Skip to main content
Erschienen in: Journal of Materials Science 13/2017

31.03.2017 | Original Paper

Effect of temperature on graphene grown by chemical vapor deposition

verfasst von: Stefanos Chaitoglou, Enric Bertran

Erschienen in: Journal of Materials Science | Ausgabe 13/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Large-area single-crystal graphene films remain a challenge which settlement will permit to take full profit of the intrinsic properties of the material in electronic application. Toward this direction, in the present work we study the effect of temperature on the chemical vapor deposition growth of graphene over copper foil, in low pressure. Graphene growth commence with the crystallization of a supersaturated fraction of carbon-adatom species, while the nucleation density is the result of competition between the mobility of the carbon-adatom species and their desorption rate. We study the nuclei size and density distribution, growth rate and coverage rate to calculate the nucleation activation energy. In addition, we provide information considering the control of the intrinsic strain present in the graphene domains as a result of the ripple formation. We study the agreement, considering the ripple formation, between the theoretical model of thermal grooving and observation made by atomic force microscopy.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Zurück zum Zitat Ferrari A, Bonaccorso F, Falko V, Novoselov K, Roche S, Bøggild P, Borini S, Koppens F, Palermo V, Pugno N et al (2015) Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems. Nanoscale 7:4598CrossRef Ferrari A, Bonaccorso F, Falko V, Novoselov K, Roche S, Bøggild P, Borini S, Koppens F, Palermo V, Pugno N et al (2015) Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems. Nanoscale 7:4598CrossRef
2.
Zurück zum Zitat Engel M, Steiner M, Lombardo A, Ferrari A, Löhneysen H, Avouris P, Krupke R (2012) Light–matter interaction in a microcavity-controlled graphene transistor. Nat Commun 3:906CrossRef Engel M, Steiner M, Lombardo A, Ferrari A, Löhneysen H, Avouris P, Krupke R (2012) Light–matter interaction in a microcavity-controlled graphene transistor. Nat Commun 3:906CrossRef
3.
Zurück zum Zitat Han W, Kawakami R, Gmitra M, Fabian J (2014) Graphene spintronics. Nat Nanotechnol 9:794–807CrossRef Han W, Kawakami R, Gmitra M, Fabian J (2014) Graphene spintronics. Nat Nanotechnol 9:794–807CrossRef
4.
Zurück zum Zitat Wang C, Chen W, Han C, Wang G, Tang B, Tang C, Wang Y, Zou W, Chen W, Zhang X, Qin S, Chang S, Wang L (2014) Growth of millimeter-size single crystal graphene on cu foils by circumfluence chemical vapor deposition. Sci Rep 4:4537 Wang C, Chen W, Han C, Wang G, Tang B, Tang C, Wang Y, Zou W, Chen W, Zhang X, Qin S, Chang S, Wang L (2014) Growth of millimeter-size single crystal graphene on cu foils by circumfluence chemical vapor deposition. Sci Rep 4:4537
5.
Zurück zum Zitat Li X, Magnuson CW, Venugopal A, Tromp RM, Hannon JB, Vogel EM, Colombo L, Ruoff RS (2011) Large area graphene single crystals grown by low-pressure chemical vapor deposition of methane on copper. J Am Chem Soc 133:2816CrossRef Li X, Magnuson CW, Venugopal A, Tromp RM, Hannon JB, Vogel EM, Colombo L, Ruoff RS (2011) Large area graphene single crystals grown by low-pressure chemical vapor deposition of methane on copper. J Am Chem Soc 133:2816CrossRef
6.
Zurück zum Zitat Vlassiouk I, Regmi M, Fulvio P, Dai S, Datskos P, Eres G, Smirnov S (2011) Role of hydrogen in chemical vapor deposition growth of large single-crystal graphene. ACS Nano 5:6069–6076CrossRef Vlassiouk I, Regmi M, Fulvio P, Dai S, Datskos P, Eres G, Smirnov S (2011) Role of hydrogen in chemical vapor deposition growth of large single-crystal graphene. ACS Nano 5:6069–6076CrossRef
7.
Zurück zum Zitat Chaitoglou S, Bertran E (2016) Effect of pressure and hydrogen flow in nucleation density andmorphology of graphene bidimensional crystals. Mater Res Express 3:075603CrossRef Chaitoglou S, Bertran E (2016) Effect of pressure and hydrogen flow in nucleation density andmorphology of graphene bidimensional crystals. Mater Res Express 3:075603CrossRef
8.
Zurück zum Zitat Chaitoglou S, Pascual E, Bertran E, Andujar JL (2016) Effect of a balanced concentration of hydrogen on graphene CVD growth. J Nanomater 2016:9640935CrossRef Chaitoglou S, Pascual E, Bertran E, Andujar JL (2016) Effect of a balanced concentration of hydrogen on graphene CVD growth. J Nanomater 2016:9640935CrossRef
9.
Zurück zum Zitat Schneider CA, Rasband WS, Eliceiri KW (2012) NIH Image to ImageJ: 25 years of image analysis. Nat Methods 9:671–675CrossRef Schneider CA, Rasband WS, Eliceiri KW (2012) NIH Image to ImageJ: 25 years of image analysis. Nat Methods 9:671–675CrossRef
10.
Zurück zum Zitat Park WH, Jo I, Hong BH, Cheong H (2016) Controlling the ripple density and heights: a new way to improve the electrical performance of CVD-grown graphene. Nanoscale 8:9822CrossRef Park WH, Jo I, Hong BH, Cheong H (2016) Controlling the ripple density and heights: a new way to improve the electrical performance of CVD-grown graphene. Nanoscale 8:9822CrossRef
11.
Zurück zum Zitat Jung DH, Kang C, Nam JE, Jeong H, Lee JS (2016) Surface diffusion directed growth of anisotropic graphene domains on different copper lattices. Sci Rep 6:21136CrossRef Jung DH, Kang C, Nam JE, Jeong H, Lee JS (2016) Surface diffusion directed growth of anisotropic graphene domains on different copper lattices. Sci Rep 6:21136CrossRef
12.
Zurück zum Zitat Kim H, Mattevi C, Reyes Calvo M, Oberg J, Artiglia L, Agnoli S, Hirjibehedin C, Chhowalla M, Saiz E (2012) Activation energy paths for graphene nucleation and growth on cu. ACS Nano 6:3614–3623CrossRef Kim H, Mattevi C, Reyes Calvo M, Oberg J, Artiglia L, Agnoli S, Hirjibehedin C, Chhowalla M, Saiz E (2012) Activation energy paths for graphene nucleation and growth on cu. ACS Nano 6:3614–3623CrossRef
13.
Zurück zum Zitat Loginova E, Norman CB, Peter JF, Kevin FM (2008) Evidence for graphene growth by C cluster attachment. New J Phys 10:093026CrossRef Loginova E, Norman CB, Peter JF, Kevin FM (2008) Evidence for graphene growth by C cluster attachment. New J Phys 10:093026CrossRef
14.
Zurück zum Zitat Robinson VNE, Robins JL (1974) nucleation kinetics of gold deposited onto UHV cleaved surfaces of NaCl and KBr. Thin Solid Films 20:155–175CrossRef Robinson VNE, Robins JL (1974) nucleation kinetics of gold deposited onto UHV cleaved surfaces of NaCl and KBr. Thin Solid Films 20:155–175CrossRef
15.
Zurück zum Zitat Xing S, Wu W, Wang Y, Bao J, Pei S (2013) Kinetic study of graphene growth: temperature perspective on growth rate and film thickness by chemical vapor deposition. Chem Phys Lett 580:62–66CrossRef Xing S, Wu W, Wang Y, Bao J, Pei S (2013) Kinetic study of graphene growth: temperature perspective on growth rate and film thickness by chemical vapor deposition. Chem Phys Lett 580:62–66CrossRef
16.
Zurück zum Zitat Hayashi K, Sato S, Ikeda M, Kaneta C, Yokoyama N (2012) Selective graphene formation on copper twin crystal. J Am Chem Soc 134:12492CrossRef Hayashi K, Sato S, Ikeda M, Kaneta C, Yokoyama N (2012) Selective graphene formation on copper twin crystal. J Am Chem Soc 134:12492CrossRef
17.
Zurück zum Zitat Vlassiouk I, Smirnov S, Surwade S, Regmi M, Srivastava N, Feenstra R, Eres G, Parish C, Lavrik N, Datskos P, Dai S, Fulvio P (2013) Graphene nucleation density on copper: fundamental role of background pressure. J Phys Chem C 117:18919CrossRef Vlassiouk I, Smirnov S, Surwade S, Regmi M, Srivastava N, Feenstra R, Eres G, Parish C, Lavrik N, Datskos P, Dai S, Fulvio P (2013) Graphene nucleation density on copper: fundamental role of background pressure. J Phys Chem C 117:18919CrossRef
18.
Zurück zum Zitat Troppenz GV, Gluba MA, Kraft M, Rappich J, Nickel NH (2013) Strain relaxation in graphene grown by chemical vapor deposition. J Appl Phys 114:214312CrossRef Troppenz GV, Gluba MA, Kraft M, Rappich J, Nickel NH (2013) Strain relaxation in graphene grown by chemical vapor deposition. J Appl Phys 114:214312CrossRef
19.
Zurück zum Zitat Lin Z, Ye X, Han J, Chen Q, Fan P, Zhang H, Xie D, Zhu H, Zhong M (2015) Precise control of the number of layers of graphene by picosecond laser thinning. Sci Rep 5:11662CrossRef Lin Z, Ye X, Han J, Chen Q, Fan P, Zhang H, Xie D, Zhu H, Zhong M (2015) Precise control of the number of layers of graphene by picosecond laser thinning. Sci Rep 5:11662CrossRef
20.
Zurück zum Zitat Yin X, Li Y, Ke F, Lin C, Zhao H, Gan L, Luo Z, Zhao R, Heinz TF, Hu Z (2014) Evolution of the Raman spectrum of graphene grown on copper upon oxidation of the substrate. Nano Res 7:1613–1622CrossRef Yin X, Li Y, Ke F, Lin C, Zhao H, Gan L, Luo Z, Zhao R, Heinz TF, Hu Z (2014) Evolution of the Raman spectrum of graphene grown on copper upon oxidation of the substrate. Nano Res 7:1613–1622CrossRef
21.
Zurück zum Zitat Paronyan TM, Pigos EM, Chen G, Harutyunyan AR (2011) Formation of ripples in graphene as a result of interfacial instabilities. ACS Nano 5:9619–9627CrossRef Paronyan TM, Pigos EM, Chen G, Harutyunyan AR (2011) Formation of ripples in graphene as a result of interfacial instabilities. ACS Nano 5:9619–9627CrossRef
22.
Zurück zum Zitat Mullins WW, Sekerka RF (1964) Stability of a planar interface during solidification of a dilute binary alloy. J Appl Phys 35:444–451CrossRef Mullins WW, Sekerka RF (1964) Stability of a planar interface during solidification of a dilute binary alloy. J Appl Phys 35:444–451CrossRef
23.
Zurück zum Zitat Chaitoglou S, Bertran E (2016) Control of the strain in chemical vapor deposition grown graphene over copper via the H2 flow. J Phys Chem C 2120:25572–25577CrossRef Chaitoglou S, Bertran E (2016) Control of the strain in chemical vapor deposition grown graphene over copper via the H2 flow. J Phys Chem C 2120:25572–25577CrossRef
24.
25.
Zurück zum Zitat Wang ZJ, Weinberg G, Zhang Q, Lunkenbein T, Klein-Hoffmann A, Kurnatowska M, Plodinec M, Li Q, Chi L, Schloegl R, Willinger M (2015) Direct observation of graphene growth and associated copper substrate dynamics by in situ scanning electron microscopy. ACS Nano 9:1506–1519CrossRef Wang ZJ, Weinberg G, Zhang Q, Lunkenbein T, Klein-Hoffmann A, Kurnatowska M, Plodinec M, Li Q, Chi L, Schloegl R, Willinger M (2015) Direct observation of graphene growth and associated copper substrate dynamics by in situ scanning electron microscopy. ACS Nano 9:1506–1519CrossRef
Metadaten
Titel
Effect of temperature on graphene grown by chemical vapor deposition
verfasst von
Stefanos Chaitoglou
Enric Bertran
Publikationsdatum
31.03.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 13/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1054-1

Weitere Artikel der Ausgabe 13/2017

Journal of Materials Science 13/2017 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.