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Journal of Materials Science
Erschienen in: Journal of Materials Science 19/2019

25.06.2019 | Energy materials

Effects of precursor composition on morphology and microstructure of hybrid organic–inorganic perovskite solar cells

verfasst von: Chung-Hsin Lu, Guan-Rong Chen, Mei-Tsan Kuo

Erschienen in: Journal of Materials Science | Ausgabe 19/2019

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Abstract

The effects of compositions on the crystalline structures, microstructures and optical characteristics of perovskite CH3NH3PbI3 films were investigated via varying the molar ratios of CH3NH3I (MAI) to PbI2 in the precursor solutions. As the amounts of MAI were increased in the precursor solution, the formation of CH3NH3PbI3 was facilitated, and the grain sizes as well as absorbance of the resulting films were increased. The enlarged grain of the prepared films effectively suppressed the carrier recombination at grain boundary and improved the electrical performance of the fabricated solar cells. The analysis of diode parameters also revealed that the additional shunt path was suppressed. On the other hand, once the molar ratio of MAI to PbI2 was further increased, the roughness of film surface was increased and caused the carrier recombination between absorber layers and hole-transport layers, thereby resulting in a dramatic decrease in conversion efficiency. This investigation indicated that controlling the compositions in the precursors of CH3NH3PbI3 films is crucial to improve the photovoltaic properties of perovskite solar cells.
Vorheriger Artikel A facile synthesis of nitrogen-doped hierarchical porous carbon with hollow sphere structure for high-performance supercapacitors
Nächster Artikel Synthesis of uniform silica nanospheres wrapped in nitrogen-doped carbon nanosheets with stable lithium-ion storage properties

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Metadaten
Titel
Effects of precursor composition on morphology and microstructure of hybrid organic–inorganic perovskite solar cells
verfasst von
Chung-Hsin Lu
Guan-Rong Chen
Mei-Tsan Kuo
Publikationsdatum
25.06.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 19/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-03766-4

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