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Erschienen in: Journal of Materials Science: Materials in Electronics 14/2017

06.04.2017

Effects of CaO additives on the structure and properties of Ba6−3xSm8+2xTi18O54 (x = 0.5) ceramics

verfasst von: Xu Wang, Juhua Luo, Hao Guan, Yue Xu

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 14/2017

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Abstract

The tungstenbronze-type-like Single-phase polycrystalline ceramics Ba6−3xSm8+2xTi18O54 (x = 0.5) doping with Ca ions had been prepared through the conventional solid-state reaction process. The phases and structure of the ceramics were analyzed through X-ray diffraction and scanning electron microscopy. The microwave dielectric properties of the ceramics were studied using a network analyzer. In this paper, the quality factor (Q × f) by substituting Ca ions for Ba ions in (Ba1−αCaα) Sm2Ti4O12 solid solutions in A1-sites was reported. In addition, the relationship between crystal structure and microwave dielectric properties was discussed from the viewpoint of structural formula and occupational state of large cations such as Ba, Ca ions in A1-sites.

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Literatur
1.
Zurück zum Zitat R. Freer, F. Azough, Microstructural engineering of microwave dielectric ceramics. J. Eur. Ceram. Soc. 28, 1433–1441 (2008)CrossRef R. Freer, F. Azough, Microstructural engineering of microwave dielectric ceramics. J. Eur. Ceram. Soc. 28, 1433–1441 (2008)CrossRef
2.
Zurück zum Zitat E.A. Nenasheva, N.F. Kartenko, High dielectric constant microwave ceramics. J. Am.Ceram. Soc. 21, 2697–2701 (2001)CrossRef E.A. Nenasheva, N.F. Kartenko, High dielectric constant microwave ceramics. J. Am.Ceram. Soc. 21, 2697–2701 (2001)CrossRef
3.
Zurück zum Zitat I.M. Reaney, D. Iddles, Microwave dielectric ceramics for resonators and filters in mobile phone networks. J. Am. Ceram. Soc. 89, 2063–2072 (2006) I.M. Reaney, D. Iddles, Microwave dielectric ceramics for resonators and filters in mobile phone networks. J. Am. Ceram. Soc. 89, 2063–2072 (2006)
4.
Zurück zum Zitat M.T. Sebastian, Dielectric materials for wireless communication. first ed. Elseiver, Oxford (2008) M.T. Sebastian, Dielectric materials for wireless communication. first ed. Elseiver, Oxford (2008)
5.
Zurück zum Zitat H. Ohsato, Science of tungstenbronze-type like Ba6–3xR8+2xTi18O54(R = rare earth) microwave dielectric solid solutions. J. Eur. Ceram. Soc. 21, 2703–2711 (2001)CrossRef H. Ohsato, Science of tungstenbronze-type like Ba6–3xR8+2xTi18O54(R = rare earth) microwave dielectric solid solutions. J. Eur. Ceram. Soc. 21, 2703–2711 (2001)CrossRef
6.
Zurück zum Zitat M. Valant, D. Suvorov, C.J. Rawn, Intrinsic reasons for variations in dielectric properties of Ba6–3xR8+2xTi18O54(R = La-Gd) solid solutions. Jpn. J. Appl. Phys. 38(5A), 2820–2826 (1999)CrossRef M. Valant, D. Suvorov, C.J. Rawn, Intrinsic reasons for variations in dielectric properties of Ba6–3xR8+2xTi18O54(R = La-Gd) solid solutions. Jpn. J. Appl. Phys. 38(5A), 2820–2826 (1999)CrossRef
7.
Zurück zum Zitat R.L. Bolton, Temperature compensating ceramic capacitors in the system baria rare earth oxide titania. PhD thesis. Ceramic Engineering, University of Illinois, Urbana (1968) R.L. Bolton, Temperature compensating ceramic capacitors in the system baria rare earth oxide titania. PhD thesis. Ceramic Engineering, University of Illinois, Urbana (1968)
8.
Zurück zum Zitat D. Kolar, Z. Stadler, S. Gaberscek, D. Suvorov, Ceramic and dielectric properties of selected compositions in the BaO-TiO2-Nd2O3 system. Ber. Dt. Keram. Ges. 55, 346–347 (1978) D. Kolar, Z. Stadler, S. Gaberscek, D. Suvorov, Ceramic and dielectric properties of selected compositions in the BaO-TiO2-Nd2O3 system. Ber. Dt. Keram. Ges. 55, 346–347 (1978)
9.
Zurück zum Zitat S. Nishigaki, H. Kato, S. Yano, R. Kamimura, Microwave dielectric properties of (Ba,Sr)O–Sm2O3–TiO2 ceramics. J. Am. Ceram. Soc. Bull. 66, 1405–1410 (1987) S. Nishigaki, H. Kato, S. Yano, R. Kamimura, Microwave dielectric properties of (Ba,Sr)O–Sm2O3–TiO2 ceramics. J. Am. Ceram. Soc. Bull. 66, 1405–1410 (1987)
10.
Zurück zum Zitat H. Ohsato, M. Mizuta, T. Ikoma, Z. Onogi, S. Nishigaki, T. Okuda, Microwave dielectric properties of tungsten bronzetype Ba6–3xR8+2xTi18O54 (R = La, Pr, Nd and Sm) solid solutions. J. Ceram. Soc. Jpn. 106(2), 178–182 (1998)CrossRef H. Ohsato, M. Mizuta, T. Ikoma, Z. Onogi, S. Nishigaki, T. Okuda, Microwave dielectric properties of tungsten bronzetype Ba6–3xR8+2xTi18O54 (R = La, Pr, Nd and Sm) solid solutions. J. Ceram. Soc. Jpn. 106(2), 178–182 (1998)CrossRef
11.
Zurück zum Zitat J. Takahashi, T. Ikegami, K. Kageyama, Occurrence of dielectric 1:1:4 compound in the ternary system BaO–Ln2O3–TiO2 (Ln = La, Nd, and Sm):II.Reexamination of formation of isostructural ternary compounds in identical systems. J. Am. Ceram. Soc. 74(8), 1873–1879 (1991)CrossRef J. Takahashi, T. Ikegami, K. Kageyama, Occurrence of dielectric 1:1:4 compound in the ternary system BaO–Ln2O3–TiO2 (Ln = La, Nd, and Sm):II.Reexamination of formation of isostructural ternary compounds in identical systems. J. Am. Ceram. Soc. 74(8), 1873–1879 (1991)CrossRef
12.
Zurück zum Zitat H. Okudera, M. Nakamura, H. Toraya, H. Ohsato, Tungsten bronze-type solid solutions Ba6–3xR8+2xTi18O54 (x = 0. 3, 0.5,0. 67, 0.71) with superstructure. J. Solid State Chem. 142, 336–343 (1999)CrossRef H. Okudera, M. Nakamura, H. Toraya, H. Ohsato, Tungsten bronze-type solid solutions Ba6–3xR8+2xTi18O54 (x = 0. 3, 0.5,0. 67, 0.71) with superstructure. J. Solid State Chem. 142, 336–343 (1999)CrossRef
13.
Zurück zum Zitat H. Ohsato, H. Kato, M. Mizuta, S. Nishigaki, T. Okuda, Microwave dielectric properties of the Ba6–3x(Sm1–yRy)8+2xTi18O54 (R = Nd, La) solid solutions with zero temperature coefficient of the resonant frequency. Jpn. J. Appl. Phys. 34, 5413–5417 (1995)CrossRef H. Ohsato, H. Kato, M. Mizuta, S. Nishigaki, T. Okuda, Microwave dielectric properties of the Ba6–3x(Sm1–yRy)8+2xTi18O54 (R = Nd, La) solid solutions with zero temperature coefficient of the resonant frequency. Jpn. J. Appl. Phys. 34, 5413–5417 (1995)CrossRef
14.
Zurück zum Zitat H. Ohsato, T. Ohhashi, S. Nishigaki, T. Okuda, K. Sumiya, S. Suzuki, Formation of solid solution of new tungsten bronze-type microwave dielectric compounds Ba6–3xR8+2xTi18O54 (R = Nd and Sm, 0 ≤ x ≤ 1). J. Appl. Phys. 32, 4323–4326 (1993)CrossRef H. Ohsato, T. Ohhashi, S. Nishigaki, T. Okuda, K. Sumiya, S. Suzuki, Formation of solid solution of new tungsten bronze-type microwave dielectric compounds Ba6–3xR8+2xTi18O54 (R = Nd and Sm, 0 ≤ x ≤ 1). J. Appl. Phys. 32, 4323–4326 (1993)CrossRef
15.
Zurück zum Zitat R. Ubic, I.M. Reaney, W.E. Lee, Microwave dielectric solid-solution phase in system BaO-Ln2O3-TiO2(Ln = Lanthanide caution). Int. Mater. Rev. 43, 205–219 (1998)CrossRef R. Ubic, I.M. Reaney, W.E. Lee, Microwave dielectric solid-solution phase in system BaO-Ln2O3-TiO2(Ln = Lanthanide caution). Int. Mater. Rev. 43, 205–219 (1998)CrossRef
16.
Zurück zum Zitat M. Imaeda, K. Ito, M. Mizuta, H. Ohsato, S. Nishigaki, T. Okuda, Microwave dielectric properties of Ba6–3xSm 8+2 x Ti18O54 solid solutions with Sr substituted for Ba. Jpn. J. Appl. Phys. 36, 012 (1997)CrossRef M. Imaeda, K. Ito, M. Mizuta, H. Ohsato, S. Nishigaki, T. Okuda, Microwave dielectric properties of Ba6–3xSm 8+2 x Ti18O54 solid solutions with Sr substituted for Ba. Jpn. J. Appl. Phys. 36, 012 (1997)CrossRef
17.
Zurück zum Zitat I. Kagomiya, M. Suzuki, K. Kakimoto, H. Ohsato, Microwave dielectric properties of tungsten bronze type like (Ba1–αSrα)6–3xR8+2xTi18O54 (R = Sm, Nd) solid solutions. J. Eur. Ceram. Soc. 27, 3059–3062 (2007)CrossRef I. Kagomiya, M. Suzuki, K. Kakimoto, H. Ohsato, Microwave dielectric properties of tungsten bronze type like (Ba1–αSrα)6–3xR8+2xTi18O54 (R = Sm, Nd) solid solutions. J. Eur. Ceram. Soc. 27, 3059–3062 (2007)CrossRef
18.
Zurück zum Zitat R. Lowndes, F. Azough, R. Cernik, R. Freer, Structures and microwave dielectric properties of Ca(1–x)Nd2x/3TiO3 ceramics. J. Eur. Ceram. Soc. 32(14), 3791–3799 (2012)CrossRef R. Lowndes, F. Azough, R. Cernik, R. Freer, Structures and microwave dielectric properties of Ca(1–x)Nd2x/3TiO3 ceramics. J. Eur. Ceram. Soc. 32(14), 3791–3799 (2012)CrossRef
19.
Zurück zum Zitat W.Q. Luo, Z.Y. Shen, Y.M. Li, Z.M. Wang, R.H. Liao, X.Y. Gu, Structural characterizations, dielectric properties and impedance spectroscopy analysis of NdxSr1–1.5xTiO3 ceramics. J. Electroceram. 31(1–2), 117–123 (2013) W.Q. Luo, Z.Y. Shen, Y.M. Li, Z.M. Wang, R.H. Liao, X.Y. Gu, Structural characterizations, dielectric properties and impedance spectroscopy analysis of NdxSr1–1.5xTiO3 ceramics. J. Electroceram. 31(1–2), 117–123 (2013)
20.
Zurück zum Zitat R.D. Shannon, Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta. Crystallogr. Section A. 32(5), 751–767 (1976) R.D. Shannon, Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta. Crystallogr. Section A. 32(5), 751–767 (1976)
21.
Zurück zum Zitat R.D. Shannon, Dielectric polarizabilities of ions in oxides and fluorides. J. Appl. Phy. 73(1), 348–366 (1993) R.D. Shannon, Dielectric polarizabilities of ions in oxides and fluorides. J. Appl. Phy. 73(1), 348–366 (1993)
22.
Zurück zum Zitat M. Suzuki, H. Ohsato, K. Kakimoto, T. Nagatomo, T. Otagiri, Crystal structure and microwave dielectric properties of (Ba1−αSrα)6−3xSm8+2xTi18O54 solid solutions. J. Eur. Ceram. Soc. 26(10), 2035–2038 (2006) M. Suzuki, H. Ohsato, K. Kakimoto, T. Nagatomo, T. Otagiri, Crystal structure and microwave dielectric properties of (Ba1−αSrα)6−3xSm8+2xTi18O54 solid solutions. J. Eur. Ceram. Soc. 26(10), 2035–2038 (2006)
Metadaten
Titel
Effects of CaO additives on the structure and properties of Ba6−3xSm8+2xTi18O54 (x = 0.5) ceramics
verfasst von
Xu Wang
Juhua Luo
Hao Guan
Yue Xu
Publikationsdatum
06.04.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 14/2017
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-017-6802-0

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