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Erschienen in: Interceram - International Ceramic Review 6/2018

01.10.2018 | Research and Development

Effect of Titanium and Vanadium on Nanomullite Derived from Diphasic Precursor Gel

verfasst von: Dr. Jagannath Roy, Saikat Maitra

Erschienen in: Interceram - International Ceramic Review | Ausgabe 6/2018

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Abstract

To process mullite ceramics, diphasic aluminosilicate gel was synthesized from inorganic salts by employing the sol-gel route. The process of mullitization was studied by FTIR, DTA and SEM analysis. The particle size of the mullite ceramics was found to be in the nanometer range. The gel was calcined at 800°C. To the calcined gel, oxides of titanium and vanadium were mixed separately. The powder masses were compacted at 100 MPa pressure and then sintered at different elevated temperatures. The mechanical and microstructural properties of the doped samples were studied, and it was found that both the oxides influenced the process of mullitization positively.

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Literatur
[1]
Zurück zum Zitat Aksay, I.A., Pask, J.A.: Stable and metastable equilibria in system SiO2-Al2O3.J. Eur. Ceram. Soc. 58 (1975) 507–512.CrossRef Aksay, I.A., Pask, J.A.: Stable and metastable equilibria in system SiO2-Al2O3.J. Eur. Ceram. Soc. 58 (1975) 507–512.CrossRef
[2]
Zurück zum Zitat Klug, F.J., Prochazka, S.: Doremus, R.H. Alumina-silica phase diagram in the mullite region. J. Am. Ceram. Soc. 70 (1987) 750–759.CrossRef Klug, F.J., Prochazka, S.: Doremus, R.H. Alumina-silica phase diagram in the mullite region. J. Am. Ceram. Soc. 70 (1987) 750–759.CrossRef
[3]
Zurück zum Zitat Schneider, H., Eberhard, E.: Thermal expansion of mullite.J. Am. Ceram. Soc. 73 (1990) 2073–2076.CrossRef Schneider, H., Eberhard, E.: Thermal expansion of mullite.J. Am. Ceram. Soc. 73 (1990) 2073–2076.CrossRef
[4]
Zurück zum Zitat Hynes, A.P., Doremus, R.H.: High-temperature compressive creep of polycrystalline mullite. J. Am. Ceram. Soc. 74 (1991) 2469–2475.CrossRef Hynes, A.P., Doremus, R.H.: High-temperature compressive creep of polycrystalline mullite. J. Am. Ceram. Soc. 74 (1991) 2469–2475.CrossRef
[5]
Zurück zum Zitat Kollenberg, W., Schneider, H.: Microhardness of mullite at temperatures to 1000 °C. J. Am. Ceram. Soc. 72 (1989) 1739–1740.CrossRef Kollenberg, W., Schneider, H.: Microhardness of mullite at temperatures to 1000 °C. J. Am. Ceram. Soc. 72 (1989) 1739–1740.CrossRef
[6]
Zurück zum Zitat Aksay, A., Dabbs, D.M., Sarikaya, M.: Mullite for structural, electronic and optical applications. J. Am. Ceram. Soc. 74 (1991)2343–2358.CrossRef Aksay, A., Dabbs, D.M., Sarikaya, M.: Mullite for structural, electronic and optical applications. J. Am. Ceram. Soc. 74 (1991)2343–2358.CrossRef
[7]
Zurück zum Zitat Skoog, A.J., Moore, R. E.: Refractory of the past for the future: mullite and its use as a bonding phase. Am. Ceram. Soc. Bull. 67 (1988)1180–1185. Skoog, A.J., Moore, R. E.: Refractory of the past for the future: mullite and its use as a bonding phase. Am. Ceram. Soc. Bull. 67 (1988)1180–1185.
[8]
Zurück zum Zitat Ramakrishnan, V., Goo, E., Roldan, J.M., Giess, E.A.: Microstructure of mullite ceramics used for substrate and packaging applications. J. Mater. Sci. 27 (1992) 6127–6130.CrossRef Ramakrishnan, V., Goo, E., Roldan, J.M., Giess, E.A.: Microstructure of mullite ceramics used for substrate and packaging applications. J. Mater. Sci. 27 (1992) 6127–6130.CrossRef
[9]
Zurück zum Zitat Mazel, F., Gonon, M., Fantozzi, G.: Manufacture of mullite substrates from andalusite for the development of thin film solar cells. J. Eur. Ceram. Soc. 22 (2002) 453–461.CrossRef Mazel, F., Gonon, M., Fantozzi, G.: Manufacture of mullite substrates from andalusite for the development of thin film solar cells. J. Eur. Ceram. Soc. 22 (2002) 453–461.CrossRef
[10]
Zurück zum Zitat Shinohara, N., Dabs, D.M., Aksay, I.A.: Infrared transparent mullite through densification of monolithic gels at 1250 °C. Proc. SPIE—Int. Soc. Opt. Eng. 83 (1986) 19–24. Shinohara, N., Dabs, D.M., Aksay, I.A.: Infrared transparent mullite through densification of monolithic gels at 1250 °C. Proc. SPIE—Int. Soc. Opt. Eng. 83 (1986) 19–24.
[11]
Zurück zum Zitat Cividanes, L.S., Campos, T.M.B., Rodrigues, L.A., Brunelli, D.D.: Thim, G.P. Review of mullite synthesis routes by solgel method. J. Sol-Gel Sci. Technol. 55 (2010) 111–125.CrossRef Cividanes, L.S., Campos, T.M.B., Rodrigues, L.A., Brunelli, D.D.: Thim, G.P. Review of mullite synthesis routes by solgel method. J. Sol-Gel Sci. Technol. 55 (2010) 111–125.CrossRef
[12]
Zurück zum Zitat Padmaja, P., Anilkumar, G.M., Warrier, K.G.K.: Characterization of stoichiometric sol-gel mullite by fourier transform infrared spectroscopy. Int. J. Inorg. Mater.3(2001) 693–698.CrossRef Padmaja, P., Anilkumar, G.M., Warrier, K.G.K.: Characterization of stoichiometric sol-gel mullite by fourier transform infrared spectroscopy. Int. J. Inorg. Mater.3(2001) 693–698.CrossRef
[13]
Zurück zum Zitat Yu, J., Shi, J., Yuan, Q., Yang, Z., Chen, Y.: Effect of composition on the sintering and microstructure of diphasic mullite gels, Ceram. Int. 26 (2000) 255–263.CrossRef Yu, J., Shi, J., Yuan, Q., Yang, Z., Chen, Y.: Effect of composition on the sintering and microstructure of diphasic mullite gels, Ceram. Int. 26 (2000) 255–263.CrossRef
[14]
Zurück zum Zitat Campos, A.L., Silva, N.T., Melo, F.C.L., Oliveira, M.A.S., Thim, G.P.: Crystallization kinetics of orthorhombic mullite from diphasic gels. J. Non-Cryst. Solids. 304 (2002) 19–24.CrossRef Campos, A.L., Silva, N.T., Melo, F.C.L., Oliveira, M.A.S., Thim, G.P.: Crystallization kinetics of orthorhombic mullite from diphasic gels. J. Non-Cryst. Solids. 304 (2002) 19–24.CrossRef
[15]
Zurück zum Zitat Buljan, I., Kosanovic, C., Kralj, D.: Novel synthesis of nanosized mullite from aluminosilicate precursors. J. Alloy. Comp. 509 (2011) 8256–8261.CrossRef Buljan, I., Kosanovic, C., Kralj, D.: Novel synthesis of nanosized mullite from aluminosilicate precursors. J. Alloy. Comp. 509 (2011) 8256–8261.CrossRef
[16]
Zurück zum Zitat Roy, J., Maitra, S.: Synthesis and Characterization of Sol-Gel-Derived Chemical Mullite. J. Ceram. Sci. Tech. 5 (2014) 57–62. Roy, J., Maitra, S.: Synthesis and Characterization of Sol-Gel-Derived Chemical Mullite. J. Ceram. Sci. Tech. 5 (2014) 57–62.
[17]
Zurück zum Zitat Murkhy, M. K., Hummel, F. A.: X-ray study of the solid solution of TiO2, Fe2O3, and Cr2O3 in mullite (3Al2O3•2SiO2). J. Am. Ceram. Soc. 43 (1960) 267–273.CrossRef Murkhy, M. K., Hummel, F. A.: X-ray study of the solid solution of TiO2, Fe2O3, and Cr2O3 in mullite (3Al2O3•2SiO2). J. Am. Ceram. Soc. 43 (1960) 267–273.CrossRef
[18]
Zurück zum Zitat Baudin, C., Moya, J. S.: Influence of titanium dioxide on the sintering and microstructural evolution of mullite. J. Am. Ceram.Soc. 67 (1984) c–134–136. Baudin, C., Moya, J. S.: Influence of titanium dioxide on the sintering and microstructural evolution of mullite. J. Am. Ceram.Soc. 67 (1984) c–134–136.
[19]
Zurück zum Zitat Naga, S. M., El-Maghraby, A.: Preparation and characterization of porous fibrous mullite bodies with TiO2. Mater. Charact. 62 (2011) 174–180.CrossRef Naga, S. M., El-Maghraby, A.: Preparation and characterization of porous fibrous mullite bodies with TiO2. Mater. Charact. 62 (2011) 174–180.CrossRef
[20]
Zurück zum Zitat Zhang, J., Wu, H., Zhang, S., Yu, J., Xiao, H.: Anisotropic grain growth in diphasic-gel-derived vanadium pentoxide doped mullite. J. Cryst. Growth. 364 (2013) 11–15.CrossRef Zhang, J., Wu, H., Zhang, S., Yu, J., Xiao, H.: Anisotropic grain growth in diphasic-gel-derived vanadium pentoxide doped mullite. J. Cryst. Growth. 364 (2013) 11–15.CrossRef
[21]
Zurück zum Zitat Roy, J., Bandyopadhyay. N., Das, S., Maitra, S.: Effect of TiO2 on the formation of mullite ceramics from diphasic Al2O3-SiO2 gel. Interceram 03–04 (2010) 213–217. Roy, J., Bandyopadhyay. N., Das, S., Maitra, S.: Effect of TiO2 on the formation of mullite ceramics from diphasic Al2O3-SiO2 gel. Interceram 03–04 (2010) 213–217.
[22]
Zurück zum Zitat Roy, J., Bandyopadhyay. N., Das, S., Maitra, S.: Role of V2O5 on the formation of chemical mullite from aluminosilicate precursor. Ceram. Int. 36 (2010) 1603–1608.CrossRef Roy, J., Bandyopadhyay. N., Das, S., Maitra, S.: Role of V2O5 on the formation of chemical mullite from aluminosilicate precursor. Ceram. Int. 36 (2010) 1603–1608.CrossRef
[23]
Zurück zum Zitat Roy, J., Bandyopadhyay. N., Das, S., Maitra, S.: Studies on the formation of mullite from diphasic Al2O3-SiO2 Gel by Fourier Transform Infrared Spectroscopy. Iran. J. Chem. Chem. Eng. 30 (2011) 65–71. Roy, J., Bandyopadhyay. N., Das, S., Maitra, S.: Studies on the formation of mullite from diphasic Al2O3-SiO2 Gel by Fourier Transform Infrared Spectroscopy. Iran. J. Chem. Chem. Eng. 30 (2011) 65–71.
[24]
Zurück zum Zitat Okada, K.: Activation energy of mullitization from various starting materials, J. Eur. Ceram. Soc. 28 (2008) 377–382.CrossRef Okada, K.: Activation energy of mullitization from various starting materials, J. Eur. Ceram. Soc. 28 (2008) 377–382.CrossRef
Metadaten
Titel
Effect of Titanium and Vanadium on Nanomullite Derived from Diphasic Precursor Gel
verfasst von
Dr. Jagannath Roy
Saikat Maitra
Publikationsdatum
01.10.2018
Verlag
Springer Fachmedien Wiesbaden
Erschienen in
Interceram - International Ceramic Review / Ausgabe 6/2018
Print ISSN: 0020-5214
Elektronische ISSN: 2523-8957
DOI
https://doi.org/10.1007/s42411-018-0036-x

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