nach oben

Journal of Polymer Research

Erschienen in:

01.11.2018 | ORIGINAL PAPER

Effect of bis[2-(methacryloyloxy)ethyl] phosphate as a crosslinker on poly(AAm-co-AMPS)/Na-MMT hydrogel nanocomposite as potential adsorbent for dyes: kinetic, isotherm and thermodynamic study

verfasst von: Mahdi Taghvay Nakhjiri, Gholam Bagheri Marandi, Mehran Kurdtabar

Erschienen in: Journal of Polymer Research | Ausgabe 11/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

In the present study, synthesis of poly(AAm-co-AMPS)/Na-MMT hydrogel nanocomposite with different amount of bis[2-(methacryloyloxy)ethyl] phosphate as a crosslinker was successfully carried out for the removal of crystal violet (CV), methylene blue (MB) and methyl red (MR) from aqueous solution. Hydrogel nanocomposite was characterized by FT-IR, SEM, EDS, XRD and TGA analysis. Several important parameters were investigated to obtain maximum adsorption capacity. Adsorption behavior of hydrogel nanocomposite was investigated for the adsorption of dyes and it was found to remove about 80% for CV, 89% for MB and 51% for MR in 50 mg/L of dyes solutions at pH 7 and about 86% for CV, 93% for MB and 23% for MR at pH 12. Kinetic studies revealed that the applicability of pseudo-first-order and pseudo-second-order model for the adsorption of CV, MB and MR. The adsorption isotherm was studied in 25, 35, 45 and 55 °C using Langmuir, Freundlich, Temkin and Jovanovic models and the adsorption data were well described by Freundlich isotherm model. Hydrogel nanocomposite showed 155, 176 and 113 mg/g maximum adsorption capacity for CV, MB and MR respectively. Negative values of ΔG⁰ for all three dyes suggested the feasibility of dyes removal and support for spontaneous adsorption of CV, MB and MR on hydrogel nanocomposite. Desorption of dyes from the dye loaded hydrogel nanocomposite was simply done in ethanol. The results indicate that the prepared poly(AAm-co-AMPS)/Na-MMT hydrogel nanocomposite is an efficient adsorbent with high adsorption capacity for the aforementioned dyes.

Vorheriger Artikel Configuration of molecular imprinted polymer for electrochemical atrazine detection

Nächster Artikel Preparation of a star-type telechelic macrophotoinitiator of poly(ε-caprolactone) and its use in photoinduced free radical promoted cationic polymerization

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Uddin MK (2017) A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade. Chem Eng J 308:438–462. https://doi.org/10.1016/j.cej.2016.09.029 CrossRef

Mousavi SJ, Parvini M, Ghorbani M (2018) Experimental design data for the zinc ions adsorption based on mesoporous modified chitosan using central composite design method. Carbohydr Polym 188:197–212. https://doi.org/10.1016/j.carbpol.2018.01.105 CrossRefPubMed

Zhang Q, Zhang T, He T, Chen L (2014) Removal of crystal violet by clay/PNIPAm nanocomposite hydrogels with various clay contents. Appl Clay Sci 90:1–5. https://doi.org/10.1016/j.clay.2014.01.003 CrossRef

Wang Y, Xiong Y, Wang J, Zhang X (2017) Ultrasonic-assisted fabrication of montmorillonite-lignin hybrid hydrogel: highly efficient swelling behaviors and super-sorbent for dye removal from wastewater. Colloids Surf A Physicochem Eng Asp 520:903–913. https://doi.org/10.1016/j.colsurfa.2017.02.050 CrossRef

Hameed BH, El-Khaiary MI (2008) Batch removal of malachite green from aqueous solutions by adsorption on oil palm trunk fibre: equilibrium isotherms and kinetic studies. J Hazard Mater 154:237–244. https://doi.org/10.1016/j.jhazmat.2007.10.017 CrossRefPubMed

Li S (2010) Bioresource technology removal of crystal violet from aqueous solution by sorption into semi-interpenetrated networks hydrogels constituted of poly ( acrylic acid-acrylamide-methacrylate ) and amylose. Bioresour Technol 101:2197–2202. https://doi.org/10.1016/j.biortech.2009.11.044 CrossRefPubMed

Saeed A, Sharif M, Iqbal M (2010) Application potential of grapefruit peel as dye sorbent: kinetics, equilibrium and mechanism of crystal violet adsorption. J Hazard Mater 179:564–572. https://doi.org/10.1016/j.jhazmat.2010.03.041 CrossRefPubMed

Jiang F, Dinh DM, Lo HY (2017) Adsorption and desorption of cationic malachite green dye on cellulose nanofibril aerogels. Carbohydr Polym 173:286–294. https://doi.org/10.1016/j.carbpol.2017.05.097 CrossRefPubMed

Goswami M, Phukan P (2017) Enhanced adsorption of cationic dyes using sulfonic acid modified activated carbon. J Environ Chem Eng 5:3508–3517. https://doi.org/10.1016/j.jece.2017.07.016 CrossRef

10.

Demirbas A (2009) Agricultural based activated carbons for the removal of dyes from aqueous solutions : a review. J Hazard Mater 167:1–9. https://doi.org/10.1016/j.jhazmat.2008.12.114 CrossRefPubMed

11.

Tao H, Zhang H, Li J, Ding W (2015) Bioresource technology biomass based activated carbon obtained from sludge and sugarcane bagasse for removing lead ion from wastewater. Bioresour Technol 192:611–617. https://doi.org/10.1016/j.biortech.2015.06.006 CrossRefPubMed

12.

Amran M, Salleh M, Khalid D et al (2011) Cationic and anionic dye adsorption by agricultural solid wastes : a comprehensive review. DES 280:1–13. https://doi.org/10.1016/j.desal.2011.07.019 CrossRef

13.

Khan TA, Chaudhry SA, Ali I (2015) Equilibrium uptake, isotherm and kinetic studies of cd(II) adsorption onto iron oxide activated red mud from aqueous solution. J Mol Liq 202:165–175. https://doi.org/10.1016/j.molliq.2014.12.021 CrossRef

14.

Chen Z, Zhou L, Zhang F, Yu C, Wei Z (2012) Multicarboxylic hyperbranched polyglycerol modified SBA-15 for the adsorption of cationic dyes and copper ions from aqueous media. Appl Surf Sci 258:5291–5298. https://doi.org/10.1016/j.apsusc.2012.02.021 CrossRef

15.

Nakhjiri MT, Bagheri Marandi G, Kurdtabar M (2018) Poly(AA-co-VPA) hydrogel cross-linked with N -maleyl chitosan as dye adsorbent: isotherms, kinetics and thermodynamic investigation. Int J Biol Macromol 117:152–166. https://doi.org/10.1016/j.ijbiomac.2018.05.140 CrossRefPubMed

16.

Bagheri Marandi G, Kermani ZP, Kurdtabar M (2013) Fast and efficient removal of cationic dyes from aqueous solution by collagen-based hydrogel nanocomposites. Polym Plast Technol Eng 52:310–318. https://doi.org/10.1080/03602559.2012.748806 CrossRef

17.

Bagheri Marandi G, Baharloui M, Kurdtabar M, Sharabian LM, Mojarrad MA (2015) Hydrogel with high laponite content as nanoclay: swelling and cationic dye adsorption properties. Res Chem Intermed 41:7043–7058. https://doi.org/10.1007/s11164-014-1797-0 CrossRef

18.

Ayawei N, Ebelegi AN, Wankasi D (2017) Modelling and interpretation of adsorption isotherms. J Chem 2017:1–11. https://doi.org/10.1155/2017/3039817 CrossRef

19.

Foo KY, Hameed BH (2010) Insights into the modeling of adsorption isotherm systems. Chem Eng J 156:2–10. https://doi.org/10.1016/j.cej.2009.09.013 CrossRef

20.

Eswaramma S, Reddy NS, Rao KSVK (2017) Phosphate crosslinked pectin based dual responsive hydrogel networks and nanocomposites: development, swelling dynamics and drug release characteristics. Int J Biol Macromol 103:1162–1172. https://doi.org/10.1016/j.ijbiomac.2017.05.160 CrossRefPubMed

21.

Wachiralarpphaithoon C, Iwasaki Y, Akiyoshi K (2007) Enzyme-degradable phosphorylcholine porous hydrogels cross-linked with polyphosphoesters for cell matrices. Biomaterials 28:984–993. https://doi.org/10.1016/j.biomaterials.2006.10.024 CrossRefPubMed

22.

Thanyacharoen T, Chuysinuan P, Techasakul S, Nooeaid P, Ummartyotin S (2018) Development of a gallic acid-loaded chitosan and polyvinyl alcohol hydrogel composite: release characteristics and antioxidant activity. Int J Biol Macromol 107:363–370. https://doi.org/10.1016/j.ijbiomac.2017.09.002 CrossRefPubMed

23.

Kurdtabar M, Koutenaee RN, Bardajee GR (2018) Synthesis and characterization of a novel pH-responsive nanocomposite hydrogel based on chitosan for targeted drug release. J Polym Res 25:119. https://doi.org/10.1007/s10965-018-1499-1 CrossRef

24.

Bagheri Marandi G, Mahdavinia GR, Ghafary S (2011) Collagen-g-poly(sodium acrylate-co-acrylamide)/sodium montmorillonite superabsorbent nanocomposites: synthesis and swelling behavior. J Polym Res 18:1487–1499. https://doi.org/10.1007/s10965-010-9554-6 CrossRef

25.

Mekhzoum MEM, Essassi EM, Qaiss A, Bouhfid R (2016) Fluorescent bio-nanocomposites based on chitosan reinforced hemicyanine dye-modified montmorillonite. RSC Adv 6:111472–111481. https://doi.org/10.1039/C6RA23320A CrossRef

26.

Phan TT, Bentiss F, Jama C (2015) Structural and anticorrosion performance characterization of phosphosilicate sol-gel coatings prepared from 3-(trimethoxysilyl) propyl methacrylate and bis[2-(methacryloyloxy)ethyl] phosphate. Prog Org Coatings 89:123–131. https://doi.org/10.1016/j.porgcoat.2015.08.011 CrossRef

27.

Saadati K, Kabiri K, Bagheri Marandi G (2014) Synthesis and characterization of Phosphonic-acrylic Organogels. Int J Polym Mater Polym Biomater 63:430–437. https://doi.org/10.1080/00914037.2013.854212 CrossRef

28.

Cengiz A, Bayramgil NP (2013) Phosphonic acid containing superporous hydrogels and their adsorption properties. Soft Mater 11:476–482. https://doi.org/10.1080/1539445X.2012.696574 CrossRef

29.

Shakeri A, Salehi H, Rastgar M (2017) Chitosan-based thin active layer membrane for forward osmosis desalination. Carbohydr Polym 174:658–668. https://doi.org/10.1016/j.carbpol.2017.06.104 CrossRefPubMed

30.

Mittal H, Kumar V, Saruchi RSS (2016) Adsorption of methyl violet from aqueous solution using gum xanthan/Fe3O4 based nanocomposite hydrogel. Int J Biol Macromol 89:1–11. https://doi.org/10.1016/j.ijbiomac.2016.04.050 CrossRefPubMed

31.

Mohammadinezhad A, Bagheri Marandi G, Farsadrooh M, Javadian H (2017) Synthesis of poly(acrylamide-co-itaconic acid)/MWCNTs superabsorbent hydrogel nanocomposite by ultrasound-assisted technique: swelling behavior and Pb (II) adsorption capacity. Ultrason Sonochem 49:1–12. https://doi.org/10.1016/j.ultsonch.2017.12.028 CrossRefPubMed

32.

Khalid I, Ahmad M, Minhas MU, Barkat K (2018) Synthesis and evaluation of chondroitin sulfate based hydrogels of loxoprofen with adjustable properties as controlled release carriers. Carbohydr Polym 181:1169–1179. https://doi.org/10.1016/j.carbpol.2017.10.092 CrossRefPubMed

33.

Nath J, Dolui SK (2018) Applied clay science synthesis of carboxymethyl cellulose-g-poly ( acrylic acid )/ LDH hydrogel for in vitro controlled release of vitamin B 12. Appl Clay Sci 155:65–73. https://doi.org/10.1016/j.clay.2018.01.004 CrossRef

34.

Mohammadzadeh Pakdel P, Peighambardoust SJ (2018) A review on acrylic based hydrogels and their applications in wastewater treatment. J Environ Manag 217:123–143. https://doi.org/10.1016/j.jenvman.2018.03.076 CrossRef

35.

Mandal B, Ray SK (2014) Swelling, diffusion, network parameters and adsorption properties of IPN hydrogel of chitosan and acrylic copolymer. Mater Sci Eng C 44:132–143. https://doi.org/10.1016/j.msec.2014.08.021 CrossRef

36.

Kurdtabar M, Peyvand Kermani Z, Bagheri Marandi G (2015) Synthesis and characterization of collagen-based hydrogel nanocomposites for adsorption of Cd2+, Pb2+, methylene green and crystal violet. Iran Polym J 24:791–803. https://doi.org/10.1007/s13726-015-0368-6 CrossRef

37.

Mittal H, Ray SS (2016) A study on the adsorption of methylene blue onto gum ghatti/TiO2 nanoparticles-based hydrogel nanocomposite. Int J Biol Macromol 88:66–80. https://doi.org/10.1016/j.ijbiomac.2016.03.032 CrossRefPubMed

38.

Bardajee GR, Mizani F, Hosseini SS (2017) pH sensitive release of doxorubicin anticancer drug from gold nanocomposite hydrogel based on poly(acrylic acid) grafted onto salep biopolymer. J Polym Res 24:48. https://doi.org/10.1007/s10965-017-1197-4 CrossRef

39.

Bardajee GR, Azimi S, Sharifi MBAS (2017) Application of central composite design for methyl red dispersive solid phase extraction based on silver nanocomposite hydrogel: microwave assisted synthesis. Microchem J 133:358–369. https://doi.org/10.1016/j.microc.2017.03.037 CrossRef

40.

Dehghani MH, Dehghan A, Najafpoor A (2017) Removing reactive red 120 and 196 using chitosan/zeolite composite from aqueous solutions: kinetics, isotherms, and process optimization. J Ind Eng Chem 51:185–195. https://doi.org/10.1016/j.jiec.2017.03.001 CrossRef

41.

Tseng R-L, Wu F-C, Juang R-S (2010) Characteristics and applications of the Lagergren’s first-order equation for adsorption kinetics. J Taiwan Inst Chem Eng 41:661–669. https://doi.org/10.1016/j.jtice.2010.01.014 CrossRef

42.

Li K, Li Y, Zheng Z (2010) Kinetics and mechanism studies of p-nitroaniline adsorption on activated carbon fibers prepared from cotton stalk by NH4H2PO4 activation and subsequent gasification with steam. J Hazard Mater 178:553–559. https://doi.org/10.1016/j.jhazmat.2010.01.120 CrossRefPubMed

43.

Aflaki Jalali M, Dadvand Koohi A, Sheykhan M (2016) Experimental study of the removal of copper ions using hydrogels of xanthan, 2-acrylamido-2-methyl-1-propane sulfonic acid, montmorillonite: kinetic and equilibrium study. Carbohydr Polym 142:124–132. https://doi.org/10.1016/j.carbpol.2016.01.033 CrossRefPubMed

44.

Mahdavinia GR, Massoudi A, Baghban A, Shokri E (2014) Study of adsorption of cationic dye on magnetic kappa-carrageenan/PVA nanocomposite hydrogels. J Environ Chem Eng 2:1578–1587. https://doi.org/10.1016/j.jece.2014.05.020 CrossRef

45.

Makhado E, Pandey S, Nomngongo PN, Ramontja J (2017) Preparation and characterization of xanthan gum-cl-poly(acrylic acid)/o-MWCNTs hydrogel nanocomposite as highly effective re-usable adsorbent for removal of methylene blue from aqueous solutions. J Colloid Interface Sci 513:700–714. https://doi.org/10.1016/j.jcis.2017.11.060 CrossRefPubMed

46.

Tsai WT, Chang YM, Lai CW, Lo CC (2005) Adsorption of basic dyes in aqueous solution by clay adsorbent from regenerated bleaching earth. Appl Clay Sci 29:149–154. https://doi.org/10.1016/j.clay.2004.10.004 CrossRef

47.

Chang J, Ma J, Ma Q, Zhang D, Qiao N, Hu M, Ma H (2016) Adsorption of methylene blue onto Fe3O4/activated montmorillonite nanocomposite. Appl Clay Sci 119:132–140. https://doi.org/10.1016/j.clay.2015.06.038 CrossRef

48.

Hosseinzadeh H, Zoroufi S, Mahdavinia GR (2015) Study on adsorption of cationic dye on novel kappa-carrageenan/poly(vinyl alcohol)/montmorillonite nanocomposite hydrogels. Polym Bull 72:1339–1363. https://doi.org/10.1007/s00289-015-1340-5 CrossRef

49.

Mahdavinia GR, Aghaie H, Sheykhloie H, Vardini MT, Etemadi H (2013) Synthesis of CarAlg/MMt nanocomposite hydrogels and adsorption of cationic crystal violet. Carbohydr Polym 98:358–365. https://doi.org/10.1016/j.carbpol.2013.05.096 CrossRefPubMed

50.

Mohammadi MJ, Khaniabadi YO, Basiri H et al (2017) Montmorillonite as adsorbent for the removal of methyl red from aqueous solution. Fresenius Environ Bull 26:4088–4096

Titel: Effect of bis[2-(methacryloyloxy)ethyl] phosphate as a crosslinker on poly(AAm-co-AMPS)/Na-MMT hydrogel nanocomposite as potential adsorbent for dyes: kinetic, isotherm and thermodynamic study
verfasst von: Mahdi Taghvay Nakhjiri
Gholam Bagheri Marandi
Mehran Kurdtabar
Publikationsdatum: 01.11.2018
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 11/2018
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-018-1625-0

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 11/2018

Preparation of chlorosulfonated polyethylene by liquid-solid method and comparison with industrial products

Poly(vinyl pyrrolidone) sub-microfibers produced by solution blow spinning

Effects of weathering aging on mechanical and thermal properties of injection molded glass fiber reinforced polypropylene composites

Synthesis of hydroxypropylated debranched pea starch with high substitution degree in an ionic liquid, and its characterization and properties

Photo-thermally cured eugenol-derived epoxy resins by simultaneous thiol-ene/thiol-epoxy/thiol-maleimide triple “click” reactions

Unique behavior of in-situ generated nanosilica particles on physico-mechanical properties of fluoroelastomer

Premium Partner

Marktübersichten