1 Introduction
2 Experimental Methods
2.1 Materials
Cement properties | Unit | Value |
---|---|---|
Specific surface area | cm2/g | 4433 |
Water demand | % | 30 |
Commencement of bonding | min | 120 |
End of bonding | min | 180 |
Volume stability | min | 2 |
Compressive strength at 2 days | MPa | 27.7 |
28 days | MPa | 57.1 |
Tensile strength at 2 days | MPa | 5.3 |
28 days | MPa | 8.2 |
Type of UHPC | Percentage of fibers (%)/mass (g/cm3) | Type of coarse aggregate 2/8 mm | |
---|---|---|---|
Steel fibers SF | Polypropylene fibers PF | ||
C1 | – | – | Granodiorite |
SC | 1/7.8 | – | Granodiorite |
SPC1 | 0.75/5.85 | 0.25/0.23 | Granodiorite |
SPC2 | 0.5/3.9 | 0.5/0.45 | Granite |
SPC3 | 0.25/1.95 | 0.75/0.68 | Granite |
PC | – | 1/0.9 | Granite |
C2 | – | – | Granite |
2.2 Test Methods
2.2.1 Resistance to salt crystallization
2.2.2 Frost Resistance Test
2.2.3 Dynamic Modulus of Elasticity
2.2.4 Contact Angle and Surface Free Energy
3 Results and Discussion
3.1 Physical and Mechanical Properties
Property of UHPC | C1 | SC | SPC1 | SPC2 | SPC3 | PC | C2 |
---|---|---|---|---|---|---|---|
Apparent density (g/cm3) | 2.57 | 2.61 | 2.51 | 2.45 | 2.36 | 2.30 | 2.40 |
Absorptivity (%) | 0.60 | 0.54 | 0.69 | 0.78 | 0.95 | 1.07 | 0.75 |
Compressive strength (MPa) | 151.0 | 154.9 | 144.7 | 133.9 | 122.3 | 94.6 | 129.5 |
Splitting tensile strength (MPa) | 8.9 | 13.8 | 13.5 | 10.0 | 9.3 | 7.6 | 6.8 |
Modulus of elasticity (GPa) | 38.37 | 39.74 | 34.27 | 32.45 | 29.60 | 29.42 | 32.55 |
3.2 Resistance to Salt Crystallization
3.3 Frost Resistance Test
3.4 Dynamic Modulus of Elasticity After Frost Resistance Test
3.5 Contact Angle and Surface Free Energy
Type of UHPC | Contact angle θ
w
(°) | SFE γ
S
(mJ/m2) | ||||||
---|---|---|---|---|---|---|---|---|
Before frost test | After frost test | Before frost test | After frost test | |||||
t1 = 0 | t2 = 35 | t1 = 0 | t2 = 35 | t1 = 0 | t2 = 35 | t1 = 0 | t2 = 35 | |
(min) | ||||||||
C1 | 63.5 | 22.6 | 60.2 | 19.4 | 45.6 | 67.6 | 46.1 | 69.0 |
SC | 67.8 | 32.4 | 55.4 | 20.6 | 43.1 | 63.3 | 50.6 | 68.5 |
SPC1 | 39.1 | 20.4 | 30.4 | 13.9 | 59.7 | 68.7 | 66.3 | 70.8 |
SPC2 | 42.7 | 12.9 | 38.5 | 10.1 | 58.1 | 71.1 | 62.2 | 71.7 |
SPC3 | 55.1 | 25.1 | 50.8 | 19.5 | 50.5 | 67.0 | 53.0 | 68.9 |
PC | 47.2 | 14.0 | 41.2 | 9.3 | 55.4 | 70.6 | 57.7 | 71.9 |
C2 | 53.4 | 10.1 | 50.2 | 4.7 | 51.8 | 71.5 | 52.7 | 72.6 |
4 Conclusions
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The degree of ice pore saturation is sufficiently low. The matrices of the UHPC with steel fibers in the amounts of 1% (SC), and 0.75% (SPC1) are slightly damaged. The increased volume of free pores in UHPC with polypropylene fibers affected the greatest rise in mass after the salt crystallization test. All the UHPC exhibited good resistance to salt crystallization.
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Freezing-thawing cycles cause cracking and degradation of the UHPC with the high content of steel fibers, affecting deterioration of the dynamic modulus and significant loss in mass, which influences the durability. However, for all the UHPC the relative values of the dynamic elastic modulus do not drop below 95% of the baseline.
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The contact angles after the frost resistance test were high for hybrid fiber reinforced UHPC and polypropylene fiber reinforced UHPC. The lowest contact angle was observed for the concrete without fibers with granite aggregate. The highest SFE value was obtained by the hybrid fiber reinforced UHPC with 0.75% SF and 0.25% PF (SPC1).
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Ultra-high performance concrete demonstrated good correlations between: the mass loss and the dynamic modulus ratio before and after F–T cycles, the water absorptivity and increase in mass after the salt crystallization test, the percentage of mass loss after the frost resistance test and salt resistance test. The adhesive properties and wettability were determined by the correlation between the mass loss and SFE ratio before and after the F–T cycles.
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Fiber hybridization increases the resistance to salt crystallization and freeze–thaw resistance, improves the adhesion properties and reduce the wettability of the UHPC surface in comparison with one type of fiber at the same fiber volume fraction.