Skip to main content
Erschienen in: Cellulose 2/2021

27.11.2020 | Original Research

Effect of starch-based flame retardant on the thermal degradation and combustion properties of reconstituted tobacco sheet

verfasst von: Ning Shao, Yaqing Qu, Li Hou, Yonghua Hu, Zhengfeng Tian, Yun Gao, Xiaolan Zhu

Erschienen in: Cellulose | Ausgabe 2/2021

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In this paper, starch, distarch phosphate (DSP) and hydroxypropyl distarch phosphate (HPDSP) were used as “green” carbon sources with ammonium polyphosphate (APP) to prepare flame retardant reconstituted tobacco sheet (RTS) by paper-making process and the effect of these starch-based flame retardants on their thermal degradation and combustion properties was preliminarily investigated. Micro-scale combustion calorimetry results showed the value of the heat release of modified RTS was lower than that of pure RTS, demonstrating the restrained combustion behavior of modified RTS. TG-FTIR and TG-MS analysis indicated that the starch-based flame retardant coating promoted the char formation, inhibited char combustion and release of gaseous products except for NH3, with the relative best comprehensive performance of APP-DSP. Cigarette burning cone analysis also confirmed that the modified RTS had lower temperature and smaller burning cone volume than that of pure RTS, especially APP-HPDSP-RTS. This work could highly expand the application of starch and its derivatives in flame retardant and tobacco industry.

Graphic abstract

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Anhänge
Nur mit Berechtigung zugänglich
Literatur
Zurück zum Zitat Ahamad T, Alshehri SM (2012) TG–FTIR–MS (evolved gas analysis) of bidi tobacco powder during combustion and pyrolysis. J Hazard Mater 199–200:200–208PubMed Ahamad T, Alshehri SM (2012) TG–FTIR–MS (evolved gas analysis) of bidi tobacco powder during combustion and pyrolysis. J Hazard Mater 199–200:200–208PubMed
Zurück zum Zitat Baker RR, Pereira da Silva JR, Smith G (2004) The effect of tobacco ingredients on smoke chemistry. Part I: flavourings and additives. Food Chem Toxicol 42:3–37 Baker RR, Pereira da Silva JR, Smith G (2004) The effect of tobacco ingredients on smoke chemistry. Part I: flavourings and additives. Food Chem Toxicol 42:3–37
Zurück zum Zitat Berski W, Ptaszek A, Ptaszek P, Ziobro R, Kowalski G, Grzesik M, Achremowicz B (2011) Pasting and rheological properties of oat starch and its derivatives. Carbohyd Polym 83:665–671 Berski W, Ptaszek A, Ptaszek P, Ziobro R, Kowalski G, Grzesik M, Achremowicz B (2011) Pasting and rheological properties of oat starch and its derivatives. Carbohyd Polym 83:665–671
Zurück zum Zitat Calabuig E, Juárez-Serrano N, Marcilla A (2019) TG-FTIR study of evolved gas in the decomposition of different types tobacco. Effect of the addition of SBA-15. Thermochim Acta 671:209–219 Calabuig E, Juárez-Serrano N, Marcilla A (2019) TG-FTIR study of evolved gas in the decomposition of different types tobacco. Effect of the addition of SBA-15. Thermochim Acta 671:209–219
Zurück zum Zitat Chen M, Xu Z, Chen G, Ge S, Yin C, Zhou Z, Sun W, Li Y, Zhong F (2014a) The generation of carbon monoxide and carbonyl compounds in restituted tobacco sheet. J Therm Anal Calorim 115:961–970 Chen M, Xu Z, Chen G, Ge S, Yin C, Zhou Z, Sun W, Li Y, Zhong F (2014a) The generation of carbon monoxide and carbonyl compounds in restituted tobacco sheet. J Therm Anal Calorim 115:961–970
Zurück zum Zitat Chen M, Xu Z, Chen G, Wang H, Yin C, Zhou Z, Sun W, Li Y, Zhong F (2014b) The influence of exogenous fiber on the generation of carbonyl compounds in reconstituted tobacco sheet. J Anal Appl Pyrol 105:227–233 Chen M, Xu Z, Chen G, Wang H, Yin C, Zhou Z, Sun W, Li Y, Zhong F (2014b) The influence of exogenous fiber on the generation of carbonyl compounds in reconstituted tobacco sheet. J Anal Appl Pyrol 105:227–233
Zurück zum Zitat Chen L, Wang X, Yang H, Lu Q, Li D, Yang Q, Chen H (2015a) Study on pyrolysis behaviors of non-woody lignins with TG-FTIR and Py-GC/MS. J Anal Appl Pyrol 113:499–507 Chen L, Wang X, Yang H, Lu Q, Li D, Yang Q, Chen H (2015a) Study on pyrolysis behaviors of non-woody lignins with TG-FTIR and Py-GC/MS. J Anal Appl Pyrol 113:499–507
Zurück zum Zitat Chen S, Li X, Li Y, Sun J (2015b) Intumescent flame retardant and self-healing superhydrophobic coatings on cotton fabric. ACS Nano 9:4070–4084PubMed Chen S, Li X, Li Y, Sun J (2015b) Intumescent flame retardant and self-healing superhydrophobic coatings on cotton fabric. ACS Nano 9:4070–4084PubMed
Zurück zum Zitat Chen J, Wang Y, Liu J, Xu X (2020) Preparation, characterization physicochemical property and potential application of porous starch: a review. Int J Biol Macromol 148:1169–1181PubMed Chen J, Wang Y, Liu J, Xu X (2020) Preparation, characterization physicochemical property and potential application of porous starch: a review. Int J Biol Macromol 148:1169–1181PubMed
Zurück zum Zitat Deng S, Liao W, Yang J, Cao Z, Wang Y (2016) Flame-retardant and smoke-suppressed silicone foams with chitosan-based nanocoatings. Ind Eng Chem Res 55:7239–7248 Deng S, Liao W, Yang J, Cao Z, Wang Y (2016) Flame-retardant and smoke-suppressed silicone foams with chitosan-based nanocoatings. Ind Eng Chem Res 55:7239–7248
Zurück zum Zitat Ding M, Wei B, Zhang Z, She S, Huang L, Ge S, Sheng L (2017) Effect of potassium organic and inorganic salts on thermal decomposition of reconstituted tobacco sheet. J Therm Anal Calorim 129:975–984 Ding M, Wei B, Zhang Z, She S, Huang L, Ge S, Sheng L (2017) Effect of potassium organic and inorganic salts on thermal decomposition of reconstituted tobacco sheet. J Therm Anal Calorim 129:975–984
Zurück zum Zitat Gao W, Chen K, Yang R, Yang F (2015) Process for coating of reconstituted tobacco sheet with citrates. J Anal Appl Pyrol 114:138–142 Gao W, Chen K, Yang R, Yang F (2015) Process for coating of reconstituted tobacco sheet with citrates. J Anal Appl Pyrol 114:138–142
Zurück zum Zitat Hamadache H, Djidjelli H, Boukerrou A, Kaci M, Antonio J, Martin-Martinez J (2019) Different compatibility approaches to improve the thermal and mechanical properties of EVA/starch composites. Polym Compos 40:3242–3253 Hamadache H, Djidjelli H, Boukerrou A, Kaci M, Antonio J, Martin-Martinez J (2019) Different compatibility approaches to improve the thermal and mechanical properties of EVA/starch composites. Polym Compos 40:3242–3253
Zurück zum Zitat ISO 4387 (1991) Cigarettes-determination of total and nicotine free dry particulate matter using a routine analytical smoking machine; Reference number ISO 4378:1991 (E). International organization for standardization, Geneva ISO 4387 (1991) Cigarettes-determination of total and nicotine free dry particulate matter using a routine analytical smoking machine; Reference number ISO 4378:1991 (E). International organization for standardization, Geneva
Zurück zum Zitat Jin W, Shen D, Liu Q, Xiao R (2016) Evaluation of the co-pyrolysis of lignin with plastic polymers by TG-FTIR and Py-GC/MS. Polym Degrad Stab 133:65–74 Jin W, Shen D, Liu Q, Xiao R (2016) Evaluation of the co-pyrolysis of lignin with plastic polymers by TG-FTIR and Py-GC/MS. Polym Degrad Stab 133:65–74
Zurück zum Zitat Li B, Pang H, Zhao L, Wang B, Liu C, McAdam K, Luo D (2014) Quantifying gas-phase temperature inside a burning cigarette. Ind Eng Chem Res 53:7810–7820 Li B, Pang H, Zhao L, Wang B, Liu C, McAdam K, Luo D (2014) Quantifying gas-phase temperature inside a burning cigarette. Ind Eng Chem Res 53:7810–7820
Zurück zum Zitat Li X, Zhao Z, Wang H, Yan H, Zhang X, Xu B (2017) Highly efficient flame retardant, flexible, and strong adhesive intumescent coating on polypropylene using hyperbranched polyamide. Chem Eng J 324:237–250 Li X, Zhao Z, Wang H, Yan H, Zhang X, Xu B (2017) Highly efficient flame retardant, flexible, and strong adhesive intumescent coating on polypropylene using hyperbranched polyamide. Chem Eng J 324:237–250
Zurück zum Zitat Lin D, Zeng X, Li H, Lai X (2018) Facile fabrication of superhydrophobic and flame-retardant coatings on cotton fabrics via layer-by-layer assembly. Cellulose 25:3135–3149 Lin D, Zeng X, Li H, Lai X (2018) Facile fabrication of superhydrophobic and flame-retardant coatings on cotton fabrics via layer-by-layer assembly. Cellulose 25:3135–3149
Zurück zum Zitat Liu X, Zhang Q, Cheng B, Ren Y, Zhang Y, Ding C (2018) Durable flame retardant cellulosic fibers modified with novel, facile and efficient phytic acid-based finishing agent. Cellulose 25:799–811 Liu X, Zhang Q, Cheng B, Ren Y, Zhang Y, Ding C (2018) Durable flame retardant cellulosic fibers modified with novel, facile and efficient phytic acid-based finishing agent. Cellulose 25:799–811
Zurück zum Zitat Liu J, Dong C, Zhang Z, Kong D, Sun H, Lu Z (2020) Multifuction flame-retarded and hydrophobic cotton fabrics modfied with a cyclic phophorus/polysiloxane copolymer. Cellulose 27:3531–3549 Liu J, Dong C, Zhang Z, Kong D, Sun H, Lu Z (2020) Multifuction flame-retarded and hydrophobic cotton fabrics modfied with a cyclic phophorus/polysiloxane copolymer. Cellulose 27:3531–3549
Zurück zum Zitat Oltramari K, Madrona G, Neto A, Morais G, Baesso M, Bergamasco R, Moraes F (2017) Citrate esterified cassava starch: preparation, physicochemical characterisation. Starch/Stärke 69:1700044 Oltramari K, Madrona G, Neto A, Morais G, Baesso M, Bergamasco R, Moraes F (2017) Citrate esterified cassava starch: preparation, physicochemical characterisation. Starch/Stärke 69:1700044
Zurück zum Zitat Passauer L, Liebner F, Fischer K (2009) Starch phosphate hydrogels. PartI: synthesis by mono-phosphorylation and cross-linking of starch. Starch/Stärke 61:621–627 Passauer L, Liebner F, Fischer K (2009) Starch phosphate hydrogels. PartI: synthesis by mono-phosphorylation and cross-linking of starch. Starch/Stärke 61:621–627
Zurück zum Zitat Safdari M, Amini E, Weise D, Fletcher T (2019) Heating rate and temperature effects on pyrolysis products from live wildland fuels. Fuel 242:295–304 Safdari M, Amini E, Weise D, Fletcher T (2019) Heating rate and temperature effects on pyrolysis products from live wildland fuels. Fuel 242:295–304
Zurück zum Zitat Schirp A, Hellmann A (2019) Fire retardancy improvement of high-density polyethylene composites based on thermomechanical pulp treated with ammonium polyphosphate. Polym Compos 40:2410–2423 Schirp A, Hellmann A (2019) Fire retardancy improvement of high-density polyethylene composites based on thermomechanical pulp treated with ammonium polyphosphate. Polym Compos 40:2410–2423
Zurück zum Zitat Shen J, Fatehi P, Ni Y (2014) Biopolymers for surface engineering of paper-based products. Cellulose 21:3145–3160 Shen J, Fatehi P, Ni Y (2014) Biopolymers for surface engineering of paper-based products. Cellulose 21:3145–3160
Zurück zum Zitat Shi Y, Wang G (2016) The novel epoxy/PEPA phosphate flame retardants: synthesis, characterization and application in transparent intumescent fire resistant coatings. Prog Org Coat 97:1–9 Shi Y, Wang G (2016) The novel epoxy/PEPA phosphate flame retardants: synthesis, characterization and application in transparent intumescent fire resistant coatings. Prog Org Coat 97:1–9
Zurück zum Zitat Takahashi Y, Kanemaru Y, Fukushima T, Eguchi K, Yoshida S, Miller-Holt J, Jonese I (2018) Chemical analysis and in vitro toxicological evaluation of aerosol from a novel tobacco vapor product: a comparison with cigarette smoke. Regul Toxicol Pharm 92:94–183 Takahashi Y, Kanemaru Y, Fukushima T, Eguchi K, Yoshida S, Miller-Holt J, Jonese I (2018) Chemical analysis and in vitro toxicological evaluation of aerosol from a novel tobacco vapor product: a comparison with cigarette smoke. Regul Toxicol Pharm 92:94–183
Zurück zum Zitat Talhout R, Schulz T, Florek E, Benthem J, Wester P, Opperhuizen A (2011) Hazardous compounds in tobacco smoke. Int J Environ Res Public Health 8:613–628PubMedPubMedCentral Talhout R, Schulz T, Florek E, Benthem J, Wester P, Opperhuizen A (2011) Hazardous compounds in tobacco smoke. Int J Environ Res Public Health 8:613–628PubMedPubMedCentral
Zurück zum Zitat Wang Y, Chen K, Mo L, Li J, Xu J (2014) Optimization of coagulation-flocculation process for papermaking-reconstituted tobacco slice wastewater treatment using response surface methodology. J Ind Eng Chem 20:391–396 Wang Y, Chen K, Mo L, Li J, Xu J (2014) Optimization of coagulation-flocculation process for papermaking-reconstituted tobacco slice wastewater treatment using response surface methodology. J Ind Eng Chem 20:391–396
Zurück zum Zitat Wang X, Yuan Y, Yue T (2015) The application of starch-based ingredients in flavor encapsulation. Starch/Stärke 67:225–236 Wang X, Yuan Y, Yue T (2015) The application of starch-based ingredients in flavor encapsulation. Starch/Stärke 67:225–236
Zurück zum Zitat Wang W, Wen P, Zhan J, Hong N, Cai W, Gui Z, Hu Y (2017) Synthesis of a novel charring agent containing pentaerythritol and triazine structure and its intumescent flame retardant performance for polypropylene. Polym Degrad Stab 144:454–463 Wang W, Wen P, Zhan J, Hong N, Cai W, Gui Z, Hu Y (2017) Synthesis of a novel charring agent containing pentaerythritol and triazine structure and its intumescent flame retardant performance for polypropylene. Polym Degrad Stab 144:454–463
Zurück zum Zitat Wang D, Zhong L, Zhang C, Li S, Tian P, Zhang F, Zhang G (2019) Eco-friendly synthesis of a highly efficient phosphorus flame retardant based on xylitol and application on cotton fabric. Cellulose 26:2123–2138 Wang D, Zhong L, Zhang C, Li S, Tian P, Zhang F, Zhang G (2019) Eco-friendly synthesis of a highly efficient phosphorus flame retardant based on xylitol and application on cotton fabric. Cellulose 26:2123–2138
Zurück zum Zitat Wang W, Guo J, Liu X, Li H, Sun J, Gu X, Wang J, Zhang S, Li W (2020) Constructiong eco-friendly flame retardant coating on cotton fabrics by layer-by-layer self-accembly. Cellulose 27:5377–5389 Wang W, Guo J, Liu X, Li H, Sun J, Gu X, Wang J, Zhang S, Li W (2020) Constructiong eco-friendly flame retardant coating on cotton fabrics by layer-by-layer self-accembly. Cellulose 27:5377–5389
Zurück zum Zitat Xu F, Zhong L, Xu Y, Zhang C, Zhang F, Zhang G (2019) Highly efficient flame-retardant and soft cotton fabric prepared by a novel reactive flame retardant. Cellulose 26:4224–4240 Xu F, Zhong L, Xu Y, Zhang C, Zhang F, Zhang G (2019) Highly efficient flame-retardant and soft cotton fabric prepared by a novel reactive flame retardant. Cellulose 26:4224–4240
Zurück zum Zitat Yan H, Li N, Cheng J, Song P, Fang Z, Wang H (2018) Fabrication of flame retardant benzoxazine semi biocomposites reinforced by ramie fabrics with bio-based flame retardant coating. Polym Compos 39(S1):E480–E488 Yan H, Li N, Cheng J, Song P, Fang Z, Wang H (2018) Fabrication of flame retardant benzoxazine semi biocomposites reinforced by ramie fabrics with bio-based flame retardant coating. Polym Compos 39(S1):E480–E488
Zurück zum Zitat Yang Z, Fu L, Fan F (2019) Thermal characteristics and kinetics of waste Camellia oleifera shells by TG-GC/MS. ACS Omega 4:10370–10375PubMedPubMedCentral Yang Z, Fu L, Fan F (2019) Thermal characteristics and kinetics of waste Camellia oleifera shells by TG-GC/MS. ACS Omega 4:10370–10375PubMedPubMedCentral
Zurück zum Zitat Zeng F, Qin Z, Li T, Chen Y, Yang L (2020) Boosting phosphorus-nitrogen-silicon synergism through introducing graphene nanobrick wall structure for fabrication multifuctional cotton fabric by spray assisted layer-by-layer assembly. Cellulose 27:6691–6705 Zeng F, Qin Z, Li T, Chen Y, Yang L (2020) Boosting phosphorus-nitrogen-silicon synergism through introducing graphene nanobrick wall structure for fabrication multifuctional cotton fabric by spray assisted layer-by-layer assembly. Cellulose 27:6691–6705
Zurück zum Zitat Zhang L, Xue W, Gu L (2020) Study on properties and application of pyrophosphate flame retardant microcapsules prepared from hemicellulose maleate. Cellulose 27:3931–3946 Zhang L, Xue W, Gu L (2020) Study on properties and application of pyrophosphate flame retardant microcapsules prepared from hemicellulose maleate. Cellulose 27:3931–3946
Zurück zum Zitat Zhao B, Kolibaba TJ, Lazar S, Grunlan JC (2020) Facile two-step phosphazine-based network coating for flame retardant cotton. Cellulose 27:4123–4132 Zhao B, Kolibaba TJ, Lazar S, Grunlan JC (2020) Facile two-step phosphazine-based network coating for flame retardant cotton. Cellulose 27:4123–4132
Zurück zum Zitat Zhou S, Ning M, Xu Y, Hu Y, Shu J, Wang C, Ge S, Tian Z, She S, He Q (2013) Thermal degradation and combustion behavior of reconstituted tobacco sheet treated with ammonium polyphosphate. J Anal Appl Pyrol 100:223–229 Zhou S, Ning M, Xu Y, Hu Y, Shu J, Wang C, Ge S, Tian Z, She S, He Q (2013) Thermal degradation and combustion behavior of reconstituted tobacco sheet treated with ammonium polyphosphate. J Anal Appl Pyrol 100:223–229
Zurück zum Zitat Zhou S, He Q, Wang X, Ning M, Yang Y, Xu Y, Zhang Y, Zou P, Tian Z, Chen K, Wang H, She S (2017) An insight into the roles of exogenous potassium salts on the thermal degradation of flue-cured tobacco. J Anal Appl Pyrol 123:385–394 Zhou S, He Q, Wang X, Ning M, Yang Y, Xu Y, Zhang Y, Zou P, Tian Z, Chen K, Wang H, She S (2017) An insight into the roles of exogenous potassium salts on the thermal degradation of flue-cured tobacco. J Anal Appl Pyrol 123:385–394
Zurück zum Zitat Zhu X, He Q, Hu Y, Huang R, Shao N, Gao Y (2018) A comparative study of structure, thermal degradation, and combustion behavior of starch from different plant sources. J Therm Anal Calorim 132:927–935 Zhu X, He Q, Hu Y, Huang R, Shao N, Gao Y (2018) A comparative study of structure, thermal degradation, and combustion behavior of starch from different plant sources. J Therm Anal Calorim 132:927–935
Metadaten
Titel
Effect of starch-based flame retardant on the thermal degradation and combustion properties of reconstituted tobacco sheet
verfasst von
Ning Shao
Yaqing Qu
Li Hou
Yonghua Hu
Zhengfeng Tian
Yun Gao
Xiaolan Zhu
Publikationsdatum
27.11.2020
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 2/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-020-03587-8

Weitere Artikel der Ausgabe 2/2021

Cellulose 2/2021 Zur Ausgabe