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Journal of Materials Science: Materials in Electronics

Erschienen in:

22.02.2017

Electrical and dielectric properties of polymer composite based on vanadium dioxide

verfasst von: V. R. Kolbunov, A. S. Tonkoshkur, I. V. Gomilko

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 11/2017

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Abstract

Samples of a polymer composite based on polypropylene and vanadium dioxide VO₂ with the volume concentration from 0 to 1 were investigated. It was shown that the electrical conductivity of composites has the percolation-like character, and the current–voltage characteristics are S-shaped. In the temperature dependence of the electrical resistance of the composites samples, a sharp resistance decrease was detected at the temperature of the semiconductor–metal phase transition in VO₂, sufficient for use in critical thermistor elements. It was established that the variance of the dielectric permittivity in the range of frequencies 10⁵−10⁷ Hz can be interpreted as part of the Maxwell’s mechanism of migration polarization associated with the separation of free charge carriers in vanadium dioxide particles in the semiconducting state. It was shown that the dependence of the low-frequency dielectric permittivity on the volume concentration of the filler can be interpreted in terms of a statistical mixture model.

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Titel: Electrical and dielectric properties of polymer composite based on vanadium dioxide
verfasst von: V. R. Kolbunov
A. S. Tonkoshkur
I. V. Gomilko
Publikationsdatum: 22.02.2017
Verlag: Springer US
Erschienen in: Journal of Materials Science: Materials in Electronics / Ausgabe 11/2017
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-017-6547-9

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