nach oben

Cellulose

Erschienen in:

02.06.2018 | Original Paper

Effect of hydrothermal treatment of microfibrillated cellulose on rheological properties and formation of hydrolysis products

verfasst von: Salla Hiltunen, Isto Heiskanen, Kaj Backfolk

Erschienen in: Cellulose | Ausgabe 8/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

The aim of this study was to determine the effects of hydrothermal treatment of microfibrillated cellulose (MFC) on its gel stability, water retention and rheological behavior. MFC gel was prepared by fibrillating endoglucanase pre-treated, never-dried dissolving pulp. The MFC gel samples were then exposed in a static chamber for different times at different temperatures. At temperatures of 120–150 °C, the viscosity profile of the gels was not significantly changed and a characteristic series of 3 successive regimes in the course of increasing shear rate, showing different behavior was revealed. The amount of water released by the samples under pressure, on the other hand, was notably increased after hydrothermal treatment. After further exposure to prolonged treatment times (24 h) and higher temperature (180 °C), a significant decrease in viscosity and shear modulus was observed. Analysis of filtrates revealed the formation of cello-oligosaccharides, glucose and HMF and a decrease in surface tension indicating peeling and molecular degradation of the sample matrice. The microfibralled cellulose sample decomposition and gel network structure breakdown on a molecular level is discussed.

Vorheriger Artikel The effect of chemical modification of wood in ionic liquids on the supermolecular structure and mechanical properties of wood/polypropylene composites

Nächster Artikel Liquefaction of poplar biomass for value-added platform chemicals

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Agoda-Tandjawa G, Durand S, Berot S, Blassel C, Gaillard C, Garnier C, Doublier JL (2010) Rheological characterization of microfibrillated cellulose suspensions after freezing. Carbohydr Polym 80(3):677–686. https://doi.org/10.1016/j.carbpol.2009.11.045 CrossRef

Álvarez E, Vázquez G, Sánchez-Vilas M, Sanjurjo B, Navaza JM (1997) Surface tension of organic acids + water binary mixtures from 20 °C to 50 °C. J Chem Eng Data 42(5):957–960. https://doi.org/10.1021/je970025m CrossRef

Atalla RH, Ellis JD, Schroeder LR (1984) Some effects of elevated temperatures on the structure of cellulose and its transformation. J Wood Chem Technol 4(4):465–482. https://doi.org/10.1080/02773818408070662 CrossRef

Borrega M, Sixta H (2013) Purification of cellulosic pulp by hot water extraction. Cellulose 20(6):2803–2812. https://doi.org/10.1007/s10570-013-0086-1 CrossRef

Davidson GF (1943) The rate of change in the properties of cotton cellulose under the prolonged action of acids. J Text Inst Trans 34(10):87–96. https://doi.org/10.1080/19447024308659271 CrossRef

Eyholzer C, Bordeanu N, Lopez-Suevos F, Rentsch D, Zimmermann T, Oksman K (2010) Preparation and characterization of water-redispersible nanofibrillated cellulose in powder form. Cellulose 17(1):19–30. https://doi.org/10.1007/s10570-009-9372-3 CrossRef

Fall AB, Lindström SB, Sundman O, Ödberg L, Wågberg L (2011) Colloidal stability of aqueous nanofibrillated cellulose dispersions. Langmuir 27(18):11332–11338. https://doi.org/10.1021/la201947x CrossRefPubMed

Gehlen MH (2010) Kinetics of autocatalytic acid hydrolysis of cellulose with crystalline and amorphous fractions. Cellulose 17(2):245–252. https://doi.org/10.1007/s10570-009-9385-y CrossRef

Grignon J, Scallan AM (1980) Effect of pH and neutral salts upon the swelling of cellulose gels. J Appl Polym Sci 25(12):2829–2843. https://doi.org/10.1002/app.1980.070251215 CrossRef

Håkansson H, Ahlgren P (2005) Acid hydrolysis of some industrial pulps: effect of hydrolysis conditions and raw material. Cellulose 12(2):177–183. https://doi.org/10.1007/s10570-004-1038-6 CrossRef

Heggset EB, Chinga-Carrasco G, Syverud K (2017) Temperature stability of nanocellulose dispersions. Carbohydr Polym 157:114–121. https://doi.org/10.1016/j.carbpol.2016.09.077 CrossRefPubMed

Helmerius J, Vinblad von Walter J, Rova U, Berglund KA, Hodge DB (2010) Impact of hemicellulose pre-extraction for bioconversion on birch kraft pulp properties. Bioresour Technol 101:5996–6005. https://doi.org/10.1016/j.biortech.2010.03.029 CrossRefPubMed

Hiltunen S, Sirén H, Heiskanen I, Backfolk K (2016) Capillary electrophoretic profiling of wood-based oligosaccharides. Cellulose 23(5):3331–3340. https://doi.org/10.1007/s10570-016-1011-1 CrossRef

Iotti M, Gregersen ØW, Moe S, Lenes M (2011) Rheological studies of microfibrillar cellulose water dispersions. J Polym Environ 19(1):137–145. https://doi.org/10.1007/s10924-010-0248-2 CrossRef

Johnson RK, Zink-Sharp A, Renneckar SH, Glasser WG (2009) A new bio-based nanocomposite: fibrillated tempo-oxidized celluloses in hydroxypropylcellulose matrix. Cellulose 16(2):227–238. https://doi.org/10.1007/s10570-008-9269-6 CrossRef

Karppinen A, Saarinen T, Salmela J, Laukkanen A, Nuopponen M, Seppälä J (2012) Flocculation of microfibrillated cellulose in shear flow. Cellulose 19(6):1807–1819. https://doi.org/10.1007/s10570-012-9766-5 CrossRef

Lahtinen P, Liukkonen S, Pere J, Sneck A, Kangas H (2014) A comparative study of fibrillated fibers from different mechanical and chemical pulps. BioResources 9:2115–2127CrossRef

Lowys MP, Desbrières J, Rinaudo M (2001) Rheological characterization of cellulosic microfibril suspensions. Role of polymeric additives. Food Hydrocolloids 15(1):25–32. https://doi.org/10.1016/S0268-005X(00)00046-1 CrossRef

Maloney TC (2015) Network swelling of TEMPO-oxidized nanocellulose. Holzforschung 69(2):207–213CrossRef

Naderi A, Lindström T (2016) A comparative study of the rheological properties of three different nanofibrillated cellulose systems. Nordic Pulp Paper Res J 31(3):354–363CrossRef

Naderi A, Lindström T, Erlandsson J, Sundström J, Flodberg G (2016) A comparative study of the properties of three nano-fibrillated cellulose systems that have been produced at about the same energy consumption levels in the mechanical delamination step. Nordic Pulp Paper Res J 31(3):364–371CrossRef

Nguyen H, Nikolakis V, Vlachos DG (2016) Mechanistic insights into Lewis acid metal salt-catalyzed glucose chemistry in aqueous solution. ACS Catal 6(3):1497–1504. https://doi.org/10.1021/acscatal.5b02698 CrossRef

Notley SM (2008) Effect of introduced charge in cellulose gels on surface interactions and the adsorption of highly charged cationic polyelectrolytes. Phys Chem Chem Phys 10:1819–1825. https://doi.org/10.1039/B718543J CrossRefPubMed

Oefner PJ, Lanziner AH, Bonn G, Bobleter O (1992) Quantitative studies on furfural and organic acid formation during hydrothermal, acidic and alkaline degradation of d-xylose. Monatshefte für Chemie Chem Mon 123(6):547–556. https://doi.org/10.1007/BF00816848 CrossRef

Olszewska A, Eronen P, Johansson LS, Malho JM, Ankerfors M, Lindström T, Ruokolainen J, Laine J, Österberg M (2011) The behaviour of cationic nanofibrillar cellulose in aqueous media. Cellulose 18(5):1213–1226. https://doi.org/10.1007/s10570-011-9577-0 CrossRef

Örså F, Holmbom B, Thornton J (1997) Dissolution and dispersion of spruce wood components into hot water. Wood Sci Technol 31(4):279–290. https://doi.org/10.1007/BF00702615 CrossRef

Pääkkö M, Ankerfors M, Kosonen H, Nykänen A, Ahola S, Österberg M, Ruokolainen J, Laine J, Larsson PT, Ikkala O, Lindström T (2007) Enzymatic hydrolysis combined with mechanical shearing and high-pressure homogenization for nanoscale cellulose fibrils and strong gels. Biomacromolecules 8(6):1934–1941. https://doi.org/10.1021/bm061215p CrossRefPubMed

Pääkkönen T, Dimic-Misic K, Orelma H, Pönni R, Vuorinen T, Maloney T (2016) Effect of xylan in hardwood pulp on the reaction rate of TEMPO-mediated oxidation and the rheology of the final nanofibrillated cellulose gel. Cellulose 23(1):277–293. https://doi.org/10.1007/s10570-015-0824-7 CrossRef

Palme A, Theliander H, Brelid H (2016) Acid hydrolysis of cellulosic fibres: comparison of bleached kraft pulp, dissolving pulps and cotton textile cellulose. Carbohydr Polym 136:1281–1287. https://doi.org/10.1016/j.carbpol.2015.10.015 CrossRefPubMed

Peng L, Lin L, Zhang J, Zhuang J, Zhang B, Gong Y (2010) Catalytic conversion of cellulose to levulinic acid by metal chlorides. Molecules 15(8):5258–5272. https://doi.org/10.3390/molecules15085258 CrossRefPubMed

Potvin J, Sorlien E, Hegner J, DeBoef B, Lucht BL (2011) Effect of NaCl on the conversion of cellulose to glucose and levulinic acid via solid supported acid catalysis. Tetrahedron Lett 52(44):5891–5893. https://doi.org/10.1016/j.tetlet.2011.09.013 CrossRef

Quiévy N, Jacquet N, Sclavons M, Deroanne C, Paquot M, Devaux J (2010) Influence of homogenization and drying on the thermal stability of microfibrillated cellulose. Polym Degrad Stab 95(3):306–314. https://doi.org/10.1016/j.polymdegradstab.2009.11.020 CrossRef

Rovio S, Simolin H, Koljonen K, Sirén H (2008) Determination of monosaccharide composition in plant fiber materials by capillary zone electrophoresis. J Chromatogr A 1185(1):139–144. https://doi.org/10.1016/j.chroma.2008.01.031 CrossRefPubMed

Sattler C, Labbé N, Harper D, Elder T, Rials T (2008) Effects of hot water extraction on physical and chemical characteristics of oriented strand board (OSB) wood flakes. Clean Soil Air Water 36(8):674–681. https://doi.org/10.1002/clen.200800051 CrossRef

Shafiei-Sabet S, Martinez M, Olson J (2016) Shear rheology of micro-fibrillar cellulose aqueous suspensions. Cellulose 23(5):2943–2953. https://doi.org/10.1007/s10570-016-1040-9 CrossRef

Shatkin JA, Wegner TH, Bilek E, Cowie J (2014) Market projections of cellulose nanomaterial-enabled products—part 1: applications. Tappi J 13(5):9–16

Silveira RL, Stoyanov SR, Kovalenko A, Skaf MS (2016) Cellulose aggregation under hydrothermal pretreatment conditions. Biomacromolecules 17(8):2582–2590. https://doi.org/10.1021/acs.biomac.6b00603 CrossRefPubMed

Song T, Pranovich A, Holmbom B (2012) Hot-water extraction of ground spruce wood of different particle size. BioResources 7(3):4214–4225

Taheri H, Samyn P (2016) Effect of homogenization (microfluidization) process parameters in mechanical production of micro- and nanofibrillated cellulose on its rheological and morphological properties. Cellulose 23(2):1221–1238. https://doi.org/10.1007/s10570-016-0866-5 CrossRef

Tanaka R, Saito T, Hondo H, Isogai A (2015) Influence of flexibility and dimensions of nanocelluloses on the flow properties of their aqueous dispersions. Biomacromolecules 16(7):2127–2131. https://doi.org/10.1021/acs.biomac.5b00539 CrossRefPubMed

Tenhunen TM, Peresin MS, Penttilä PA, Pere J, Serimaa R, Tammelin T (2014) Significance of xylan on the stability and water interactions of cellulosic nanofibrils. React Funct Polym 85:157–166CrossRef

Tingaut P, Zimmermann T, Lopez-Suevos F (2010) Synthesis and characterization of bionanocomposites with tunable properties from poly(lactic acid) and acetylated microfibrillated cellulose. Biomacromolecules 11(2):454–464. https://doi.org/10.1021/bm901186u CrossRefPubMed

Vesterinen AH, Myllytie P, Laine J, Seppälä J (2010) The effect of water-soluble polymers on rheology of microfibrillar cellulose suspension and dynamic mechanical properties of paper sheet. J Appl Polym Sci 116(5):2990–2997. https://doi.org/10.1002/app.31832 CrossRef

Willför S, Sjöholm R, Laine C, Roslund M, Hemming J, Holmbom B (2003) Characterisation of water-soluble galactoglucomannans from norway spruce wood and thermomechanical pulp. Carbohydr Polym 52(2):175–187. https://doi.org/10.1016/S0144-8617(02)00288-6 CrossRef

Titel: Effect of hydrothermal treatment of microfibrillated cellulose on rheological properties and formation of hydrolysis products
verfasst von: Salla Hiltunen
Isto Heiskanen
Kaj Backfolk
Publikationsdatum: 02.06.2018
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 8/2018
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-018-1884-2

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 8/2018

AQC functionalized CNCs/PVA-co-PE composite nanofibrous membrane with flower-like microstructures for photo-induced multi-functional protective clothing

Green method to reinforce natural rubber with tunicate cellulose nanocrystals via one-pot reaction

Enzymatic production of cellulose nanofibers and sugars in a stirred-tank reactor: determination of impeller speed, power consumption, and rheological behavior

Effect of ultrasonication on physicochemical properties of apple based nanocellulose-calcium carbonate composites

Synthesis of Ag–Fe3O4 nanoparticles supported on polydopamine-functionalized porous cellulose acetate microspheres: catalytic and antibacterial applications

Development of some functional properties on viscose fabrics using nano kaolin