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2013 | OriginalPaper | Buchkapitel

ECE-Type Pincer Complexes of Nickel

verfasst von : Davit Zargarian, Annie Castonguay, Denis M. Spasyuk

Erschienen in: Organometallic Pincer Chemistry

Verlag: Springer Berlin Heidelberg

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Abstract

Pincer complexes of transition metals have demonstrated valuable catalytic reactivities and desirable properties as functional materials. Much more is known about pincer complexes of noble metals, but the pincer chemistry of nonprecious, 3d metals is poised for rapid growth over the next decade. This chapter presents a literature survey of nickel complexes based on tridentate ECE-type pincer ligands featuring a meridional coordination of the central metal atom through two dative E → Ni interactions and a covalent C–Ni linkage. The discussion is focused on the synthesis, characterization, and reactivities of complexes featuring both symmetrical and unsymmetrical ligands, ECE and ECE′. The material is organized into various sections according to the type of donor moiety E and E′ (phosphine, amine, phosphinite, phosphinimine, thioether, and N-heterocyclic carbene) and the hydrocarbyl linker (aromatic or aliphatic). Where possible, the presentation reflects the chronological order of the developments in this field of study. The review concludes with an overview of the current state of the chemistry of (ECE)Ni complexes and offers some predictions on the future prospects of this field.

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Titel: ECE-Type Pincer Complexes of Nickel
verfasst von: Davit Zargarian
Annie Castonguay
Denis M. Spasyuk
Verlag: Springer Berlin Heidelberg
Buch: Organometallic Pincer Chemistry
Print ISBN: 978-3-642-31080-5

Electronic ISBN: 978-3-642-31081-2

Copyright-Jahr: 2013
DOI: https://doi.org/10.1007/978-3-642-31081-2_5

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