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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 19/2019

03.09.2019

Effect of CdS shell thickness on the photocatalytic properties of TiO2@CdS core–shell nanorod arrays

verfasst von: Zhu Shi, Jiani Liu, Huixia Lan, Xiuyan Li, Bangyao Zhu, Jinghai Yang

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 19/2019

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Abstract

Rutile TiO2 nanorod arrays (NRAs) with average diameter approximately 80 nm were first synthesized by solvothermal method using Ti foil as both titanium source and substrate. And then TiO2@CdS core–shell heterostructure NRAs were fabricated via subsequent successive ionic layer adsorption and reaction (SILAR) route using the TiO2 NRAs as precursor. The thicknesses of CdS shell varied from 4 to 18 nm by changing the times of SILAR cycle. The photocatalytic performances of pure TiO2 and all TiO2@CdS NRAs were investigated on the degradation of rhodamine B (RhB) aqueous solution under simulated sunlight irradiation. Compared to pure TiO2 NRAs, all TiO2@CdS NRAs displayed superior photocatalytic activities, and the optimal CdS shell thickness of TiO2@CdS NRAs was about 11 nm. A possible Z-scheme electron transfer mechanism for TiO2@CdS NRAs nanocomposite with the enhanced photocatalytic performance was provided.
Vorheriger Artikel Increasing sensitivity of ZnO nanoparticles by hydrogenation and sensing reaction mechanism
Nächster Artikel A highly selective Ag+ sensor based on 8-hydroxyquinoline functionalized graphene oxide -silica nanosheet and its logic gate behaviour

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Literatur
1.
Z. Zhu, Z.Y. Lu, D.D. Wang, X. Tang, Y.S. Yan, Construction of high-dispersed Ag/Fe3O4/g-C3N4 photocatalyst by selective photo-deposition and improved photocatalytic activity. Appl. Catal. B 182, 115–122 (2016)
2.
D.J. Martin, K. Qiu, S.A. Shevlin, A.D. Handoko, X. Handoko, Highly efficient photocatalytic h2 evolution from water using visible light and structure-controlled graphitic carbon nitride. Angew. Chem. Int. Ed. 53, 9240–9245 (2014)
3.
M. Rafatullah, O. Sulaiman, R. Hashim, A. Ahmad, Adsorption of methylene blue on lowcost adsorbents: a review. J. Hazard. Mater. 177, 70–80 (2010)
4.
C. Namasivayam, D. Kavitha, Removal of Congo Red from water by adsorption onto activated carbon prepared from coir pith, an agricultural solid waste. Dyes Pigm. 54, 47–58 (2002)
5.
J. Zhang, L. Huang, H. Jin, Y. Sun, X. Ma, Constructing two-dimension MoS2/Bi2WO6 core-shell heterostructure as carriers transfer channel for enhancing photocatalytic activity. Mater. Res. Bull. 85, 140–146 (2017)
6.
Z.F. Jiang, D.L. Jiang, Z.X. Yan, D. Liu, A new visible light active multifunctional ternary composite based on TiO2-In2O3 nanocrystals heterojunction decorated porous graphitic carbon nitride for photocatalytic treatment of hazardous pollutant and H2 evolution. Appl. Catal. B 170, 195–205 (2015)
7.
X. Li, T. Xia, C.H. Xu, J. Murowchick, X.B. Chen, Synthesis and photoactivity of nanostructured CdS-TiO2 composite catalysts. Catal. Today 225, 64–73 (2014)
8.
X. Chen, S.S. Mao, Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications. Chem. Rev. 107, 2891–2959 (2007)
9.
C. Zhao, H. Luo, F. Chen, P. Zhang, L. Yi, K. You, A novel composite of TiO2 nanotubes with remarkably high efficiency for hydrogen production in solardriven water splitting. Energ. Environ. Sci. 7, 1700–1707 (2014)
10.
C.B.D. Marien, T. Cottineau, D. Roberta, P. Drogui, TiO2 nanotube arrays: influence of tube length on the photocatalytic degradation of Paraquat. Appl. Catal. B 194, 1–6 (2016)
11.
D. Reyes-Coronado, G. Rodr´ıguez-Gattorno, M.E. Espinosa-Pesqueira, C. Cab, R. Coss, G. Oskam, Phase-pure TiO2 nanoparticles: anatase, brookite and rutile. Nanotechnology 19, 145605 (2008)
12.
M. Dawson, C. Ribeiro, M.R. Morelli, Rutile supported anatase nanostructured films as photocatalysts for the degradation of water contaminants. Ceram. Int. 42, 808–819 (2016)
13.
K. Ozawa, S. Yamamoto, R. Yukawa, R.Y. Liu, N. Terashima, Y. Natsui, H. Kato, K. Mase, I. Matsuda, Correlation between photocatalytic activity and carrier lifetime: acetic acid on single-crystal surfaces of anatase and rutile TiO2. J. Phys. Chem. C 122, 9562–9569 (2018)
14.
X. Yang, L. Wu, L. Ma, X. Li, T. Wang, S. Liao, Pd nano-particles (NPs) confined in titanate nanotubes (TNTs) for hydrogenation of cinnamaldehyde. Catal. Commun. 59, 184–188 (2015)
15.
R. Daghrir, P. Drogui, D. Robert, Modified TiO2 for environmental photocatalytic applications: a review. Ind. Eng. Chem. Res. 52, 3581–3599 (2013)
16.
P. Kar, S. Zheng, Y. Zhang, E. Vahidzadeh, A. Manuel, R. Kisslinger, K. Alam, U. Thakur, N. Mahdi, P. Kumar, K. Shankar, High rate CO2 photoreduction using flame annealed TiO2 nanotubes. Appl. Catal. B 243, 522–536 (2019)
17.
M. Kobielusz, K. Pilarczyk, E. Swietek, K. Szaciłowski, W. Macyk, Spectroelectrochemical analysis of TiO2 electronic states-implications on the photocatalytic activity of anatase and rutile. Catal. Today 309, 35–42 (2018)
18.
U. Nwankwo, R. Bucher, A.B.C. Ekwealor, M. Maaza, F.I. Ezema, Synthesis and characterizations of rutile-TiO2 nanoparticles derived from chitin for potential photocatalytic applications. Vacuum 161, 49–54 (2019)
19.
A. Mohammadpour, B.D. Wiltshire, Y. Zhang, S. Farsinezhad, A.M. Askar, R. Kisslinger, Y. Ren, P. Kar, K. Shankar, 100-fold improvement in carrier drift mobilities in alkanephosphonate-passivated monocrystalline TiO2 nanowire arrays. Nanotechnology 28, 144001 (2017)
20.
U.K. Thakur, A.M. Askar, R. Kisslinger, B.D. Wiltshire, P. Kar, K. Shankar, Halide perovskite solar cells using monocrystalline TiO2 nanorod arrays as electron transport layers: impact of nanorod morphology. Nanotechnology 28, 274001 (2017)
21.
D. Sarkar, C.K. Ghosh, S. Mukherjee, Three dimensional Ag2O/TiO2 type-II (p-n) nanoheterojunctions for superior photocatalytic activity. ACS Appl. Mater. Interfaces. 5, 331–337 (2013)
22.
Y.S. Chang, M. Choi, M. Baek, P.Y. Hsieh, K.J. Yong, Y.J. Hsu, CdS/CdSe co-sensitized brookite H: TiO2 nanostructures: charge carrier dynamics and photoelectrochemical hydrogen generation. Appl. Catal. B 225, 379–385 (2018)
23.
T. Lv, L.K. Pan, X.J. Liu, Z. Sun, Visible-light photocatalytic degradation of methyl orange by CdS-TiO2-Au composites synthesized via microwave-assisted reaction. Electrochim. Acta 83, 216–220 (2012)
24.
N. Mohaghegh, B. Eshaghi, E. Rahimi, M.R. Gholami, Ag2CO3 sensitized TiO2 nanoparticles prepared in ionic liquid medium: a new Ag2CO3/TiO2/RTIL heterostructure with highly efficient photocatalytic activity. J. Mol. Catal. A 406, 152–158 (2015)
25.
J. Zhang, X.M. Ma, L.L. Zhang, Z.D. Lu, Constructing a novel n-p-n dual heterojunction between anatase TiO2 nanosheets with coexposed 101}, {001 facets and porous ZnS for enhancing photocatalytic activity. J. Phys. Chem. C 121, 6133–6140 (2017)
26.
Y.B. Liu, H.B. Zhou, B.X. Zhou, J.H. Li, H.C. Chen, J.J. Wang, J. Bai, Highly stable CdS-modified short TiO2 nanotube array electrode for efficient visible-light hydrogen generation. Int. J. Hydrog. Energy 36, 167–174 (2011)
27.
Y. Lin, J. Song, Y. Ding, S. Lu, Z.L. Wang, Alternating the output of a CdS nanowire nanogenerator by a white-light-stimulated optoelectronic effect. Adv. Mater. 20, 3127–3130 (2008)
28.
Y. Liu, P. Zhang, B.Z. Tian, J.L. Zhang, Enhancing the photocatalytic activity of CdS nanorods for selective oxidation of benzyl alcohol by coating amorphous TiO2 shell layer. Catal. Commun. 70, 30–33 (2015)
29.
W.H. Dong, F. Pan, L.L. Xu, M.R. Zheng, C.H. Sow, K. Wu, G.Q. Xu, W. Chen, Facile synthesis of CdS@TiO2 core-shell nanorods with controllable shell thickness and enhanced photocatalytic activity under visible light irradiation. Appl. Surf. Sci. 349, 279–286 (2015)
30.
C. Su, C. Shao, Y. Liu, Electrospun nanofibers of TiO2/CdS heteroarchitectures with enhanced photocatalytic activity by visible light. J. Colloids Interface Sci. 359, 220–227 (2011)
31.
X.Y. Guo, C.F. Chen, W.Y. Song, X. Wang, W.H. Di, W.P. Qin, CdS embedded TiO2 hybrid nanospheres for visible light photocatalysis. J. Mol. Catal. A 387, 1–6 (2014)
32.
P. Gao, J. Liu, T. Zhang, D.D. Sun, W. Ng, Hierarchical TiO2/CdS “spindle-like” composite with high photodegradation and antibacterial capability under visible light irradiation. J. Hazard. Mater. 229–230, 209–216 (2012)
33.
Y. Zhang, Y. Gao, X.H. Xia, Q.R. Deng, M.L. Guo, Structural engineering of thin films of vertically aligned TiO2 nanorods. Mater. Lett. 64, 1614–1617 (2010)
34.
H. Pan, J.S. Qian, A. Yu, M.G. Xu, TiO2 wedgy nanotubes array flims for photovoltaic enhancement. Appl. Surf. Sci. 257, 5059–5063 (2011)
35.
Y.T. Xue, Z.S. Wu, X.F. He, X. Yang, X.Q. Chen, Z.Z. Gao, Constructing a Z-scheme heterojunction of egg-like core@shell CdS@TiO2 photocatalyst via a facile reflux method for enhanced photocatalytic performance. Nanomaterials 9, 222 (2019)
36.
C.J. Liu, Y.H. Yang, J. Li, S. Chen, Phase transformation synthesis of TiO2/CdS heterojunction film with high visible-light photoelectrochemical activity. Nanotechnology 29, 265401 (2018)
37.
E. Üzer, P. Kumar, R. Kisslinger, P. Kar, U.K. Thakur, S. Zeng, K. Shankar, T. Nilges, Vapor deposition of semiconducting phosphorus allotropes into TiO2 nanotube arrays for photoelectrocatalytic water splitting. ACS Appl Nano Mater 26, 3358–3367 (2019)
38.
M. Xi, Y.L. Zhang, L.Z. Long, X.J. Li, Controllable hydrothermal synthesis of rutile TiO2 hollow nanorod arrays on TiCl4 pretreated Ti foil for DSSC application. J. Solid State Chem. 219, 118–126 (2014)
39.
P. Kumar, U.K. Thakur, K. Alam, P. Kar, R. Kisslinger, S. Zeng, S. Patel, K. Shankar, Arrays of TiO2 nanorods embedded with fluorine doped carbon nitride quantum dots (CNFQDs) for visible light driven water splitting. Carbon 137, 174–187 (2018)
40.
P. Kar, Y. Zhang, S. Farsinezhad, A. Mohammadpour, B.D. Wiltshire, H. Sharma, K. Shankar, Rutile phase n-and p-type anodic titania nanotube arrays with square-shaped pore morphologies. Chem. Commun. 51, 7816–7819 (2015)
41.
S.S. Mali, S.K. Desai, D.S. Dalavi, C.A. Betty, P.N. Bhosalea, P.S. Patil, CdS sensitized TiO2 nanocorals: hydrothermal synthesis, characterization, application. Photochem. Photobiol. Sci. 10, 1652–1658 (2011)
42.
P.P. Zhou, Y. Xie, J. Fang, Y. Ling, C.L. Yu, X.M. Liu, Y.H. Dai, Y.C. Qin, D. Zhou, CdS quantum dots confined in mesoporous TiO2 with exceptional photocatalytic performance for degradation of organic pollutants. Chemosphere 178, 1–10 (2017)
43.
N. Qin, J.H. Xiong, R.W. Liang, Y.H. Liu, S.Y. Zhang, Y.H. Li, Z.H. Li, L. Wu, Highly efficient photocatalytic H2 evolution over MoS2/CdS-TiO2 nanofibers prepared by an electrospinning mediated photodeposition method. Appl. Catal. B 202, 374–380 (2017)
44.
S. David, M.A. Mahadik, H.S. Chung, J. Ryu, J.S. Jang, Facile hydrothermally synthesized a novel CdS nanoflower/rutile-TiO2 nanorod heterojunction photoanode used for photoelectrocatalytic hydrogen generation. ACS Sustain. Chem. Eng. 5, 7537–7548 (2017)
45.
S.Y. Li, Z.L. Liu, G.X. Xiang, B.H. Ma, X.D. Meng, Y.L. He, Influence of calcination temperature on the photocatalytic performance of the hierarchical TiO2 pinecone-like structure decorated with CdS nanoparticles. Ceram. Int. 45, 767–776 (2019)
46.
Y.F. Li, L.L. Wang, Z.L. Li, Y.L. Liu, Z.Y. Peng, Synthesis and photocatalytic property of V2O5@TiO2 core-shell microspheres towards gaseous benzene. Catal. Today 321–322, 164–171 (2019)
47.
H.Y. Yang, Z.L. Liu, K. Wang, S.T. Pu, S.N. Yang, L. Yang, A facile synthesis of TiO2-CdS heterostructures with enhanced photocatalytic activity. Catal. Lett. 147, 2581–2591 (2017)
48.
P.S. Shinde, J.W. Park, M.A. Mahadik, J. Ryu, J.H. Park, Y.J. Yi, J.S. Jang, Fabrication of efficient CdS nanoflowers-decorated TiO2 nanotubes array heterojunction photoanode by a novel synthetic approach for solar hydrogen production. Int. J. Hydrog. Energy 46, 21078–21087 (2016)
49.
G.D. Yang, B.L. Yang, T.C. Xiao, Z.F. Yan, One-step solvothermal synthesis of hierarchically porous nanostructured CdS/TiO2 heterojunction with higher visible light photocatalytic activity. Appl. Surf. Sci. 283, 402–410 (2013)
50.
M. Fujishima, Y. Nakabayashi, K. Takayama, H. Kobayashi, H. Tada, High coverage formation of CdS quantum dots on TiO2 by the photocatalytic growth of preformed seeds. J. Phys. Chem. C 120, 17365–17371 (2016)
51.
X.Y. Li, D.X. Liu, Z. Shi, J.H. Yang, Effect of Ag2S shell thickness on the photocatalytic properties of ZnO/Ag2S core-shell nanorod arrays. J. Mater. Sci. 54, 1226–1235 (2019)
52.
X.Y. Li, X. Li, B.Y. Zhu, J.S. Wang, H.X. Lan, X.B. Chen, Synthesis of porous ZnS ZnO and ZnS/ZnO nanosheets and their photocatalytic properties. RSC Adv. 7, 30956–30962 (2017)
53.
Y.H. Zhang, N. Zhang, Z.R. Tang, Y.J. Xu, Identification of Bi2WO6 as a highly selective visible-light photocatalyst toward oxidation of glyceroltodihy-droxyacetone in water. Chem. Sci. 4, 1820–1824 (2013)
54.
C.L. Cao, C.G. Hu, W.D. Shen, S.X. Wang, Y.S. Tian, X. Wang, Synthesis and characterization of TiO2/CdS core–shell nanorod arrays and their photoelectrochemical property. J. Alloys Compd. 523, 139–145 (2012)
55.
X. Li, C.Y. Liu, D.Y. Wu, J.Z. Li, P.W. Huo, H.Q. Wang, Improved charge transfer by size-dependent plasmonic Au on C3N4 for efficient photocatalytic oxidation of RhB and CO2 reduction. Chin. J. Catal. 40, 928–939 (2019)
56.
D. Li, C. Shen, J.Z. Liu, Y.J. Li, X.H. Zhou, P.W. Song, H.Q. Huo, Y.S. Wang, Yan, Fabricated rGO-modified Ag2S nanoparticles/g-C3N4 nanosheets photocatalyst for enhancing photocatalytic activity. J. Colloids Interface Sci. 554, 468–478 (2019)
57.
Y.Y. Lu, Y.Y. Zhang, J. Zhang, Y. Shi, Z. Li, Z.C. Feng, C. Li, In situ loading of CuS nanoflowers on rutile TiO2 surface and their improved photocatalytic performance. Appl. Surf. Sci. 370, 312–319 (2016)
58.
X.Y. Li, D.X. Liu, B.Y. Zhu, J. Wang, J.H. Lang, Facile preparation of ZnO/Ag2CO3 heterostructured nanorod arrays with improved photocatalytic activity. J. Phys. Chem. Solids 125, 96–102 (2019)
59.
D.D. Wang, D.L. Han, Z. Shi, J. Wang, J.H. Yang, X.Y. Li, H. Song, Optimized design of three-dimensional multi-shell Fe3O4/SiO2/ZnO/ZnSe microspheres with type II heterostructure for photocatalytic applications. Appl. Catal. B 227, 61–69 (2018)
60.
H.R. Liu, H.F. Zhai, C.J. Hu, J.E. Yang, Z.Y. Liu, Hydrothermal synthesis of In2O3 nanoparticles hybrid twins hexagonal disk ZnO heterostructures for enhanced photocatalytic activities and stability. Nanoscale Res. Lett. 12, 466–476 (2017)
61.
H.R. Liu, Y.C. Hu, Z.X. Zhang, X.G. Liu, H.S. Jia, B.S. Xu, Synthesis of spherical Ag/ZnO heterostructural composites with excellent photocatalytic activity under visible light and UV irradiation. Appl. Surf. Sci. 355, 644–652 (2015)
62.
H.X. Zhao, S. Cui, L. Yang, G.D. Li, N. Li, X.T. Li, Synthesis of hierarchically meso-macroporous TiO2/CdS heterojunction photocatalysts with excellent visible-light photocatalytic activity. J. Colloids Interface Sci. 23, 4246–4254 (2013)
63.
W. Wu, C.Z. Jiang, V.A.L. Roy, Recent progress in magnetic iron oxide-semiconductor composite nanomaterials as promising photocatalysts. Nanoscale 7, 38–58 (2015)
64.
Y.X. Zhu, Y.F. Wang, Z. Chen, L.S. Qin, L.B. Yang, L. Zhu, Visible light induced photocatalysis on CdS quantum dots decorated TiO2 nanotube arrays. Appl. Catal. A 498, 164–171 (2015)
Metadaten
Titel
Effect of CdS shell thickness on the photocatalytic properties of TiO2@CdS core–shell nanorod arrays
verfasst von
Zhu Shi
Jiani Liu
Huixia Lan
Xiuyan Li
Bangyao Zhu
Jinghai Yang
Publikationsdatum
03.09.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 19/2019
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-02118-x

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