Skip to main content
Erschienen in: Journal of Coatings Technology and Research 1/2016

15.09.2015

Electrochemical investigation of the epoxy nanocomposites containing MnAl2O4 and CoAl2O4 nanopigments applied on the aluminum alloy 1050

verfasst von: E. Ghasemi, B. Ramezanzadeh, S. Saket, S. Ashhari

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 1/2016

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The MnAl2O4 and CoAl2O4 nanopigments were synthesized through solution combustion method. The nanopigments extracts in the 3.5 wt% NaCl solution were prepared. Electrochemical impedance spectroscopy (EIS) and linear polarization (LP) techniques were utilized to investigate the corrosion inhibition properties of the pigments in the solutions containing pigments extracts. The epoxy nanocomposites were prepared and applied on the aluminum specimens. EIS and pull-off measurements were performed to characterize the corrosion protection properties of the epoxy nanocomposites. It was revealed that the MnAl2O4 pigment showed higher corrosion inhibition properties than CoAl2O4 in the solution phase. In addition, MnAl2O4 enhanced the corrosion resistance and decreased the adhesion loss of the epoxy coating on the aluminum substrate significantly. The MnAl2O4 nanopigment improved the corrosion resistance of the epoxy coating through increasing the barrier performance and releasing inhibitive species.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Vargel, C, Corrosion of Aluminium. Elsevier, Boston, 2004 Vargel, C, Corrosion of Aluminium. Elsevier, Boston, 2004
2.
Zurück zum Zitat Koroleva, EV, Thompson, GE, Hollrigl, G, Bloeck, M, “Surface Morphological Changes of Aluminium Alloys in Alkaline Solution: Effect of Second Phase Material.” Corros. Sci., 41 1475–1495 (1991)CrossRef Koroleva, EV, Thompson, GE, Hollrigl, G, Bloeck, M, “Surface Morphological Changes of Aluminium Alloys in Alkaline Solution: Effect of Second Phase Material.” Corros. Sci., 41 1475–1495 (1991)CrossRef
3.
Zurück zum Zitat Dalmoro, V, dos Santos, JHZ, Armelin, E, Alemán, C, Azambuja, DS, “A Synergistic Combination of Tetraethylorthosilicate and Multiphosphonic Acid Offers Excellent Corrosion Protection to AA1100 Aluminum Alloy.” Appl. Surf. Sci., 273 758–768 (2013)CrossRef Dalmoro, V, dos Santos, JHZ, Armelin, E, Alemán, C, Azambuja, DS, “A Synergistic Combination of Tetraethylorthosilicate and Multiphosphonic Acid Offers Excellent Corrosion Protection to AA1100 Aluminum Alloy.” Appl. Surf. Sci., 273 758–768 (2013)CrossRef
4.
Zurück zum Zitat Witkowska, M, Thompson, GE, Hashimoto, T, Koroleva, E, “Assessment of the Surface Reactivity of AA1050 Aluminium Alloy.” Surf. Interface Anal., 45 1585–1589 (2013)CrossRef Witkowska, M, Thompson, GE, Hashimoto, T, Koroleva, E, “Assessment of the Surface Reactivity of AA1050 Aluminium Alloy.” Surf. Interface Anal., 45 1585–1589 (2013)CrossRef
5.
Zurück zum Zitat Ambat, R, Davenport, AJ, Scamans, GM, Afseth, A, “Effect of Iron-Containing Intermetallic Particles on the Corrosion Behaviour of Aluminium.” Corros. Sci., 48 3455–3471 (2006)CrossRef Ambat, R, Davenport, AJ, Scamans, GM, Afseth, A, “Effect of Iron-Containing Intermetallic Particles on the Corrosion Behaviour of Aluminium.” Corros. Sci., 48 3455–3471 (2006)CrossRef
6.
Zurück zum Zitat Allachi, H, Chaouket, F, Draoui, K, “Corrosion Inhibition of AA6060 Aluminium Alloy by Lanthanide Salts in Chloride Solution.” J. Alloys Compd., 475 300–303 (2009)CrossRef Allachi, H, Chaouket, F, Draoui, K, “Corrosion Inhibition of AA6060 Aluminium Alloy by Lanthanide Salts in Chloride Solution.” J. Alloys Compd., 475 300–303 (2009)CrossRef
7.
Zurück zum Zitat Allachi, H, Chaouket, F, Draoui, K, “Protection Against Corrosion in Marine Environments of AA6060 Aluminium Alloy by Cerium Chlorides.” J. Alloys Compd., 491 223–229 (2010)CrossRef Allachi, H, Chaouket, F, Draoui, K, “Protection Against Corrosion in Marine Environments of AA6060 Aluminium Alloy by Cerium Chlorides.” J. Alloys Compd., 491 223–229 (2010)CrossRef
8.
Zurück zum Zitat Sharifi Golru, S, Attar, MM, Ramezanzadeh, B, “Effects of Surface Treatment of Aluminium Alloy 1050 on the Adhesion and Anticorrosion Properties of the Epoxy Coating.” Appl. Surf. Sci., 345 360–368 (2015)CrossRef Sharifi Golru, S, Attar, MM, Ramezanzadeh, B, “Effects of Surface Treatment of Aluminium Alloy 1050 on the Adhesion and Anticorrosion Properties of the Epoxy Coating.” Appl. Surf. Sci., 345 360–368 (2015)CrossRef
9.
Zurück zum Zitat Stoffer, JO, O’Keefe, TJ, Sitaram, SP, Yu, P, Lin, X, Morris, E, Electrodeposition of Cerium Based Coatings for Corrosion Protection of Aluminum Alloys. US Patent 5,932,083, 3 1999 Stoffer, JO, O’Keefe, TJ, Sitaram, SP, Yu, P, Lin, X, Morris, E, Electrodeposition of Cerium Based Coatings for Corrosion Protection of Aluminum Alloys. US Patent 5,932,083, 3 1999
10.
Zurück zum Zitat Hayes, SA, Yu, P, O’Keefe, TJ, O’Keefe, MJ, Stoffer, JO, “The Phase Stability of Cerium Species in Aqueous Systems. I. E-pH Diagram for the Ce-HClO4-H2O System.” J. Electrochem. Soc., 149 (12) C623–C630 (2002)CrossRef Hayes, SA, Yu, P, O’Keefe, TJ, O’Keefe, MJ, Stoffer, JO, “The Phase Stability of Cerium Species in Aqueous Systems. I. E-pH Diagram for the Ce-HClO4-H2O System.” J. Electrochem. Soc., 149 (12) C623–C630 (2002)CrossRef
11.
Zurück zum Zitat Bierwagen, GP, “Reflections on Corrosion Control by Coatings.” Prog. Org. Coat., 28 42–48 (1996) Bierwagen, GP, “Reflections on Corrosion Control by Coatings.” Prog. Org. Coat., 28 42–48 (1996)
12.
Zurück zum Zitat Simoes, A, Battocchi, D, Tallman, D, Bierwagen, G, “Assessment of the Corrosion Protection of Aluminium Substrates by a Mg-rich Primer: EIS, SVET and SECM Study.” Prog. Org. Coat., 63 (3) 260–266 (2008)CrossRef Simoes, A, Battocchi, D, Tallman, D, Bierwagen, G, “Assessment of the Corrosion Protection of Aluminium Substrates by a Mg-rich Primer: EIS, SVET and SECM Study.” Prog. Org. Coat., 63 (3) 260–266 (2008)CrossRef
13.
Zurück zum Zitat Bierwagen, G, Battocchi, D, Simoes, A, Stamness, A, Tallman, D, “The Use of Multiple Electrochemical Techniques to Characterize Mg-rich Primers for Al Alloys.” Prog. Org. Coat., 59 172–178 (2007)CrossRef Bierwagen, G, Battocchi, D, Simoes, A, Stamness, A, Tallman, D, “The Use of Multiple Electrochemical Techniques to Characterize Mg-rich Primers for Al Alloys.” Prog. Org. Coat., 59 172–178 (2007)CrossRef
14.
Zurück zum Zitat Sinko, J, “Challenges of Chromate Inhibitor Pigments Replacement in Organic Coatings.” Prog. Org. Coat., 42 267–282 (2001)CrossRef Sinko, J, “Challenges of Chromate Inhibitor Pigments Replacement in Organic Coatings.” Prog. Org. Coat., 42 267–282 (2001)CrossRef
15.
Zurück zum Zitat Twite, RL, Bierwagen, P, “Review of Alternatives to Chromate for Corrosion Protection of Aluminum Aerospace Alloys.” Prog. Org. Coat., 33 91–100 (1998)CrossRef Twite, RL, Bierwagen, P, “Review of Alternatives to Chromate for Corrosion Protection of Aluminum Aerospace Alloys.” Prog. Org. Coat., 33 91–100 (1998)CrossRef
16.
Zurück zum Zitat Heydarpour, MR, Zarrabi, A, Attar, MM, Ramezanzadeh, B, “Studying the Corrosion Protection Properties of an Epoxy Coating Containing Different Mixtures of Strontium Aluminum Polyphosphate (SAPP) and Zinc Aluminum Phosphate (ZPA) Pigments.” Prog. Org. Coat., 77 160–167 (2014)CrossRef Heydarpour, MR, Zarrabi, A, Attar, MM, Ramezanzadeh, B, “Studying the Corrosion Protection Properties of an Epoxy Coating Containing Different Mixtures of Strontium Aluminum Polyphosphate (SAPP) and Zinc Aluminum Phosphate (ZPA) Pigments.” Prog. Org. Coat., 77 160–167 (2014)CrossRef
17.
Zurück zum Zitat Naderi, R, Arman, SY, Fouladvand, SH, “Investigation on the Inhibition Synergism of New Generations of Phosphate-Based Anticorrosion Pigments.” Dye Pigm., 105 23–33 (2014)CrossRef Naderi, R, Arman, SY, Fouladvand, SH, “Investigation on the Inhibition Synergism of New Generations of Phosphate-Based Anticorrosion Pigments.” Dye Pigm., 105 23–33 (2014)CrossRef
18.
Zurück zum Zitat Askari, F, Ghasemi, E, Ramezanzadeh, B, Mahdavian, M, “Mechanistic Approach for Evaluation of the Corrosion Inhibition of Potassium Zinc Phosphate Pigment on the Steel Surface: Application of Surface Analysis and Electrochemical Techniques.” Dye Pigm., (2014). doi:10.1016/j.dyepig.2014.05.024 Askari, F, Ghasemi, E, Ramezanzadeh, B, Mahdavian, M, “Mechanistic Approach for Evaluation of the Corrosion Inhibition of Potassium Zinc Phosphate Pigment on the Steel Surface: Application of Surface Analysis and Electrochemical Techniques.” Dye Pigm., (2014). doi:10.​1016/​j.​dyepig.​2014.​05.​024
19.
Zurück zum Zitat Sitaram, SP, Stoffer, JO, O’Keefe, TJ, “Application of Conducting Polymers in Corrosion Protection.” J. Coat. Technol., 69 65–69 (1997)CrossRef Sitaram, SP, Stoffer, JO, O’Keefe, TJ, “Application of Conducting Polymers in Corrosion Protection.” J. Coat. Technol., 69 65–69 (1997)CrossRef
20.
Zurück zum Zitat O’Keefe, MJ, Fahrenholtz, WG, Stoffer, JO, Morris, EL, “Corrosion-Resistant Polymer Coatings Containing Rare Earth Compounds.” Rare Earth-Based Corros. Inhib., 175e–182e 163–174 (2014)CrossRef O’Keefe, MJ, Fahrenholtz, WG, Stoffer, JO, Morris, EL, “Corrosion-Resistant Polymer Coatings Containing Rare Earth Compounds.” Rare Earth-Based Corros. Inhib., 175e–182e 163–174 (2014)CrossRef
21.
Zurück zum Zitat Joshi, S, Kulp, EA, Fahrenholtz, WG, O’Keefe, MJ, “Dissolution of Cerium from Cerium-Based Conversion Coatings on Al 7075-T6 in 0.1 M NaCl Solutions.” Corros. Sci., 60 290–295 (2012)CrossRef Joshi, S, Kulp, EA, Fahrenholtz, WG, O’Keefe, MJ, “Dissolution of Cerium from Cerium-Based Conversion Coatings on Al 7075-T6 in 0.1 M NaCl Solutions.” Corros. Sci., 60 290–295 (2012)CrossRef
22.
Zurück zum Zitat Hernandez, M, Genesca, J, “Effect of an Inhibitive Pigment Zinc-Aluminum-Phosphate (ZAP) on the Corrosion Mechanisms of Steel in Waterborne Coatings.” Prog. Org. Coat., 56 199–206 (2006)CrossRef Hernandez, M, Genesca, J, “Effect of an Inhibitive Pigment Zinc-Aluminum-Phosphate (ZAP) on the Corrosion Mechanisms of Steel in Waterborne Coatings.” Prog. Org. Coat., 56 199–206 (2006)CrossRef
23.
Zurück zum Zitat Naderi, R, Mahdavian, M, Attar, MM, “Electrochemical Behavior of Organic and Inorganic Complexes of Zn(II) as Corrosion Inhibitors for Mild Steel: Solution Phase Study.” Electrochim. Acta., 54 6892–6895 (2009)CrossRef Naderi, R, Mahdavian, M, Attar, MM, “Electrochemical Behavior of Organic and Inorganic Complexes of Zn(II) as Corrosion Inhibitors for Mild Steel: Solution Phase Study.” Electrochim. Acta., 54 6892–6895 (2009)CrossRef
24.
Zurück zum Zitat Kalendová, A, “Alkalising and Neutralising Effects of Anticorrosive Pigments Containing Zn, Mg, Ca, and Sr Cations.” Prog. Org. Coat., 38 199–206 (2000)CrossRef Kalendová, A, “Alkalising and Neutralising Effects of Anticorrosive Pigments Containing Zn, Mg, Ca, and Sr Cations.” Prog. Org. Coat., 38 199–206 (2000)CrossRef
25.
Zurück zum Zitat Palimi, MJ, Peymannia, M, Ramezanzadeh, B, “An Evaluation of the Anticorrosion Properties of the Spinel Nanopigment-Filled Epoxy Composite Coatings Applied on the Steel Surface.” Prog. Org. Coat., 80 164–175 (2015)CrossRef Palimi, MJ, Peymannia, M, Ramezanzadeh, B, “An Evaluation of the Anticorrosion Properties of the Spinel Nanopigment-Filled Epoxy Composite Coatings Applied on the Steel Surface.” Prog. Org. Coat., 80 164–175 (2015)CrossRef
26.
Zurück zum Zitat Kalendová, A, Šňupárek, J, Kalenda, P, “Nontoxic Anticorrosion Pigments of the Spinel Type Compared with Condensed Phosphates.” Dye Pigm., 30 (2) 129–140 (1996)CrossRef Kalendová, A, Šňupárek, J, Kalenda, P, “Nontoxic Anticorrosion Pigments of the Spinel Type Compared with Condensed Phosphates.” Dye Pigm., 30 (2) 129–140 (1996)CrossRef
27.
Zurück zum Zitat Kalendová, A, Brodinová, J, “Spinel and Rutile Pigments Containing Mg, Ca, Zn and Other Cations for Anticorrosive Coatings.” Anti-Corrosion Methods Mater., 50 (5) 352–363 (2003)CrossRef Kalendová, A, Brodinová, J, “Spinel and Rutile Pigments Containing Mg, Ca, Zn and Other Cations for Anticorrosive Coatings.” Anti-Corrosion Methods Mater., 50 (5) 352–363 (2003)CrossRef
28.
Zurück zum Zitat Rasouli, S, Jebeli Moeen, S, “Combustion Synthesis of Co-doped Zinc Oxide Nanoparticles using Mixture of Citric Acid–Glycine Fuels.” J. Alloys Compd., 509 1915–1919 (2011)CrossRef Rasouli, S, Jebeli Moeen, S, “Combustion Synthesis of Co-doped Zinc Oxide Nanoparticles using Mixture of Citric Acid–Glycine Fuels.” J. Alloys Compd., 509 1915–1919 (2011)CrossRef
29.
Zurück zum Zitat Palimi, MJ, Rostami, M, Mahdavian, M, Ramezanzadeh, B, “A Study on the Corrosion Inhibition Properties of Silane-Modified Fe2O3 Nanoparticle on Mild Steel and Its Effect on the Anticorrosion Properties of the Polyurethane Coating.” J. Coat. Technol. Res., 12 (2) 277–292 (2015)CrossRef Palimi, MJ, Rostami, M, Mahdavian, M, Ramezanzadeh, B, “A Study on the Corrosion Inhibition Properties of Silane-Modified Fe2O3 Nanoparticle on Mild Steel and Its Effect on the Anticorrosion Properties of the Polyurethane Coating.” J. Coat. Technol. Res., 12 (2) 277–292 (2015)CrossRef
30.
Zurück zum Zitat Tallman, DE, Levine, KL, Siripirom, C, Gelling, VG, Bierwagen, GP, Croll, SG, “Nanocomposite of Polypyrrole and Alumina Nanoparticles as a Coating Filler for the Corrosion Protection of Aluminium Alloy 2024-T3.” Appl. Surf. Sci., 254 (17) 5452–5459 (2008)CrossRef Tallman, DE, Levine, KL, Siripirom, C, Gelling, VG, Bierwagen, GP, Croll, SG, “Nanocomposite of Polypyrrole and Alumina Nanoparticles as a Coating Filler for the Corrosion Protection of Aluminium Alloy 2024-T3.” Appl. Surf. Sci., 254 (17) 5452–5459 (2008)CrossRef
31.
Zurück zum Zitat Sharifi Golru, S, Attar, MM, Ramezanzadeh, B, “Studying the Influence of Nano-Al2O3 Particles on the Corrosion Performance and Hydrolytic Degradation Resistance of Anepoxy/Polyamide Coating on AA-1050.” Prog. Org. Coat., 77 1391–1399 (2014)CrossRef Sharifi Golru, S, Attar, MM, Ramezanzadeh, B, “Studying the Influence of Nano-Al2O3 Particles on the Corrosion Performance and Hydrolytic Degradation Resistance of Anepoxy/Polyamide Coating on AA-1050.” Prog. Org. Coat., 77 1391–1399 (2014)CrossRef
32.
Zurück zum Zitat Gama, L, Ribeiro, MA, Barros, BS, Kiminami, RHA, Weber, IT, Costa, ACFM, “Synthesis and Characterization of the NiAl2O4, CoAl2O4 and ZnAl2O4 Spinels by the Polymeric Precursors Method.” J. Alloys Compd., 483 (1–2) 453–455 (2009)CrossRef Gama, L, Ribeiro, MA, Barros, BS, Kiminami, RHA, Weber, IT, Costa, ACFM, “Synthesis and Characterization of the NiAl2O4, CoAl2O4 and ZnAl2O4 Spinels by the Polymeric Precursors Method.” J. Alloys Compd., 483 (1–2) 453–455 (2009)CrossRef
33.
Zurück zum Zitat Duan, X, Pan, M, Yu, F, Yuan, D, “Synthesis, Structure and Optical Properties of CoAl2O4 Spinel Nanocrystals.” J. Alloys Compd., 509 (3) 1079–1083 (2011)CrossRef Duan, X, Pan, M, Yu, F, Yuan, D, “Synthesis, Structure and Optical Properties of CoAl2O4 Spinel Nanocrystals.” J. Alloys Compd., 509 (3) 1079–1083 (2011)CrossRef
34.
Zurück zum Zitat Motamedi, M, Tehrani-Bagha, AR, Mahdavian, M, “A Comparative Study on the Electrochemical Behavior of Mild Steel in Sulfamic Acid Solution in the Presence of Monomeric and Gemini Surfactants.” Electrochim. Acta., 58 488–496 (2011)CrossRef Motamedi, M, Tehrani-Bagha, AR, Mahdavian, M, “A Comparative Study on the Electrochemical Behavior of Mild Steel in Sulfamic Acid Solution in the Presence of Monomeric and Gemini Surfactants.” Electrochim. Acta., 58 488–496 (2011)CrossRef
35.
Zurück zum Zitat Mahdavian, M, Ashhari, S, “Corrosion Inhibition Performance of 2- mercaptobenzimidazole and 2-mercaptobenzoxazole Compounds for Protection of Mild Steel in Hydrochloric Acid Solution.” Electrochim. Acta, 55 1720–1724 (2010)CrossRef Mahdavian, M, Ashhari, S, “Corrosion Inhibition Performance of 2- mercaptobenzimidazole and 2-mercaptobenzoxazole Compounds for Protection of Mild Steel in Hydrochloric Acid Solution.” Electrochim. Acta, 55 1720–1724 (2010)CrossRef
36.
Zurück zum Zitat Liu, X, Xiong, J, Lv, Y, Zuo, Y, “Study on Corrosion Electrochemical Behavior of Several Different Coating Systems by EIS.” Prog. Org. Coat., 64 497–503 (2009)CrossRef Liu, X, Xiong, J, Lv, Y, Zuo, Y, “Study on Corrosion Electrochemical Behavior of Several Different Coating Systems by EIS.” Prog. Org. Coat., 64 497–503 (2009)CrossRef
Metadaten
Titel
Electrochemical investigation of the epoxy nanocomposites containing MnAl2O4 and CoAl2O4 nanopigments applied on the aluminum alloy 1050
verfasst von
E. Ghasemi
B. Ramezanzadeh
S. Saket
S. Ashhari
Publikationsdatum
15.09.2015
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 1/2016
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-015-9728-6

Weitere Artikel der Ausgabe 1/2016

Journal of Coatings Technology and Research 1/2016 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.