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Journal of Materials Science
Erschienen in: Journal of Materials Science 21/2015

01.11.2015 | Original Paper

Effect of cellulose nanocrystals on the properties of pea starch–poly(vinyl alcohol) blend films

verfasst von: A. Cano, E. Fortunati, M. Cháfer, C. González-Martínez, A. Chiralt, J. M. Kenny

Erschienen in: Journal of Materials Science | Ausgabe 21/2015

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Abstract

Incorporation of cellulose nanocrystals (CNCs) to pea starch–poly(vinyl alcohol) (PVA) (1:2 ratio) blend films was carried out in order to improve their mechanical and barrier properties and film stability throughout storage, thus overcoming some drawbacks of starch based films. Different ratios (1, 3 and 5 %) of CNC were used and structural, thermal and physical (barrier, mechanical and optical) properties were analysed in comparison to the control film without CNC. Incorporation of CNC enhanced phase separation of polymers in two layers. The upper PVA-rich phase contained lumps of starch which emerged from the film surface, thus reducing the film gloss. CNCs were dispersed in both polymeric phases as aggregates, whose size increased with the CNC ratio rise. CNC addition did not implied changes in water vapour barrier of the films, but they became slightly stiffer and more stretchable, while crystallization of PVA was partially inhibited.
Vorheriger Artikel Characterization of superconducting Fe y (Se1−x Te x ) thin films deposited on MgO substrates by sputtering
Nächster Artikel Electronic structure and optical properties of Bi,N co-doped SnO2

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Metadaten
Titel
Effect of cellulose nanocrystals on the properties of pea starch–poly(vinyl alcohol) blend films
verfasst von
A. Cano
E. Fortunati
M. Cháfer
C. González-Martínez
A. Chiralt
J. M. Kenny
Publikationsdatum
01.11.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 21/2015
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-015-9249-9

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