Skip to main content
main-content

Tipp

Weitere Artikel dieser Ausgabe durch Wischen aufrufen

05.03.2018 | Composites | Ausgabe 12/2018

Journal of Materials Science 12/2018

Effects of POSS functionalization of carbon nanotubes on microstructure and thermomechanical behavior of carbon nanotube/polymer nanocomposites

Zeitschrift:
Journal of Materials Science > Ausgabe 12/2018
Autoren:
Seyed Morteza Sabet, Hassan Mahfuz, Andrew C. Terentis, Majid Nezakat, Javad Hashemi

Abstract

Surface modification of carbon nanotubes (CNTs) is a promising method to control the properties of a CNT/polymer system. Recent research has been directed toward chemical attachment of polyhedral oligomeric silsesquioxane (POSS) moieties to the CNT surface. POSS modification of CNTs can affect both the quality of CNT dispersion in the matrix and the interactions between polymer chains and nanotubes at the interphase region. The goal of the current study is to investigate these effects. Accordingly, nanocomposites containing POSS-modified CNTs, unmodified CNTs, and POSS were fabricated by infusion of 0.25, 0.5, and 1.0 wt% particles into a vinyl ester (VE) resin. Mechanical and thermal properties of experimental materials were evaluated using three-point bending, differential scanning calorimetry, and thermogravimetric analysis methods. The state of particle distribution/dispersion in VE matrix was also observed. Optical microscopic studies showed that both POSS/VE and CNT/VE nanocomposites possess local agglomeration. This was more extensive in CNT/VE system. However, CNT-POSS/VE systems showed a fine-textured microstructure with homogeneous distribution of CNT-POSS hybrids into VE resin. This indicates that the dispersibility of CNTs improved due to POSS functionalization. Scanning electron microscopy (SEM) of fracture surfaces revealed apparent de-bonding of agglomerates from the matrix in both POSS/VE and CNT/VE system, which is in agreement with the observed drop in their fracture strain. On the other hand, SEM studies of nanocomposites containing POSS-modified nanotubes revealed formation of a 3D network of well-dispersed CNT-POSS hybrids. SEM analysis further indicated the occurrence of a fracture mechanism with enhanced interactions between individual CNTs and VE matrix. This stiff and flexible network of individual CNTs is responsible for enhancement in elastic modulus, glass transition, and thermal decomposition temperatures of CNT-POSS/VE nanocomposites.

Bitte loggen Sie sich ein, um Zugang zu diesem Inhalt zu erhalten

Sie möchten Zugang zu diesem Inhalt erhalten? Dann informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 69.000 Bücher
  • über 500 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Umwelt
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Testen Sie jetzt 30 Tage kostenlos.

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 50.000 Bücher
  • über 380 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Umwelt
  • Maschinenbau + Werkstoffe




Testen Sie jetzt 30 Tage kostenlos.

Literatur
Über diesen Artikel

Weitere Artikel der Ausgabe 12/2018

Journal of Materials Science 12/2018 Zur Ausgabe

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Bildnachweise