Skip to main content
Erschienen in: Interceram - International Ceramic Review 6/2018

01.10.2018 | Research and Development

Effects of TiO2 on the Microstructure of Synthesized Elongated Mullite

verfasst von: Xiangong Deng, Yongwan Wu, Tingting Wei, Peng Guo, Songlin Ran, Lei Han, Chuangang Fan, Prof. Dr. Haijun Zhang

Erschienen in: Interceram - International Ceramic Review | Ausgabe 6/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Elongated mullite was synthesized via an in situ solid-phase reaction using α-Al2O3 and SiO2 as the raw materials and TiO2 as an additive, and characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM). On the basis of thermodynamic analysis of the reaction process, the effects of TiO2 content and reaction temperature on the phase composition, phase contents, and microstructure of the synthesized samples were investigated. The results showed that elongated mullite with a length of about 8.0 μm was formed for the sample with 7 mass-% TiO2 at 1873 K. The dosage of TiO2 exceeded its solid solubility limit in mullite which resulted in the anisotropic growth of mullite grains.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Interceram - International Ceramic Review

Interceram - Das internationale Fachmagazin für das gesamte Gebiet der keramischen sowie thematisch verwandter Technologien. Jetzt kostenlos testen!

Literatur
[1]
Zurück zum Zitat Zeng, D.J., Zhang, H.H., Yang, J.F., Wang, B., Zhang, X.L.: Microstructure and property of porous mullites with a whiskers framework obtained by a sol-gel process. Ceram. Int. 42 (2016) 11270–11274CrossRef Zeng, D.J., Zhang, H.H., Yang, J.F., Wang, B., Zhang, X.L.: Microstructure and property of porous mullites with a whiskers framework obtained by a sol-gel process. Ceram. Int. 42 (2016) 11270–11274CrossRef
[2]
Zurück zum Zitat Zhang, H.H., Zhang, Y.M., Wang, B., Yang, J.F: Preparation and characterization of continuous alumina based fiber reinforced with orientated mullite whisker. Chem. Eng. J. 268 (2015) 109–115CrossRef Zhang, H.H., Zhang, Y.M., Wang, B., Yang, J.F: Preparation and characterization of continuous alumina based fiber reinforced with orientated mullite whisker. Chem. Eng. J. 268 (2015) 109–115CrossRef
[3]
Zurück zum Zitat Yuan, L., Ma, B.Y., Zhu, Qiang, Zhang, X.D., Zhang, H., Yu, J.K.: Preparation and properties of mullite-bonded porous fibrous mullite ceramics by an epoxy resin gel-casting process. Ceram. Int. 43 (2017) 5478–5483CrossRef Yuan, L., Ma, B.Y., Zhu, Qiang, Zhang, X.D., Zhang, H., Yu, J.K.: Preparation and properties of mullite-bonded porous fibrous mullite ceramics by an epoxy resin gel-casting process. Ceram. Int. 43 (2017) 5478–5483CrossRef
[4]
Zurück zum Zitat Deng, X.G., Ran, S.L., Han, L., Zhang, H.J., Ge, S.T., Zhang, S.W.: Foam-gelcasting preparation of high-strength self-reinforced porous mullite ceramics. J. Eur. Ceram. Soc. 37 (2017) 4059–4066CrossRef Deng, X.G., Ran, S.L., Han, L., Zhang, H.J., Ge, S.T., Zhang, S.W.: Foam-gelcasting preparation of high-strength self-reinforced porous mullite ceramics. J. Eur. Ceram. Soc. 37 (2017) 4059–4066CrossRef
[5]
Zurück zum Zitat Deng, X.G., Wang, J.K., Zhang, H.J., Li, F.L., Zhao, W.G., Huang, Z., Zhang, S.W.: Synthesis and growth mechanism of mullite whiskers. J. Chin. Ceram. Soc. 44 (2016) 901–907 Deng, X.G., Wang, J.K., Zhang, H.J., Li, F.L., Zhao, W.G., Huang, Z., Zhang, S.W.: Synthesis and growth mechanism of mullite whiskers. J. Chin. Ceram. Soc. 44 (2016) 901–907
[6]
Zurück zum Zitat Wang, W., Zhou, C.J, Liu, G.W., Qiao, G.J.: Molten salt synthesis of mullite whiskers on the surface of SiC ceramics. J. Alloy. Compd. 582 (2014) 96–100CrossRef Wang, W., Zhou, C.J, Liu, G.W., Qiao, G.J.: Molten salt synthesis of mullite whiskers on the surface of SiC ceramics. J. Alloy. Compd. 582 (2014) 96–100CrossRef
[7]
Zurück zum Zitat Cao, L.Y., Liu, J.T., Huang, J.F., Zhou, L., Yong, X., Shen, X.T., Kong, L., Yao, C.Y.: Mullite whisker toughened mullite coating to enhance the thermal shock resistance of SiC pre-coated carbon/carbon composites. Ceram. Int. 43 (2017) 16512–16517CrossRef Cao, L.Y., Liu, J.T., Huang, J.F., Zhou, L., Yong, X., Shen, X.T., Kong, L., Yao, C.Y.: Mullite whisker toughened mullite coating to enhance the thermal shock resistance of SiC pre-coated carbon/carbon composites. Ceram. Int. 43 (2017) 16512–16517CrossRef
[8]
Zurück zum Zitat Ji, Z.J., Luo, W.Y., Zhou, K.K., Hou, S., Zhang, Q.F., Li, L.Y., Jin, H.Y.: Effects of the shapes and dimensions of mullite whisker on the friction and wear behaviors of resin-based friction materials. Wear 406 (2018) 118–125CrossRef Ji, Z.J., Luo, W.Y., Zhou, K.K., Hou, S., Zhang, Q.F., Li, L.Y., Jin, H.Y.: Effects of the shapes and dimensions of mullite whisker on the friction and wear behaviors of resin-based friction materials. Wear 406 (2018) 118–125CrossRef
[9]
Zurück zum Zitat Li, J.H., Ma, H.W., Huang, W.H.: Effect of V2O5 on the properties of mullite ceramics synthesized from high-aluminum fly ash and bauxite. J. Hazard. Mater. 166 (2009) 1535–1539CrossRef Li, J.H., Ma, H.W., Huang, W.H.: Effect of V2O5 on the properties of mullite ceramics synthesized from high-aluminum fly ash and bauxite. J. Hazard. Mater. 166 (2009) 1535–1539CrossRef
[10]
Zurück zum Zitat Roy, J., Bandyopadhyay, N., Das, S., Maitra, S.: Effect of CoO on the formation of mullite ceramics from diphasic Al2O3-SiO2 gel. J. Eng. Sci. Tech. Rev. 3 (2010) 136–141CrossRef Roy, J., Bandyopadhyay, N., Das, S., Maitra, S.: Effect of CoO on the formation of mullite ceramics from diphasic Al2O3-SiO2 gel. J. Eng. Sci. Tech. Rev. 3 (2010) 136–141CrossRef
[11]
Zurück zum Zitat Monteiro, R.R., Sabioni, A.C.S.: Preparation of mullite whiskers derived from topaz doped with rare earth oxides for applications in composite materials. Ceram. Int. 42 (2016) 49–55CrossRef Monteiro, R.R., Sabioni, A.C.S.: Preparation of mullite whiskers derived from topaz doped with rare earth oxides for applications in composite materials. Ceram. Int. 42 (2016) 49–55CrossRef
[12]
Zurück zum Zitat Li, J.F., Lin, H., Li, J.B., Wu, J.: Effects of different potassium salts on the formation of mullite as the only crystal phase in kaolinite. J. Eur. Ceram. Soc. 29 (2009) 2929–2936CrossRef Li, J.F., Lin, H., Li, J.B., Wu, J.: Effects of different potassium salts on the formation of mullite as the only crystal phase in kaolinite. J. Eur. Ceram. Soc. 29 (2009) 2929–2936CrossRef
[13]
Zurück zum Zitat Rashad, M., Balasubramanian, M.: Characteristics of porous mullite developed from clay and AlF3·3H2O. J. Eur. Ceram. Soc. 38 (2018) 3673–3680CrossRef Rashad, M., Balasubramanian, M.: Characteristics of porous mullite developed from clay and AlF3·3H2O. J. Eur. Ceram. Soc. 38 (2018) 3673–3680CrossRef
[14]
Zurück zum Zitat Deng, X.G., Wu, Y.W., Wei, T.T., Ran, S.L., Huang, L., Zhang, H.J., Li, F.L., Han, L., Ge, S.T., Zhang, S.W.: Preparation of elongated mullite self-reinforced porous ceramics. Ceram. Int. 44 (2018) 7500–7508CrossRef Deng, X.G., Wu, Y.W., Wei, T.T., Ran, S.L., Huang, L., Zhang, H.J., Li, F.L., Han, L., Ge, S.T., Zhang, S.W.: Preparation of elongated mullite self-reinforced porous ceramics. Ceram. Int. 44 (2018) 7500–7508CrossRef
[15]
Zurück zum Zitat Zhu, Z.W., Wei, Z.L., Shen, J.X., Zhu, L., Xu, L., Zhang, Y.F., Wang, S., Liu, T.: Fabrication and catalytic growth mechanism of mullite ceramic whiskers using molybdenum oxide as catalyst. Ceram. Int. 43 (2017) 2871–2875CrossRef Zhu, Z.W., Wei, Z.L., Shen, J.X., Zhu, L., Xu, L., Zhang, Y.F., Wang, S., Liu, T.: Fabrication and catalytic growth mechanism of mullite ceramic whiskers using molybdenum oxide as catalyst. Ceram. Int. 43 (2017) 2871–2875CrossRef
[16]
Zurück zum Zitat Ji, H.P., Fang, M.H., Huang, Z.H., Chen, K., Xu, Y.G., Liu, Y.G., Huang, J.T.: Effect of La2O3 additives on the strength and microstructure of mullite ceramics obtained from coal gangue and γ-Al2O3. Ceram. Int. 39 (2013) 6841–6846CrossRef Ji, H.P., Fang, M.H., Huang, Z.H., Chen, K., Xu, Y.G., Liu, Y.G., Huang, J.T.: Effect of La2O3 additives on the strength and microstructure of mullite ceramics obtained from coal gangue and γ-Al2O3. Ceram. Int. 39 (2013) 6841–6846CrossRef
[17]
Zurück zum Zitat Kong, L.B., Zhang, T.S., Ma, J., Boey, F.: Anisotropic grain growth of mullite in high-energy ball milled powders doped with transition metal oxides. J. Eur. Ceram. Soc. 23 (2003) 2247–2256CrossRef Kong, L.B., Zhang, T.S., Ma, J., Boey, F.: Anisotropic grain growth of mullite in high-energy ball milled powders doped with transition metal oxides. J. Eur. Ceram. Soc. 23 (2003) 2247–2256CrossRef
[18]
Zurück zum Zitat He, C.L., Li, Y.E.: Metallurgical furnace thermal basis. Beijing: Metallurgical Industrial Press, (1979) 297 He, C.L., Li, Y.E.: Metallurgical furnace thermal basis. Beijing: Metallurgical Industrial Press, (1979) 297
[19]
Zurück zum Zitat Baudin, C., Osendi, M.I., Moya, J.S.: Solid solution of TiO2 in mullite. J. Mater. Sci. Lett. 2 (1983) 185–187CrossRef Baudin, C., Osendi, M.I., Moya, J.S.: Solid solution of TiO2 in mullite. J. Mater. Sci. Lett. 2 (1983) 185–187CrossRef
[20]
Zurück zum Zitat Liang., Y., Yin, Y., Wu, Y., Wang, J.: Effect of TiO2 on the sinterability and microstructure of mullite synthesized from Al(OH)3 and SiO2. China’s Refractories 15 (2006) 3–6 Liang., Y., Yin, Y., Wu, Y., Wang, J.: Effect of TiO2 on the sinterability and microstructure of mullite synthesized from Al(OH)3 and SiO2. China’s Refractories 15 (2006) 3–6
[21]
Zurück zum Zitat Sola, E.R., Serrano, F.J., Delgado-Pinar, E., Reventós, M.M., Pardo, A.I., Kojdecki, M.A., Amigó, J.M., Alarcón, J.: Solubility and microstructural development of TiO2-containing 3Al2O3-2SiO2 and 2Al2O3-SiO2 mullites obtained from single-phase gels. J. Eur. Ceram. Soc. 27 (2007) 2647–2654CrossRef Sola, E.R., Serrano, F.J., Delgado-Pinar, E., Reventós, M.M., Pardo, A.I., Kojdecki, M.A., Amigó, J.M., Alarcón, J.: Solubility and microstructural development of TiO2-containing 3Al2O3-2SiO2 and 2Al2O3-SiO2 mullites obtained from single-phase gels. J. Eur. Ceram. Soc. 27 (2007) 2647–2654CrossRef
Metadaten
Titel
Effects of TiO2 on the Microstructure of Synthesized Elongated Mullite
verfasst von
Xiangong Deng
Yongwan Wu
Tingting Wei
Peng Guo
Songlin Ran
Lei Han
Chuangang Fan
Prof. Dr. Haijun Zhang
Publikationsdatum
01.10.2018
Verlag
Springer Fachmedien Wiesbaden
Erschienen in
Interceram - International Ceramic Review / Ausgabe 6/2018
Print ISSN: 0020-5214
Elektronische ISSN: 2523-8957
DOI
https://doi.org/10.1007/s42411-018-0051-y

Weitere Artikel der Ausgabe 6/2018

Interceram - International Ceramic Review 6/2018 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.