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2019 | OriginalPaper | Buchkapitel

5. Electrochemical Measurements as Screening Method for Water Oxidation Catalyst

verfasst von : Carminna Ottone, Simelys Hernández, Marco Armandi, Barbara Bonelli

Erschienen in: Testing Novel Water Oxidation Catalysts for Solar Fuels Production

Verlag: Springer International Publishing

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Abstract

In actual water splitting devices, the WOC will be deposited on an anode surface. Therefore, whatever the results obtained with WOC particles suspended in stirrer tank reactors, it becomes necessary to study WOC performances by means of electrochemical experimental setups. The WOCs deposition on an anode will depend on their physico-chemical nature, therefore several deposition methods, including wet and dry approaches, are found in literature. This Chapter reviews the available electrochemical techniques that can be adopted to study WOCs that are deposited on an electrode. In addition, the parameters used in literature to compare the different WOC materials will be explained. At the end of the Chapter, an example of the performance of different MnO_x films will be reported. The water oxidation activity of three MnO_x crystalline phases prepared by two deposition techniques will be compared. The aim of the comparison is to determine whether two electrodes having the same crystalline phase behave differently or not when they are deposited by two different techniques.

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Vorheriges Kapitel Use of the Bubbling Reactor with the Photosystem for Measuring the Rate of Water Oxidation as Promoted by Different Manganese Oxides

Nächstes Kapitel Scaling Up the Process of Photo-Electrochemical Water Splitting

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Titel: Electrochemical Measurements as Screening Method for Water Oxidation Catalyst
verfasst von: Carminna Ottone
Simelys Hernández
Marco Armandi
Barbara Bonelli
Verlag: Springer International Publishing
Buch: Testing Novel Water Oxidation Catalysts for Solar Fuels Production
Print ISBN: 978-3-030-12711-4

Electronic ISBN: 978-3-030-12712-1

Copyright-Jahr: 2019
DOI: https://doi.org/10.1007/978-3-030-12712-1_5