Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Polymer Bulletin
Erschienen in: Polymer Bulletin 1/2018

06.04.2017 | Original Paper

Dynamics of nucleation and growth mechanism in the presence of nanoparticles or block copolymers: polystyrene/poly(vinyl methyl ether)

verfasst von: Jafar Khademzadeh Yeganeh

Erschienen in: Polymer Bulletin | Ausgabe 1/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

This study aimed at controlling the phase separation kinetics in the metastable region of polystyrene/poly(vinyl methyl ether) (PS/PVME) blend by adding a block copolymer or hydrophilic and hydrophobic nanoparticles as the compatibilizer. We studied the effects of compatibilizer localization and volume fraction on the dynamics of nucleation and growth (NG) mechanism. For this purpose, time sweep experiments were performed using rheological analysis and phase contrast optical microscopy. Based on the results, hydrophilic nanosilica with preferential affinity to the PVME-rich matrix phase slowed down efficiently the phase separation and beyond a critical volume fraction, pinned the domain growth. The block copolymer, self-assembling along the interface, caused a considerable decrease in phase separation kinetics as well. However, its efficiency was lower than the hydrophilic nanosilica and in the range of the applied volume fractions, no pinning behavior was observed. The hydrophobic nanosilica which preferentially wetted the PS-rich droplets had the minimal effect on phase separation. It was observed that adding nanoparticles or block copolymer could change the dynamical scaling of phase separation.
Nächster Artikel Steady-shear rheology and activation thermodynamics of the interpolymer complex between nonionic polymeric surfactant and hydrophobically modified polyacrylic acid in propylene glycol–water mixture

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Zhong X, Liu Y, Su H, Zhan G, Yu Y, Gan W (2011) Enhanced viscoelastic effect of mesoscopic fillers in phase separation. Soft Matter 7:3642–3650CrossRef
2.
Tanaka H (2009) Formation of network and cellular structures by viscoelastic phase separation. Adv Mater 21:1872–1880CrossRef
3.
Asadi K, Wondergem HJ, Moghaddam RS, McNeill CR, Stingelin N, Noheda B, Blom PWM, de Leeuw DM (2011) Spinodal decomposition of blends of semiconducting and ferroelectric polymers. Adv Funct Mater 21:1887–1894CrossRef
4.
Shin M, Kim H, Park J, Nam S, Heo K, Ree M, Ha CS, Kim Y (2010) Abrupt morphology change upon thermal annealing in poly(3-hexylthiophene)/soluble fullerene blend films for polymer solar cells. Adv Funct Mater 20:748–754CrossRef
5.
Sperling LH (2006) Introduction to physical polymer science. Wiley, Hoboken, pp 159–162
6.
Tanaka H (1996) Universality of viscoelastic phase separation in dynamically asymmetric fluid mixtures. Phys Rev Lett 76:787–790CrossRef
7.
Yeganeh JK, Goharpey F, Foudazi R (2014) Anomalous phase separation behavior in dynamically asymmetric LCST polymer blends. RSC Adv 4:12809–12825CrossRef
8.
Chaykar AS, Goharpey F, Yeganeh JK (2016) Volume phase transition of electron beam cross-linked thermo-responsive PVME nanogels in the presence and absence of nanoparticles: with a view toward rheology and interactions. RSC Adv 6:9693–9708CrossRef
9.
Al-Saleh MH (2016) Carbon nanotube-filled polypropylene/polyethylene blends: compatibilization and electrical properties. Polym Bull 73:975–987CrossRef
10.
Liu XQ, Li RH, Bao RY, Jiang WR, Yang W, Xie BH, Yang MB (2014) Suppression of phase coarsening in immiscible, cocontinuous polymer blends under high temperature quiescent annealing. Soft Matter 10:3587–3596CrossRef
11.
Yan LT, Maresov E, Buxtonb GA, Balazs AC (2011) Self-assembly of mixtures of nanorods in binary, phase-separating blends. Soft Matter 7:595–607CrossRef
12.
Barham B, Fosser K, Voge G, Waldow D, Halasa A (2011) Phase separation kinetics of a polymer blend modified by random and block copolymer additives. Macromolecules 34:514–521CrossRef
13.
Yeganeh JK, Goharpey F, Moghimi E, Petekidis G, Foudazi R (2014) Controlling the kinetics of viscoelastic phase separation through self-assembly of spherical nanoparticles or block copolymers. Soft Matter 10:9270–9280CrossRef
14.
Li L, Miesch C, Sudeep PK, Balazs AC, Emrick T, Russell TP, Hayward RC (2011) Kinetically trapped co-continuous polymer morphologies through intraphase gelation of nanoparticles. Nano Lett 11:1997–2003CrossRef
15.
Gharachorlou A, Goharpey F (2008) Rheologically determined phase behavior of LCST blends in the presence of spherical nanoparticles. Macromolecule 41:3276–3283CrossRef
16.
Xavier P, Sharma K, Elayaraja K, Vasu KS, Sood AK, Bose S (2014) Reduced graphene oxide induced phase miscibility in polystyrene–poly(vinyl methyl ether) blends. RSC Adv 4:12376–12387CrossRef
17.
Gao J, Huang C, Wang N, Yu W, Zhou C (2012) Phase separation of poly (methyl methacrylate)/poly (styrene-co-acrylonitrile) blends in the presence of silica nanoparticles. Polymer 53:1772–1782CrossRef
18.
Bharati A, Xavier P, Kar GP, Madras G, Bose S (2014) Nanoparticle-driven intermolecular cooperativity and miscibility in polystyrene/poly(vinyl methyl ether) blends. J Phys Chem B 118:2214–2225
19.
Huang Y, Jiang S, Li G, Chen D (2005) Effect of fillers on the phase stability of binary polymer blends: a dynamic shear rheology study. Acta Mater 53:5117–5124CrossRef
20.
Huang C, Gao J, Yu W, Zhou C (2012) Phase separation of poly(methyl methacrylate)/poly(styrene-coacrylonitrile) blends with controlled distribution of silica nanoparticles. Macromolecules 45:8420–8429CrossRef
21.
Yeganeh JK, Goharpey F, Moghimi E, Petekidis G, Foudazi R (2015) Manipulating the kinetics and mechanism of phase separation in dynamically asymmetric LCST blends by nanoparticles. Phys Chem Chem Phys 17:27446–27461CrossRef
22.
Zhu YJ, Ma YQ (2003) Phase separation of a polymer blend driven by oscillating particles. Phys Rev E 67:041503CrossRef
23.
Ginzburg VV, Qiu F, Paniconi M, Peng G, Jasnow D, Balazs AC (1999) Simulation of hard particles in a phase-separating binary mixture. Phys Rev Lett 82:4026–4029CrossRef
24.
Balazs AC, Ginzburg VV, Qiu F, Peng G, Jasnow DJ (2000) Multi-scale model for binary mixtures containing nanoscopic particles. Phys Chem Part B 104:3411–3422CrossRef
25.
Ginzburg VV, Peng G, Qiu F, Jasnow D, Balazs AC (1999) Kinetic model of phase separation in binary mixtures with hard mobile impurities. Phys Rev E 60:4352–4359CrossRef
26.
Du M, Wu Q, Zuo M, Zheng Q (2013) Filler effects on the phase separation behavior of poly (methyl methacrylate)/poly (styrene-co-acrylonitrile) binary polymer blends. Eur Polym J 49:2721–2729CrossRef
27.
Yeganeh JK, Goharpey F, Foudazi F (2012) Can only rheology be used to determine the phase separation mechanism indynamically asymmetric polymer blends (PS/PVME)? RSC Adv 2:8116–8127CrossRef
28.
Kapnistos M, Hinrichs A, Vlassopoulos D, Anastasiadis SH, Stammer A, Wolf BA (1996) Rheology of a lower critical solution temperature binary polymer blend in the homogeneous, phase-separated, and transitional regimes. Macromolecules 29:7155–7163CrossRef
29.
Minkova L, Yordanov H, Filippi S, Grizzuti N (2003) Interfacial tension of compatibilized blends of LDPE and PA6:the breaking thread method. Polymer 44:7925–7932CrossRef
30.
Yziquel F, Carreau PJ, Tanguy PA (2009) Non-linear viscoelastic behavior of fumed silica suspensions. Rheol Acta 38:14–25CrossRef
31.
Kim J, Kwei TK, Pearce EM (1992) Thermal oxidation of polymer blends containing an antioxidant. Chem Eng Commun 116:105–116CrossRef
32.
Reich S, Cohen YJ (1981) Phase separation of polymer blends in thin films. J Polym Sci Polym Phys Ed 19:1255–1267CrossRef
33.
Polios IS, Soliman M, Lee C, Gido SP, Roher KS, Winter HH (1997) Late stages of phase separation in a binary polymer blend studied by rheology, optical and electron microscopy, and solid state NMR. Macromolecules 30:4470–4480CrossRef
34.
Yeganeh JK, Goharpey F, Foudazi F (2010) Rheology and morphology of dynamically asymmetric LCST blends: polystyrene/poly(vinyl methyl ether). Macromolecules 43:8670–8685CrossRef
35.
Svoboda P, Svobodova D, Slobodian P, Ougizawa T, Inoue T (2009) Transmission electron microscopy study of phase morphology in polypropylene/ethylene-octene copolymer blends. Eur Polym J 45:1485–1492CrossRef
36.
Lifshitz IM, Slyozov VV (1961) The kinetics of precipitation from supersaturated solid solutions. J Phys Chem Solids 19:35–50CrossRef
37.
Shimizu R, Tanaka H (2015) A novel coarsening mechanism of droplets in immiscible fluid mixtures. Nat Commun 6:7407CrossRef
38.
Binder K, Stauffer D (1974) Theory for the slowing down of the relaxation and spinodal decomposition of binary mixtures. Phys Rev Lett 33:1006–1009CrossRef
39.
Tanaka H (1994) New coarsening mechanisms for spinodal decomposition having droplet pattern in binary fluid mixture: collision-induced collisions. Phys Rev Lett 72:1702–1705CrossRef
40.
Tanaka H (1997) New mechanisms of droplet coarsening in phase-separating fluid mixtures. J Chem Phys 107:3734–3737CrossRef
41.
Fortelny I, Zivny A (1995) Coalescence in molten quiescent polymer blends. Polymer 36:4113–4118CrossRef
42.
Fortelny I, Zivny A (1998) Film drainage between droplets during their coalescence in quiescent polymer blends. Polymer 39:2669–2675CrossRef
43.
Fortelny I, Kovar J (1988) Theory of coalescence in immiscible polymer blends. Polym Compos 9:119–124CrossRef
44.
Utracki LU (2002) Polymer blends handbook. Kluwer Academic Publishers, Dordrecht, The Netherlands
45.
Sumita M, Sakata K, Asai S, Miyasaka K, Hideaki H (1991) Dispersion of fillers and the electrical conductivity of polymer blends filled with carbon black. Polym Bull 25:265–271CrossRef
46.
Owens DK, Wendt RC (1969) Estimation of the surface free energy of polymers. J Appl Polym Sci 13:1741–1747CrossRef
47.
Elias L, Fenouillot F, Majeste JC, Cassagnau P (2007) Morphology and rheology of immiscible polymer blends filled with silica nanoparticles. Polymer 48:6029–6040CrossRef
48.
Svab I, Musil V, Smit I, Makarovic M (2007) Mechanical properties of wollastonite-reinforced polypropylene composites modified with SEBS and SEBS-g-MA elastomers. Polym Eng Sci 47:1873–1880CrossRef
49.
Foudazi R, Nazockdast H (2013) Rheology and morphology of nanosilica-containing polypropylene and polypropylene/liquid crystalline polymer blend. J Appl Polym Sci 128:3501–3511CrossRef
Metadaten
Titel
Dynamics of nucleation and growth mechanism in the presence of nanoparticles or block copolymers: polystyrene/poly(vinyl methyl ether)
verfasst von
Jafar Khademzadeh Yeganeh
Publikationsdatum
06.04.2017
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 1/2018
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-017-2016-0

Weitere Artikel der Ausgabe 1/2018

Polymer Bulletin 1/2018 Zur Ausgabe

Original Paper

Controlled release of fragrance with cross-linked polymers: synthesis and hydrolytic property of cross-linked amphiphilic copolymers bearing octanal-derived acetal moieties

Original Paper

Preparation and characterization of some polymer/pharmaceutical-based composites. Part. II ivermectin

Original Paper

A novel approach on poly(ionic liquid)-based poly(vinyl alcohol) as a hydrophilic/hydrophobic conductive polymer electrolytes

Original Paper

Steady-shear rheology and activation thermodynamics of the interpolymer complex between nonionic polymeric surfactant and hydrophobically modified polyacrylic acid in propylene glycol–water mixture

Original Paper

Physical properties of poly[(thiophene-2,5-diyl)-co-para-chloro benzylidene] doped with cobalt sulphate: synthesis and characterization

Original Paper

Effect of nature of chemical crosslinker on swelling and solubility parameter of a new stimuli-responsive cationic poly(N-acryloyl-N′-propyl piperazine) hydrogel

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise