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Erschienen in: Journal of Materials Science: Materials in Electronics 6/2015

01.06.2015

Effect of Cr incorporation on the properties of TiO2 nanoparticles synthesized by microwave technique

verfasst von: K. Vijayalakshmi, S. David Jereil

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 6/2015

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Abstract

The present work focus on the development of an effective process for the production of undoped and Cr doped TiO2 nano powders by microwave technique. The influence of Cr doping on the structure, phase, vibrational bands and optical properties of TiO2 were discussed. The X-ray diffraction patterns of the nanoparticles revealed preferentially oriented (101) anatase phase for TiO2. Fourier transform infrared spectral analysis confirmed the presence of anatase phase for both pure and Cr Doped TiO2. The UV–Visible spectra revealed the increase in absorption band with Cr doping when compared with undoped TiO2 nano particles, and optical band gap decreased slightly with Cr doping. SEM micrographs show spherical shaped grains of TiO2 with high homogeneity, with a subsequent reduction in agglomeration of particles with Cr doping suggesting its potential application for better photo catalytic activity.

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Literatur
1.
Zurück zum Zitat T. Ihara, M. Miyoshi, M. Ando, S. Sugihara, Y. Iriyama, Preparation of a visible-light-active TiO2 photocatalyst by RF plasma treatment. J. Mater. Sci. 3(6), 4201–4207 (2001)CrossRef T. Ihara, M. Miyoshi, M. Ando, S. Sugihara, Y. Iriyama, Preparation of a visible-light-active TiO2 photocatalyst by RF plasma treatment. J. Mater. Sci. 3(6), 4201–4207 (2001)CrossRef
2.
Zurück zum Zitat R. Cai, R. Baba, K. Hashimoto, Y. Kubota, A. Fujishima, photoelectrochemistry of TiO2 particles: efficient electron transfer from the TiO2 particles to a redox enzyme. J. Electroanal. Chem. 360, 237–245 (1993)CrossRef R. Cai, R. Baba, K. Hashimoto, Y. Kubota, A. Fujishima, photoelectrochemistry of TiO2 particles: efficient electron transfer from the TiO2 particles to a redox enzyme. J. Electroanal. Chem. 360, 237–245 (1993)CrossRef
3.
Zurück zum Zitat Y. Wang, Y. Hao, H. Cheng, J. Ma, X. Bin, W. Li, S. Cai, The photo electrochemistry of transition metal-ion doped TiO2 nanocrystalline electrodes and higher solar cell conversion efficiency based on Zn2+-doped TiO2 electrode. J. Mater. Sci. 34, 2773–2779 (1999)CrossRef Y. Wang, Y. Hao, H. Cheng, J. Ma, X. Bin, W. Li, S. Cai, The photo electrochemistry of transition metal-ion doped TiO2 nanocrystalline electrodes and higher solar cell conversion efficiency based on Zn2+-doped TiO2 electrode. J. Mater. Sci. 34, 2773–2779 (1999)CrossRef
4.
Zurück zum Zitat K. Vijayalakshmin, S.D. Jereil, Enhanced ethanol sensing performance of Fe: TiO2 nanowires and their mechanism of sensing at room temperature. Ceram. Int. 41, 3220–3226 (2015)CrossRef K. Vijayalakshmin, S.D. Jereil, Enhanced ethanol sensing performance of Fe: TiO2 nanowires and their mechanism of sensing at room temperature. Ceram. Int. 41, 3220–3226 (2015)CrossRef
5.
Zurück zum Zitat S. Akbar, P. Duta, C. Lee, High temperature ceramic gas sensor. Int. J. Appl. Ceram. Technol. 3, 302–311 (2006)CrossRef S. Akbar, P. Duta, C. Lee, High temperature ceramic gas sensor. Int. J. Appl. Ceram. Technol. 3, 302–311 (2006)CrossRef
6.
Zurück zum Zitat M. Pfanzelt, P. Kubiak, M. Fleischhammer, M. Wohlfahrt-Mehrens, TiO2 rutile—an alternative anode material for safe lithium-ion batteries. J. Power Sources 196, 6815–6821 (2011)CrossRef M. Pfanzelt, P. Kubiak, M. Fleischhammer, M. Wohlfahrt-Mehrens, TiO2 rutile—an alternative anode material for safe lithium-ion batteries. J. Power Sources 196, 6815–6821 (2011)CrossRef
7.
Zurück zum Zitat S. Šegota, L. Ćurković, D. Ljubas, V. Svetličić, I.F. Houra, N. Tomašić, Synthesis characterization and photocatalytic properties of sol–gel TiO2 films. Ceram. Int. 37, 1153–1160 (2011)CrossRef S. Šegota, L. Ćurković, D. Ljubas, V. Svetličić, I.F. Houra, N. Tomašić, Synthesis characterization and photocatalytic properties of sol–gel TiO2 films. Ceram. Int. 37, 1153–1160 (2011)CrossRef
8.
Zurück zum Zitat S. Xin, W. QingLiu, X. Zhan, J. Wu, S. Wei, Z. Guo, Advanced titania nanostructures and composites for lithium ion battery. J. Mater. Sci. 47, 2519–2534 (1998) S. Xin, W. QingLiu, X. Zhan, J. Wu, S. Wei, Z. Guo, Advanced titania nanostructures and composites for lithium ion battery. J. Mater. Sci. 47, 2519–2534 (1998)
9.
Zurück zum Zitat W. Choi, A. Termin, M.R. Hoffmann, The role of metal ion dopants in quantum-sized TiO2: correlation between photoreactivity and charge carrier recombination dynamics. J. Phys. Chem. 98, 13669–13679 (1994)CrossRef W. Choi, A. Termin, M.R. Hoffmann, The role of metal ion dopants in quantum-sized TiO2: correlation between photoreactivity and charge carrier recombination dynamics. J. Phys. Chem. 98, 13669–13679 (1994)CrossRef
10.
Zurück zum Zitat Y. Zhang, Y. Shen, G. Feng, W. Mingming, Y. Xie, J. Zhang, Influence of Fe ions in characteristics and optical properties of mesoporous titanium oxide thin films. Appl. Surf. Sci. 256(1), 85–89 (2009)CrossRef Y. Zhang, Y. Shen, G. Feng, W. Mingming, Y. Xie, J. Zhang, Influence of Fe ions in characteristics and optical properties of mesoporous titanium oxide thin films. Appl. Surf. Sci. 256(1), 85–89 (2009)CrossRef
11.
Zurück zum Zitat F. Yakuphanoglu, M. Okutan, K. Korkmaz, The electrical conductivity and microstructure properties of Ni-doped TiO2 ceramic. J. Alloys Compd. 450, 39–43 (2008)CrossRef F. Yakuphanoglu, M. Okutan, K. Korkmaz, The electrical conductivity and microstructure properties of Ni-doped TiO2 ceramic. J. Alloys Compd. 450, 39–43 (2008)CrossRef
12.
Zurück zum Zitat H. Yamashita, M. Harada, J. Misaka, M. Takeuchi, B. Neppolian, M. Anpo, Photocatalytic degradation of organic compounds diluted in water using visible light-responsive metal ion-implanted TiO2 catalysts: Fe ion-implanted TiO2. Catal. Today 84, 191–196 (2003)CrossRef H. Yamashita, M. Harada, J. Misaka, M. Takeuchi, B. Neppolian, M. Anpo, Photocatalytic degradation of organic compounds diluted in water using visible light-responsive metal ion-implanted TiO2 catalysts: Fe ion-implanted TiO2. Catal. Today 84, 191–196 (2003)CrossRef
13.
Zurück zum Zitat F. Li, L.-x. Guan, M.-l. Dai, J.-j. Feng, M.-m. Yao, Effects of V and Zn co doping on the microstructures and photocatalytic activities of nanocrystalline TiO2 films. Ceram. Int. 39, 7395–7400 (2013)CrossRef F. Li, L.-x. Guan, M.-l. Dai, J.-j. Feng, M.-m. Yao, Effects of V and Zn co doping on the microstructures and photocatalytic activities of nanocrystalline TiO2 films. Ceram. Int. 39, 7395–7400 (2013)CrossRef
14.
Zurück zum Zitat A. Hajjaji, M. Gaidi, B. Bessais, M.A. El Khakani, Effect of Cr incorporation on the structural and optoelectronic properties of TiO2: Cr deposited by means of a magnetron co-sputtering process. Appl. Surface Sci. 257, 10351–10357 (2011)CrossRef A. Hajjaji, M. Gaidi, B. Bessais, M.A. El Khakani, Effect of Cr incorporation on the structural and optoelectronic properties of TiO2: Cr deposited by means of a magnetron co-sputtering process. Appl. Surface Sci. 257, 10351–10357 (2011)CrossRef
15.
Zurück zum Zitat D. Reyes-coronado, G. Rodriguez-gattorono, M.E. Espinosa-Pesqueira, C. Cab, R. de Coss, G. Oskam, Phase-pure TiO2 nanoparticles: anatase, brookite and rutile. Nanotechnology 19, 145605 (2008)CrossRef D. Reyes-coronado, G. Rodriguez-gattorono, M.E. Espinosa-Pesqueira, C. Cab, R. de Coss, G. Oskam, Phase-pure TiO2 nanoparticles: anatase, brookite and rutile. Nanotechnology 19, 145605 (2008)CrossRef
16.
Zurück zum Zitat M. Hamadanian, A.S. Sarabi, A.M. Mehra, V. Jabbari, Photocatalyst Cr-doped titanium oxide nanoparticles: fabrication, characterization, and investigation of the effect of doping on methyl orange dye degradation. Mater. Sci. Semicond. Process. 21, 161–166 (2014)CrossRef M. Hamadanian, A.S. Sarabi, A.M. Mehra, V. Jabbari, Photocatalyst Cr-doped titanium oxide nanoparticles: fabrication, characterization, and investigation of the effect of doping on methyl orange dye degradation. Mater. Sci. Semicond. Process. 21, 161–166 (2014)CrossRef
17.
Zurück zum Zitat X. Li, Z. Guoa, T. He, The doping mechanism of Cr into TiO2 and its influence on the photocatalytic performance. Phys. Chem. Chem. Phys. 15, 20037–20045 (2013)CrossRef X. Li, Z. Guoa, T. He, The doping mechanism of Cr into TiO2 and its influence on the photocatalytic performance. Phys. Chem. Chem. Phys. 15, 20037–20045 (2013)CrossRef
18.
Zurück zum Zitat S.N.R. Inturi, T. Boningari, M. Suidan, P.G. Smirniotis, Visible-light-induced photodegradation of gas phase acetonitrile using aerosol-made transition metal (V, Cr, Fe Co, Mn, Mo, Ni, Cu, Y, Ce, and Zr) doped TiO2. Appl. Catal. B Environ. 144, 333–342 (2014)CrossRef S.N.R. Inturi, T. Boningari, M. Suidan, P.G. Smirniotis, Visible-light-induced photodegradation of gas phase acetonitrile using aerosol-made transition metal (V, Cr, Fe Co, Mn, Mo, Ni, Cu, Y, Ce, and Zr) doped TiO2. Appl. Catal. B Environ. 144, 333–342 (2014)CrossRef
19.
Zurück zum Zitat Y. Gao, Y. Masuda, W.-S. Seo, H. Ohta, K. Koumoto, TiO2 nanoparticles prepared using an aqueous peroxotitanate solution. Ceram. Int. 30, 1365–1368 (2004)CrossRef Y. Gao, Y. Masuda, W.-S. Seo, H. Ohta, K. Koumoto, TiO2 nanoparticles prepared using an aqueous peroxotitanate solution. Ceram. Int. 30, 1365–1368 (2004)CrossRef
20.
Zurück zum Zitat M. Hirano, T. Joji, M. Inagaki, H. Iwata, Direct formation of iron (III)-doped titanium oxide (Anatase) by thermal hydrolysis and its structural property. J. Am. Ceram. Soc. 87, 35–41 (2004)CrossRef M. Hirano, T. Joji, M. Inagaki, H. Iwata, Direct formation of iron (III)-doped titanium oxide (Anatase) by thermal hydrolysis and its structural property. J. Am. Ceram. Soc. 87, 35–41 (2004)CrossRef
21.
Zurück zum Zitat B. Tian, C. Li, J. Zhang, One-step preparation, characterization and visible-light photocatalytic activity of Cr-doped TiO2 with anatase and rutile bicrystalline phases. Chem. Eng. J. 191, 402–409 (2012)CrossRef B. Tian, C. Li, J. Zhang, One-step preparation, characterization and visible-light photocatalytic activity of Cr-doped TiO2 with anatase and rutile bicrystalline phases. Chem. Eng. J. 191, 402–409 (2012)CrossRef
22.
Zurück zum Zitat K. Vijayalakshmi, K. Karthick, Influence of Mg doping on the microstructure and PL emission of wurtzite ZnO synthesized by microwave processing. J. Mater. Sci. Mater. Electron. 24, 2067–2071 (2013)CrossRef K. Vijayalakshmi, K. Karthick, Influence of Mg doping on the microstructure and PL emission of wurtzite ZnO synthesized by microwave processing. J. Mater. Sci. Mater. Electron. 24, 2067–2071 (2013)CrossRef
23.
Zurück zum Zitat K. Vijayalakshmi, K. Karthick, High quality ZnO/CuO nanocomposites synthesized by microwave assisted reaction. J. Mater. Sci. Mater. Electron. 25, 832–836 (2014)CrossRef K. Vijayalakshmi, K. Karthick, High quality ZnO/CuO nanocomposites synthesized by microwave assisted reaction. J. Mater. Sci. Mater. Electron. 25, 832–836 (2014)CrossRef
24.
Zurück zum Zitat K. Vijayalakshmi, K. Karthick, D. Gopalakrishna, Influence of annealing on the structural, optical and photoluminescence properties of ZnO thin films for enhanced H2 sensing application. Ceram. Int. 39, 4749–4756 (2013)CrossRef K. Vijayalakshmi, K. Karthick, D. Gopalakrishna, Influence of annealing on the structural, optical and photoluminescence properties of ZnO thin films for enhanced H2 sensing application. Ceram. Int. 39, 4749–4756 (2013)CrossRef
25.
Zurück zum Zitat T. Ikeda, T. Nomoto, K. Eda, Y. Mizutani, H. Kato, A. Kudo, H. Onishi, Photoinduced dynamics of TiO2 doped with Cr and Sb. J. Phys. Chem. C 112, 1167–1173 (2008)CrossRef T. Ikeda, T. Nomoto, K. Eda, Y. Mizutani, H. Kato, A. Kudo, H. Onishi, Photoinduced dynamics of TiO2 doped with Cr and Sb. J. Phys. Chem. C 112, 1167–1173 (2008)CrossRef
26.
Zurück zum Zitat B.M. Reddy, I. Ganesh, Characterization of La2O3–TiO2 and V2O5/La2O3–TiO2 catalyst and their activity for synthesis of 2, 6-dimethylphenol. J. Mol. Catal. A Chem. 169, 207–223 (2001)CrossRef B.M. Reddy, I. Ganesh, Characterization of La2O3–TiO2 and V2O5/La2O3–TiO2 catalyst and their activity for synthesis of 2, 6-dimethylphenol. J. Mol. Catal. A Chem. 169, 207–223 (2001)CrossRef
27.
Zurück zum Zitat F. Taleshi, A. Pahlavan, Effect of rapid cooling time on optical absorption and band gap energy of TiO2 nanoparticles. J. Mater. Sci. Mater. Electron. 25, 2450–2455 (2014)CrossRef F. Taleshi, A. Pahlavan, Effect of rapid cooling time on optical absorption and band gap energy of TiO2 nanoparticles. J. Mater. Sci. Mater. Electron. 25, 2450–2455 (2014)CrossRef
28.
Zurück zum Zitat H. Yamashita, M. Harada, J. Misaka, M. Takeuchi, K. Ikeue, M. Anpo, Degradation of propanol diluted in water under visible light irradiation using metal ion-implanted titanium dioxide photocatalysts. J. Photochem. Photobiol. A 148, 257–261 (2002)CrossRef H. Yamashita, M. Harada, J. Misaka, M. Takeuchi, K. Ikeue, M. Anpo, Degradation of propanol diluted in water under visible light irradiation using metal ion-implanted titanium dioxide photocatalysts. J. Photochem. Photobiol. A 148, 257–261 (2002)CrossRef
29.
Zurück zum Zitat F. Mayadas, M. Shatzkes, Electrical-resistivity model for polycrystalline films: the case of arbitrary reflection at external surfaces. Phys. Rev. B 1, 1382 (1970)CrossRef F. Mayadas, M. Shatzkes, Electrical-resistivity model for polycrystalline films: the case of arbitrary reflection at external surfaces. Phys. Rev. B 1, 1382 (1970)CrossRef
30.
Zurück zum Zitat K. Vijayalakshmi, K. Karthick, Influence of annealing on the photoluminescence of nanocrystalline ZnO synthesized by microwave processing. Philos. Mag. Lett. 92, 710–717 (2012)CrossRef K. Vijayalakshmi, K. Karthick, Influence of annealing on the photoluminescence of nanocrystalline ZnO synthesized by microwave processing. Philos. Mag. Lett. 92, 710–717 (2012)CrossRef
31.
Zurück zum Zitat J.F. Banfield, S.A. Welch, H. Zhang, T.T. Ebert, R.L. Penn, Aggregation-based crystal growth and microstructure development in natural iron oxyhydroxide biomineralization products. Science 289, 751–754 (2000)CrossRef J.F. Banfield, S.A. Welch, H. Zhang, T.T. Ebert, R.L. Penn, Aggregation-based crystal growth and microstructure development in natural iron oxyhydroxide biomineralization products. Science 289, 751–754 (2000)CrossRef
Metadaten
Titel
Effect of Cr incorporation on the properties of TiO2 nanoparticles synthesized by microwave technique
verfasst von
K. Vijayalakshmi
S. David Jereil
Publikationsdatum
01.06.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 6/2015
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-015-2904-8

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