Skip to main content
Erschienen in: Journal of Materials Engineering and Performance 6/2018

03.05.2018

Effect of Sm-Rich Phase on Corrosion Behavior of Hot-Extruded AZ31-1.5Sm Magnesium Alloy

verfasst von: Xiao Li, Zhi Hu, Hong Yan, Xiaoquan Wu, Hecong Xie, Zhou Dong

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 6/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The effects of Sm on the corrosion and microstructure behavior of hot-extruded AZ31 magnesium alloy were investigated by SEM, TEM, weight loss analysis, and electrochemical measurements. The results indicated that granular Al2Sm phase ~ 4 μm in size in the hot-extruded AZ31 magnesium alloy modified with 1.5 wt.% Sm leads to significant grain refinement. The corrosion rate decreased from 15.98 × 10−4 to 11.19 × 10−4 g cm−2 h−1 in the transverse section and from 8.57 × 10−4 to 6.20 × 10−4 g cm−2 h−1 in the longitudinal section. Compared to the unmodified alloy, the corrosion potential of the Sm-modified alloy in the transverse and longitudinal sections increased by 98 and 62 mV, respectively, and the Rct value (charge transfer resistance) in the transverse and longitudinal sections of the modified alloy increased from 1764 and 1756 to 2928 and 2408 Ω cm2, respectively. The results showed that the corrosion resistance of hot-extruded AZ31 magnesium alloy was significantly improved by Sm addition due to the grain refinement, the decreased dislocation density, and the suppression of micro-galvanic corrosion caused by Al-Sm-(Mn) intermetallic compounds.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat M. Yang, Y.H. Liu, J.A. Liu, and Y.L. Song, Corrosion and Mechanical Properties of AM50 Magnesium Alloy After Being Modified by 1 wt.% Rare Earth Element Gadolinium, J. Rare Earth, 2014, 32, p 558–563CrossRef M. Yang, Y.H. Liu, J.A. Liu, and Y.L. Song, Corrosion and Mechanical Properties of AM50 Magnesium Alloy After Being Modified by 1 wt.% Rare Earth Element Gadolinium, J. Rare Earth, 2014, 32, p 558–563CrossRef
2.
Zurück zum Zitat L.J. Liu and M. Schlesinger, Corrosion of Magnesium and Its Alloys, Corros. Sci., 2009, 51, p 1733–1737CrossRef L.J. Liu and M. Schlesinger, Corrosion of Magnesium and Its Alloys, Corros. Sci., 2009, 51, p 1733–1737CrossRef
3.
Zurück zum Zitat J.E. Gray and B. Luan, Protective Coatings on Magnesium and Its Alloys—A Critical Review, J. Alloys. Compd., 2002, 336, p 88–113CrossRef J.E. Gray and B. Luan, Protective Coatings on Magnesium and Its Alloys—A Critical Review, J. Alloys. Compd., 2002, 336, p 88–113CrossRef
4.
Zurück zum Zitat Y.L. Song, Y.H. Liu, S.R. Yu, X.Y. Zhu, and S.H. Wang, Effect of Neodymium on Microstructure and Corrosion Resistance of AZ91 Magnesium Alloy, J. Mater. Sci., 2007, 42, p 4435–4440CrossRef Y.L. Song, Y.H. Liu, S.R. Yu, X.Y. Zhu, and S.H. Wang, Effect of Neodymium on Microstructure and Corrosion Resistance of AZ91 Magnesium Alloy, J. Mater. Sci., 2007, 42, p 4435–4440CrossRef
5.
Zurück zum Zitat C.H. Liang, S.S. Wang, N.B. Huang, Z.H. Zhang, S.C. Zhang, and J. Ren, Effects of Lanthanum and Cerium Mixed Rare Earth Metal on Abrasion and Corrosion Resistance of AM60 Magnesium Alloy, Rare. Metal. Mater. Eng., 2015, 44, p 521–526CrossRef C.H. Liang, S.S. Wang, N.B. Huang, Z.H. Zhang, S.C. Zhang, and J. Ren, Effects of Lanthanum and Cerium Mixed Rare Earth Metal on Abrasion and Corrosion Resistance of AM60 Magnesium Alloy, Rare. Metal. Mater. Eng., 2015, 44, p 521–526CrossRef
6.
Zurück zum Zitat N. Jiang, L. Chen, L.G. Meng, C.F. Fang, H. Hao, and X.G. Zhang, Effect of Neodymium, Gadolinium Addition on Microstructure and Mechanical Properties of AZ80 Magnesium Alloy, J. Rare Earth, 2016, 34, p 632–637CrossRef N. Jiang, L. Chen, L.G. Meng, C.F. Fang, H. Hao, and X.G. Zhang, Effect of Neodymium, Gadolinium Addition on Microstructure and Mechanical Properties of AZ80 Magnesium Alloy, J. Rare Earth, 2016, 34, p 632–637CrossRef
7.
Zurück zum Zitat S.Y. Chen, S.T. Zhang, X.L. Ren, S.Y. Xu, and L.L. Yin, Cerium-based Chemical Conversion Coating on Aluminum Alloy to Inhibits Corrosion in Chloride Solution, Int. J. Electrochem. Sci., 2015, 10, p 9073–9088 S.Y. Chen, S.T. Zhang, X.L. Ren, S.Y. Xu, and L.L. Yin, Cerium-based Chemical Conversion Coating on Aluminum Alloy to Inhibits Corrosion in Chloride Solution, Int. J. Electrochem. Sci., 2015, 10, p 9073–9088
8.
Zurück zum Zitat L.N. Zhang, R.L. Jia, D. Li, W. Zhang, and F. Guo, Effect of Intermetallic Phases on Corrosion Initiation of AZ91 Alloy With Rare Earth Y Addition, J. Mater. Sci. Technol., 2015, 31, p 504–511CrossRef L.N. Zhang, R.L. Jia, D. Li, W. Zhang, and F. Guo, Effect of Intermetallic Phases on Corrosion Initiation of AZ91 Alloy With Rare Earth Y Addition, J. Mater. Sci. Technol., 2015, 31, p 504–511CrossRef
9.
Zurück zum Zitat S. Seetharaman, C. Blawert, B.M. Ng, W.L.E. Wong, C.S. Goh, N. Hort, and M. Gupta, Effect of Erbium Modification on the Microstructure, Mechanical and Corrosion Characteristics of Binary Mg-Al Alloys, J. Alloys. Compd., 2015, 648, p 759–770CrossRef S. Seetharaman, C. Blawert, B.M. Ng, W.L.E. Wong, C.S. Goh, N. Hort, and M. Gupta, Effect of Erbium Modification on the Microstructure, Mechanical and Corrosion Characteristics of Binary Mg-Al Alloys, J. Alloys. Compd., 2015, 648, p 759–770CrossRef
10.
Zurück zum Zitat J. Zheng, Q.D. Wang, Z.L. Jin, and T. Peng, Effect of Zinc Additions on the Microstructure Mechanical Properties and Creep Behavior of As-Cast Mg-3Sm-0.4Zr (wt.%) Alloy, Mater. Sci. Eng. A, 2010, 527, p 4605–4612CrossRef J. Zheng, Q.D. Wang, Z.L. Jin, and T. Peng, Effect of Zinc Additions on the Microstructure Mechanical Properties and Creep Behavior of As-Cast Mg-3Sm-0.4Zr (wt.%) Alloy, Mater. Sci. Eng. A, 2010, 527, p 4605–4612CrossRef
11.
Zurück zum Zitat Q.A. Li, X.F. Li, Q. Zhang, and J. Chen, Effect of Rare-Earth Element Sm on the Corrosion Behavior of Mg-6Al-1.2Y-0.9Nd Alloy, Rare Met., 2010, 29, p 557–560CrossRef Q.A. Li, X.F. Li, Q. Zhang, and J. Chen, Effect of Rare-Earth Element Sm on the Corrosion Behavior of Mg-6Al-1.2Y-0.9Nd Alloy, Rare Met., 2010, 29, p 557–560CrossRef
12.
Zurück zum Zitat D.G. Wu, S.H. Yan, Z.Q. Wang, Z.Q. Zhang, R.Y. Miao, X.W. Zhang, and D.H. Chen, Effect of Samarium on Microstructure and Corrosion Resistance of Aged As-Cast AZ92 Magnesium Alloy, J. Rare Earth, 2014, 32, p 663–671CrossRef D.G. Wu, S.H. Yan, Z.Q. Wang, Z.Q. Zhang, R.Y. Miao, X.W. Zhang, and D.H. Chen, Effect of Samarium on Microstructure and Corrosion Resistance of Aged As-Cast AZ92 Magnesium Alloy, J. Rare Earth, 2014, 32, p 663–671CrossRef
13.
Zurück zum Zitat H. Wang, J.B. Wen, J.G. He, J.L. Ma, Y.S. Yang, and H.Y. Shao, Effect of Rare Earth Element Sm on Corrosion Resistance of AZ80 Magnesium Alloy, Trans. Mater. Heat Treat., 2013, 34, p 41–45 H. Wang, J.B. Wen, J.G. He, J.L. Ma, Y.S. Yang, and H.Y. Shao, Effect of Rare Earth Element Sm on Corrosion Resistance of AZ80 Magnesium Alloy, Trans. Mater. Heat Treat., 2013, 34, p 41–45
14.
Zurück zum Zitat Z.M. Zhang, H.Y. Xu, and Q. Wang, Corrosion and Mechanical Properties of Hot-Extruded AZ31 Magnesium Alloys, Trans. Nonferrous. Met. Soc. China, 2008, 18, p 140–144CrossRef Z.M. Zhang, H.Y. Xu, and Q. Wang, Corrosion and Mechanical Properties of Hot-Extruded AZ31 Magnesium Alloys, Trans. Nonferrous. Met. Soc. China, 2008, 18, p 140–144CrossRef
15.
Zurück zum Zitat C. Wang, T.J. Luo, J.X. Zhou, and Y.S. Yang, Anisotropic Cyclic Deformation Behavior of Extruded ZA81M Magnesium Alloy, Int. J. Fatigue, 2016, 96, p 178–184CrossRef C. Wang, T.J. Luo, J.X. Zhou, and Y.S. Yang, Anisotropic Cyclic Deformation Behavior of Extruded ZA81M Magnesium Alloy, Int. J. Fatigue, 2016, 96, p 178–184CrossRef
16.
Zurück zum Zitat M. Sun, X.Y. Hu, L.M. Peng, P.H. Fu, and Y.H. Peng, Effects of Sm on the Grain Refinement, Microstructures and Mechanical Properties of AZ31 Magnesium Alloy, Mater. Sci. Eng. A, 2015, 620, p 89–96CrossRef M. Sun, X.Y. Hu, L.M. Peng, P.H. Fu, and Y.H. Peng, Effects of Sm on the Grain Refinement, Microstructures and Mechanical Properties of AZ31 Magnesium Alloy, Mater. Sci. Eng. A, 2015, 620, p 89–96CrossRef
17.
Zurück zum Zitat L.D.Y. Pozzo, T.F.D. Conceicão, A. Spinelli, N. Scharnagl, and A.T.N. Pires, Chitosan Coatings Crosslinked with Genipin for Corrosion Protection of AZ31 Magnesium Alloy Sheets, Carbohydr. Polym., 2018, 181, p 71–77CrossRef L.D.Y. Pozzo, T.F.D. Conceicão, A. Spinelli, N. Scharnagl, and A.T.N. Pires, Chitosan Coatings Crosslinked with Genipin for Corrosion Protection of AZ31 Magnesium Alloy Sheets, Carbohydr. Polym., 2018, 181, p 71–77CrossRef
18.
Zurück zum Zitat T.Y. Pan and L.B. Wang, Finite-Element Analysis of Chemical Transport and Reinforcement Corrosion-Induced Cracking in Variably Saturated Heterogeneous Concrete, J. Eng. Mech. ASCE, 2011, 137, p 334–345CrossRef T.Y. Pan and L.B. Wang, Finite-Element Analysis of Chemical Transport and Reinforcement Corrosion-Induced Cracking in Variably Saturated Heterogeneous Concrete, J. Eng. Mech. ASCE, 2011, 137, p 334–345CrossRef
19.
Zurück zum Zitat T. Zhang, G.Z. Meng, Y.W. Shao, Z.Y. Cui, and F.H. Wang, Corrosion of Hot Extrusion AZ91 Magnesium Alloy. Part II: Effect of Rare Earth Element Neodymium (Nd) on the Corrosion Behavior of Extruded Alloy, Corros. Sci., 2011, 53, p 2934–2942CrossRef T. Zhang, G.Z. Meng, Y.W. Shao, Z.Y. Cui, and F.H. Wang, Corrosion of Hot Extrusion AZ91 Magnesium Alloy. Part II: Effect of Rare Earth Element Neodymium (Nd) on the Corrosion Behavior of Extruded Alloy, Corros. Sci., 2011, 53, p 2934–2942CrossRef
20.
Zurück zum Zitat M. Andrei, A. Eliezer, P.L. Bonora, and E.M. Gutman, DC and AC Polarisation Study on Magnesium Alloys Influence of the Mechanical Deformation, Mater. Corros., 2002, 53, p 455–461CrossRef M. Andrei, A. Eliezer, P.L. Bonora, and E.M. Gutman, DC and AC Polarisation Study on Magnesium Alloys Influence of the Mechanical Deformation, Mater. Corros., 2002, 53, p 455–461CrossRef
21.
Zurück zum Zitat N.N. Aung and W. Zhou, Effect of Grain Size and Twins on Corrosion Behaviour of AZ31B Magnesium Alloy, Corros. Sci., 2010, 52, p 589–594CrossRef N.N. Aung and W. Zhou, Effect of Grain Size and Twins on Corrosion Behaviour of AZ31B Magnesium Alloy, Corros. Sci., 2010, 52, p 589–594CrossRef
22.
Zurück zum Zitat G.B. Hamu, D. Eliezer, and L. Wagner, The Relation Between Severe Plastic Deformation Microstructure and Corrosion Behavior of AZ31 Magnesium Alloy, J. Alloys Compd., 2009, 468, p 222–229CrossRef G.B. Hamu, D. Eliezer, and L. Wagner, The Relation Between Severe Plastic Deformation Microstructure and Corrosion Behavior of AZ31 Magnesium Alloy, J. Alloys Compd., 2009, 468, p 222–229CrossRef
23.
Zurück zum Zitat K.J. Li, Q.A. Li, X.T. Jing, J. Chen, X.Y. Zhang, and Q. Zhang, Effects of Sm Addition on Microstructure and Mechanical Properties of Mg-6Al-0.6Zn Alloy, Scr. Mater., 2009, 60, p 1101–1104CrossRef K.J. Li, Q.A. Li, X.T. Jing, J. Chen, X.Y. Zhang, and Q. Zhang, Effects of Sm Addition on Microstructure and Mechanical Properties of Mg-6Al-0.6Zn Alloy, Scr. Mater., 2009, 60, p 1101–1104CrossRef
24.
Zurück zum Zitat M. Mohedano, R. Arrabal, Á. Pardo, M.C. Mreino, K. Paucar, P. Casajús, and E. Matykina, Salt Spray Corrosion Behaviour of New Mg–Al Alloys Containing Nd or Gd, Corros. Eng. Sci. Technol., 2013, 48, p 183–193CrossRef M. Mohedano, R. Arrabal, Á. Pardo, M.C. Mreino, K. Paucar, P. Casajús, and E. Matykina, Salt Spray Corrosion Behaviour of New Mg–Al Alloys Containing Nd or Gd, Corros. Eng. Sci. Technol., 2013, 48, p 183–193CrossRef
25.
Zurück zum Zitat M.C. Merino, A. Pardo, R. Arrabal, S. Merino, P. Casajús, and M. Mohedano, Influence of Chloride Ion Concentration and Temperature on the Corrosion of Mg–Al Alloys in Salt Fog, Corros. Sci., 2010, 52, p 1696–1704CrossRef M.C. Merino, A. Pardo, R. Arrabal, S. Merino, P. Casajús, and M. Mohedano, Influence of Chloride Ion Concentration and Temperature on the Corrosion of Mg–Al Alloys in Salt Fog, Corros. Sci., 2010, 52, p 1696–1704CrossRef
26.
Zurück zum Zitat R. Arrabal, A. Pardo, M.C. Merino, S. Merino, M. Mohedano, and P. Casajús, Corrosion Behaviour of Mg/Al Alloys in High Humidity Atmospheres, Mater. Corros., 2011, 62, p 326–334CrossRef R. Arrabal, A. Pardo, M.C. Merino, S. Merino, M. Mohedano, and P. Casajús, Corrosion Behaviour of Mg/Al Alloys in High Humidity Atmospheres, Mater. Corros., 2011, 62, p 326–334CrossRef
27.
Zurück zum Zitat B. Chen, R.C. Wang, C.Q. Peng, Y. Feng, and N.G. Wang, Influence of Al–Mn Master Alloys on Microstructures and Electrochemical Properties of Mg-Al-Pb-Mn Alloys, Trans. Nonferrous Met. Soc. China, 2014, 24, p 423–430CrossRef B. Chen, R.C. Wang, C.Q. Peng, Y. Feng, and N.G. Wang, Influence of Al–Mn Master Alloys on Microstructures and Electrochemical Properties of Mg-Al-Pb-Mn Alloys, Trans. Nonferrous Met. Soc. China, 2014, 24, p 423–430CrossRef
28.
Zurück zum Zitat N.G. Wang, R.C. Wang, C.Q. Peng, and Y. Feng, Effect of Manganese on Discharge and Corrosion Performance of Magnesium Alloy AP65 as Anode for Seawater-Activated Battery, Corrosion, 2012, 68, p 388–397CrossRef N.G. Wang, R.C. Wang, C.Q. Peng, and Y. Feng, Effect of Manganese on Discharge and Corrosion Performance of Magnesium Alloy AP65 as Anode for Seawater-Activated Battery, Corrosion, 2012, 68, p 388–397CrossRef
Metadaten
Titel
Effect of Sm-Rich Phase on Corrosion Behavior of Hot-Extruded AZ31-1.5Sm Magnesium Alloy
verfasst von
Xiao Li
Zhi Hu
Hong Yan
Xiaoquan Wu
Hecong Xie
Zhou Dong
Publikationsdatum
03.05.2018
Verlag
Springer US
Erschienen in
Journal of Materials Engineering and Performance / Ausgabe 6/2018
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-018-3370-2

Weitere Artikel der Ausgabe 6/2018

Journal of Materials Engineering and Performance 6/2018 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.