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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 2/2019

26.11.2018 | Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Efficient, highly stable Zn-doped NiO nanocluster electrocatalysts for electrochemical water splitting applications

verfasst von: B. Jansi Rani, G. Ravi, R. Yuvakkumar, S. Ravichandran, Fuad Ameen, A. Al-Sabri

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 2/2019

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Abstract

Solvothermal synthesis of pristine and Zn-doped NiO nanocluster electrocatalysts have been synthesized for efficient electrochemical water splitting applications. Cubic structure with lattice constant of 4.16 A° was revealed through XRD analysis. Presence of oxygen vacancy was confirmed by employing PL study. Nanosheets combined feather like nanocluster morphology was obtained for optimized electrocatalysts. Variation in optical absorption and energy band gap was observed for undoped and Zn-doped NiO electrocatalysts. Highest specific capacitance of 455.74 F/g at 5 mV/s scan rate was obtained for 10% Zn-doped NiO nanoclusters. Improved oxygen evolution was achieved for the same electrocatalysts by addressing the current density of 0.77 mA/g at 10 mV/s with lowest Tafel slope of 75 mV/decade. Higher conductivity with lower internal resistance (Rs) of 10.36 Ω was obtained for the above optimized electrocatalyst. Practically applicable stability over 12 h of 10% Zn-doped NiO nanocluster electrocatalyst was proposed for efficient electrochemical water splitting applications.
Vorheriger Artikel In situ synthesis of two-dimensional Co2+-doped β-Ni(OH)2 using nickel complex as template for application in supercapacitors
Nächster Artikel Template-free synthesis of NiO skeleton crystal octahedron and effect of surface depression on electrochemical performance

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Metadaten
Titel
Efficient, highly stable Zn-doped NiO nanocluster electrocatalysts for electrochemical water splitting applications
verfasst von
B. Jansi Rani
G. Ravi
R. Yuvakkumar
S. Ravichandran
Fuad Ameen
A. Al-Sabri
Publikationsdatum
26.11.2018
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 2/2019
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-018-4886-5

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