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01.04.2015 | Original Paper

Effect of Ir and Pt Addition on the HDO Performance of RuS₂/SBA-15 Sulfide Catalysts

verfasst von: Antonia Infantes-Molina, Barbara Pawelec, Jose Luis G. Fierro, Cristina V. Loricera, Antonio Jiménez-López, Enrique Rodríguez-Castellón

Erschienen in: Topics in Catalysis | Ausgabe 4-6/2015

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Abstract

Ir and Pt have been tested as dopants for ruthenium sulfide supported on ordered SBA-15 mesoporous silica. The incorporation of Ir or Pt into RuS₂/SBA-15 was found to enhance the activity in the gas-phase hydrodeoxygenation (HDO) of phenol carried out at 310 °C and 30 bar of total H₂ pressure. X-ray photoelectron spectroscopy (XPS), high resolution transmission electron microscopy, temperature programmed desorption of NH₃ and H₂-temperature-programmed reduction of the sulfided catalysts were used to characterize the catalysts. XPS analysis of the spent catalysts confirmed the oxidation of ruthenium sulfide during HDO of phenol. The main factor that influences the catalyst activity was the surface exposure of the active phases, whereas the formation of oxysulfide species did not inhibit the HDO reaction.

Vorheriger Artikel Replacing Precious Metals with Carbide Catalysts for Hydrogenation Reactions

Nächster Artikel Use of Solvatochromism to Assay Preferential Solvation of a Prototypic Catalytic Site

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Titel: Effect of Ir and Pt Addition on the HDO Performance of RuS2/SBA-15 Sulfide Catalysts
verfasst von: Antonia Infantes-Molina
Barbara Pawelec
Jose Luis G. Fierro
Cristina V. Loricera
Antonio Jiménez-López
Enrique Rodríguez-Castellón
Publikationsdatum: 01.04.2015
Verlag: Springer US
Erschienen in: Topics in Catalysis / Ausgabe 4-6/2015
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-015-0366-0

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