2(dobdc). Microporous Mesoporous Mater. 157, 94–100 (2012)CrossRef
Zurück zum Zitat Jain, S., Moharir, A.S., Li, P., Wozny, G.: Heuristic design of pressure swing adsorption: a preliminary study. Sep. Purif. Technol. 33, 25–43 (2003)CrossRef Jain, S., Moharir, A.S., Li, P., Wozny, G.: Heuristic design of pressure swing adsorption: a preliminary study. Sep. Purif. Technol. 33, 25–43 (2003)CrossRef
Zurück zum Zitat Kim, J., Kim, W.Y., Ahn, W.S.: Amine-functionalized MIL-53(Al) for CO2/N2 separation: effect of textural properties. Fuel 102, 574–579 (2012)CrossRef Kim, J., Kim, W.Y., Ahn, W.S.: Amine-functionalized MIL-53(Al) for CO2/N2 separation: effect of textural properties. Fuel 102, 574–579 (2012)CrossRef
Zurück zum Zitat Knaebel, K., Reinhold, H.: Landfill gas: from rubbish to resource. Adsorption 9, 87–94 (2003)CrossRef Knaebel, K., Reinhold, H.: Landfill gas: from rubbish to resource. Adsorption 9, 87–94 (2003)CrossRef
Zurück zum Zitat Krishna, R., van Baten, J.M.: A comparison of the CO2 capture characteristics of zeolites and metal–organic frameworks. Sep. Purif. Technol. 87, 120–126 (2012)CrossRef Krishna, R., van Baten, J.M.: A comparison of the CO2 capture characteristics of zeolites and metal–organic frameworks. Sep. Purif. Technol. 87, 120–126 (2012)CrossRef
Zurück zum Zitat Krishna, R., Long, J.R.: Screening metal–organic frameworks by analysis of transient breakthrough of gas mixtures in a fixed bed adsorber. J. Phys. Chem. C 115, 12941–12950 (2011)CrossRef Krishna, R., Long, J.R.: Screening metal–organic frameworks by analysis of transient breakthrough of gas mixtures in a fixed bed adsorber. J. Phys. Chem. C 115, 12941–12950 (2011)CrossRef
Zurück zum Zitat Lashof, D.A., Ahuja, D.R.: Relative contributions of greenhouse gas emissions to global warming. Nature 344, 529–531 (1990)CrossRef Lashof, D.A., Ahuja, D.R.: Relative contributions of greenhouse gas emissions to global warming. Nature 344, 529–531 (1990)CrossRef
Zurück zum Zitat Li, J.R., Kuppler, R.J., Zhou, H.C.: Selective gas adsorption and separation in metal–organic frameworks. Chem. Soc. Rev. 38, 1477–1504 (2009)CrossRef Li, J.R., Kuppler, R.J., Zhou, H.C.: Selective gas adsorption and separation in metal–organic frameworks. Chem. Soc. Rev. 38, 1477–1504 (2009)CrossRef
Zurück zum Zitat Ma, S.: Gas adsorption applications of porous metal–organic frameworks. Pure Appl. Chem. 81, 2235–2251 (2009)CrossRef Ma, S.: Gas adsorption applications of porous metal–organic frameworks. Pure Appl. Chem. 81, 2235–2251 (2009)CrossRef
Zurück zum Zitat Mitariten, M.: New technology improves nitrogen-removal economics. Oil Gas J. 99, 42–44 (2001) Mitariten, M.: New technology improves nitrogen-removal economics. Oil Gas J. 99, 42–44 (2001)
Zurück zum Zitat Myers, A.L., Prausnitz, J.L.: Thermodynamics of mixed-gas adsorption. AIChE J. 11, 121–127 (1965)CrossRef Myers, A.L., Prausnitz, J.L.: Thermodynamics of mixed-gas adsorption. AIChE J. 11, 121–127 (1965)CrossRef
Zurück zum Zitat Pera-Titus, M., Lescouet, T., Aguado, S., Farrusseng, D.: Quantitative characterization of breathing upon adsorption for a series of amino-functionalized MIL-53. J. Phys. Chem. C 116, 9507–9516 (2012)CrossRef Pera-Titus, M., Lescouet, T., Aguado, S., Farrusseng, D.: Quantitative characterization of breathing upon adsorption for a series of amino-functionalized MIL-53. J. Phys. Chem. C 116, 9507–9516 (2012)CrossRef
Zurück zum Zitat Pillai, R.S., Peter, S.A., Jasra, R.V.: CO2 and N2 adsorption in alkali metal ion exchanged X-Faujasite: grand canonical Monte Carlo simulation and equilibrium adsorption studies. Microporous Mesoporous Mater. 162, 143–151 (2012)CrossRef Pillai, R.S., Peter, S.A., Jasra, R.V.: CO2 and N2 adsorption in alkali metal ion exchanged X-Faujasite: grand canonical Monte Carlo simulation and equilibrium adsorption studies. Microporous Mesoporous Mater. 162, 143–151 (2012)CrossRef
Zurück zum Zitat Primera-Pedrozo, J.N., Torres-Cosme, B.D., Clardy, M.E., Rivera-Ramos, M.E., Hernández-Maldonado, A.J.: Titanium silicate porous materials for carbon dioxide adsorption: synthesis using a structure directing agent, detemplation and inclusion of alkaline earth metal cations. Ind. Eng. Chem. Res. 49, 7515–7523 (2010)CrossRef Primera-Pedrozo, J.N., Torres-Cosme, B.D., Clardy, M.E., Rivera-Ramos, M.E., Hernández-Maldonado, A.J.: Titanium silicate porous materials for carbon dioxide adsorption: synthesis using a structure directing agent, detemplation and inclusion of alkaline earth metal cations. Ind. Eng. Chem. Res. 49, 7515–7523 (2010)CrossRef
Zurück zum Zitat Rallapalli, P., Prasanth, K.P., Patil, D., Somani, R.S., Jasra, R.V., Bajaj, H.C.: Sorption studies of CO2, CH4, N2, CO, O2 and Ar on nanoporous aluminum terephthalate. J. Porous Mater. 18, 205–210 (2011)CrossRef Rallapalli, P., Prasanth, K.P., Patil, D., Somani, R.S., Jasra, R.V., Bajaj, H.C.: Sorption studies of CO2, CH4, N2, CO, O2 and Ar on nanoporous aluminum terephthalate. J. Porous Mater. 18, 205–210 (2011)CrossRef
Zurück zum Zitat Rege, S.U., Yang, R.T.: Kinetic separation of oxygen and argon using molecular sieve carbon. Adsorption 22, 15–22 (2000)CrossRef Rege, S.U., Yang, R.T.: Kinetic separation of oxygen and argon using molecular sieve carbon. Adsorption 22, 15–22 (2000)CrossRef
Zurück zum Zitat Rege, S.U., Yang, R.T.: A simple parameter for selecting an adsorbent for gas separation by pressure swing adsorption. Sep. Sci. Technol. 36, 3355–3365 (2001)CrossRef Rege, S.U., Yang, R.T.: A simple parameter for selecting an adsorbent for gas separation by pressure swing adsorption. Sep. Sci. Technol. 36, 3355–3365 (2001)CrossRef
Zurück zum Zitat Ruthven, D.M., Farooq, S., Knaebel, K.S.: Pressure swing adsorption. Wiley-VCH, New York (1994) Ruthven, D.M., Farooq, S., Knaebel, K.S.: Pressure swing adsorption. Wiley-VCH, New York (1994)
Zurück zum Zitat Ryckebosch, E., Drouillon, M., Vervaeren, H.: Techniques for transformation of biogas to biomethane. Biomass Bioenergy 35, 1633–1645 (2011)CrossRef Ryckebosch, E., Drouillon, M., Vervaeren, H.: Techniques for transformation of biogas to biomethane. Biomass Bioenergy 35, 1633–1645 (2011)CrossRef
Zurück zum Zitat Sircar, S.: Separation of methane and carbon dioxide gas mixtures by pressure swing adsorption. Sep. Sci. Technol. 23, 519–529 (1988)CrossRef Sircar, S.: Separation of methane and carbon dioxide gas mixtures by pressure swing adsorption. Sep. Sci. Technol. 23, 519–529 (1988)CrossRef
Zurück zum Zitat Stavitski, E., Pidko, E.A., Couck, S., Remy, T., Hensen, E.J.M., Weckhuysen, B.M., Denayer, J., Gascon, J., Kapteijn, F.: Complexity behind CO2 capture on NH2-MIL-53(Al). Langmuir 53, 3970–3976 (2011)CrossRef Stavitski, E., Pidko, E.A., Couck, S., Remy, T., Hensen, E.J.M., Weckhuysen, B.M., Denayer, J., Gascon, J., Kapteijn, F.: Complexity behind CO2 capture on NH2-MIL-53(Al). Langmuir 53, 3970–3976 (2011)CrossRef
Zurück zum Zitat Sumida, K., Rogow, D.L., Mason, J.A., McDonald, T.M., Bloch, E.D., Herm, Z.R., Bae, T., Long, J.R.: Carbon dioxide capture in metal–organic frameworks. Chem. Rev. 112, 724–781 (2012)CrossRef Sumida, K., Rogow, D.L., Mason, J.A., McDonald, T.M., Bloch, E.D., Herm, Z.R., Bae, T., Long, J.R.: Carbon dioxide capture in metal–organic frameworks. Chem. Rev. 112, 724–781 (2012)CrossRef
Zurück zum Zitat Yang, R.T.: Gas separation by adsorption process. Imperial College Press, London (1997)CrossRef Yang, R.T.: Gas separation by adsorption process. Imperial College Press, London (1997)CrossRef
Metadaten
Titel
Dynamic desorption of CO2 and CH4 from amino-MIL-53(Al) adsorbent
verfasst von
Sunil A. Peter
Gino V. Baron
Jorge Gascon
Freek Kapteijn
Joeri F. M. Denayer
Publikationsdatum
01.12.2013
Verlag
Springer US
Erschienen in
Adsorption / Ausgabe 6/2013
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI
https://doi.org/10.1007/s10450-013-9564-x

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