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Erschienen in: Journal of Materials Science 11/2017

10.02.2017 | Original Paper

Electrochemical study of NiO nanosheets: toward the understanding of capacity fading

verfasst von: Jan Kaspar, Mahdi Seifollahi Bazarjani, Cristina Schitco, Aleksander Gurlo, Magdalena Graczyk-Zajac, Ralf Riedel

Erschienen in: Journal of Materials Science | Ausgabe 11/2017

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Abstract

NiO nanosheets are prepared by calcination of nickel hydroxide nanosheets, obtained by the hydrolysis of trans-bis(acetato-κO)bis(2-aminoethanol-κ2 N,O)nickel(II) complex. BET analysis reveals the presence of a high specific surface area of 48 m2g−1 and a pore volume of 0.26 cm3g−1 after calcination at 400 °C. The two-dimensional NiO nanostructure undergoes a reversible lithium ion uptake and release revealing an initial unexpectedly high capacity of ~1100 mAhg−1 at a cycling current of 400 mAg−1, exceeding the theoretical capacity of NiO (718 mAhg−1). We attribute this high storage capacity to the advantageous two-dimensional morphology of the sample, namely to the presence of agglomerates composed of NiO nanosheets, allowing a pronounced Li-ion storage through the insertion mechanism and by the formation of a polymer-like layer at the samples internal surfaces. However, after 20 cycles the recovered capacity diminishes rapidly due to the onset of Li-ion intercalation into NiO, which is found less reversible. In addition, an increase in the charge transfer resistance and increase in the electrode polarization, measured by differential capacity, contribute to the analyzed capacity decay upon continuous cycling.

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Metadaten
Titel
Electrochemical study of NiO nanosheets: toward the understanding of capacity fading
verfasst von
Jan Kaspar
Mahdi Seifollahi Bazarjani
Cristina Schitco
Aleksander Gurlo
Magdalena Graczyk-Zajac
Ralf Riedel
Publikationsdatum
10.02.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 11/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-0885-0

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