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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 7/2013

01.07.2013 | Original Contribution

Effect of molecular interactions on the performance of poly(isobutylene-co-isoprene)/graphene and clay nanocomposites

verfasst von: Kishor Kumar Sadasivuni, Allisson Saiter, Nicolas Gautier, Sabu Thomas, Yves Grohens

Erschienen in: Colloid and Polymer Science | Ausgabe 7/2013

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Abstract

Poly(isobutylene-co-isoprene) (IIR)/graphene and cloisite10A nanocomposites were prepared successfully and the resulting mechanical, rheological and barrier properties were carefully evaluated and compared. Chemical treatments like maleic anhydride grafting were used to improve the dispersion of the clay in the IIR matrix. Blends with different loading (20, 40, 60, and 80 %) of maleic anhydride grafted poly(isobutylene-co-isoprene) (MA-g-IIR) and IIR were made to maintain a balance between the beneficial polarity induced by MA grafting and the inevitable decrease in molecular weight (due to chain scission) induced by the free radical grafting process. The highest moduli, tensile strength and elongation at break were achieved in the case of a 60:40 ratio of MA-g-IIR (grafting degree 0.75)/IIR mixture with 5 phr of cloisite 10A. IIR/graphene nanocomposites exhibited higher reinforcement (Young’s moduli) and lower gas permeability compared to the optimized clay nanocomposites with same weight percentage. The filler–elastomer and filler–filler interactions deduced from rheology, stress relaxation and Payne effect experiments emphasize the reinforcing ability in IIR/graphene and MA-g-IIR/clay. XRD, SEM and TEM results further substantiated the results from the obtained micro structure of the nanocomposites. The improved performances of IIR/MA-g-IIR/clay and IIR/graphene were successfully correlated with interactions between the filler platelets and elastomer chains occurring in the nanocomposites.
Vorheriger Artikel Rigidity of the crystals of thermo-sensitive gel spheres of poly (N-isopropyl acrylamide) in the deionized aqueous media as studied by the reflection spectroscopy in the sedimentation equilibrium
Nächster Artikel Synthesis of monodisperse anionic submicron polystyrene particles by stabilizer-free dispersion polymerization in alcoholic media

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Metadaten
Titel
Effect of molecular interactions on the performance of poly(isobutylene-co-isoprene)/graphene and clay nanocomposites
verfasst von
Kishor Kumar Sadasivuni
Allisson Saiter
Nicolas Gautier
Sabu Thomas
Yves Grohens
Publikationsdatum
01.07.2013
Verlag
Springer-Verlag
Erschienen in
Colloid and Polymer Science / Ausgabe 7/2013
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-013-2908-y

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