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Journal of Materials Engineering and Performance

Erschienen in:

11.09.2015

Electrolytic Synthesis and Characterization of Electrocatalytic Ni-W Alloy

verfasst von: Liju Elias, Keith Scott, A. Chitharanjan Hegde

Erschienen in: Journal of Materials Engineering and Performance | Ausgabe 11/2015

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Abstract

Inspired by the more positive (about 0.38 V nobler) discharge potential of hydrogen on Ni-W alloy compared to that on both Ni and W, a Ni-W alloy has been developed electrolytically as an efficient electrode material for water electrolysis. The deposition conditions, for peak performance of the electrodeposits for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in 1.0 M KOH medium have been optimized. Electrocatalytic activity of the coatings, deposited at different current densities (c.d.’s) for water splitting reactions of HER and OER was tested by cyclic voltammetry and chronopotentiometry. It was found that Ni-W alloys deposited, at 4.0 A/dm² (having about 12.49 wt.% W) and 1.0 A/dm² (having about 0.95 wt.% W) are good electrode materials as cathode (for HER) and anode (for OER), respectively. A dependency of the electrocatalytic activity for HER and OER with relative amount of Ni and W, in the deposit was found. The variation of electrocatalytic activity with W content showed the existence of a synergism between high-catalytic property of W (due to low hydrogen overvoltage) and Ni (having increased adsorption of OH⁻ ions), for hydrogen (as cathode) and oxygen (as anode) evolution, respectively. Electrocatalytic activities of the coatings, developed at different c.d.’s were explained in the light of their phase structure, surface morphology, and chemical composition, confirmed by XRD, FESEM, and EDX analysis. The effect of c.d. on thickness, hardness, composition, HER, and OER was analyzed, and results were discussed with possible mechanisms.

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G. Lu and G. Zangari, Study of the Electroless Deposition Process of Ni-P-Based Ternary Alloys, J. Electrochem. Soc., 2003, 150(11), p C777–C786CrossRef

H. Hosokawa, T. Yamasaki, N. Sugamoto, M. Tomizawa, K. Shimojima, and M. Mabuchi, Bending Properties of Nanocrystalline Ni-18 at.% W Alloy Produced by Electrodeposition, Mater. Trans., 2004, 45(5), p 1807–1810CrossRef

T.M. Sridhar, N. Eliaz, and E. Gileadi, Electroplating of Ni4W, Electrochem. Solid State Lett., 2005, 8(3), p C58–C61CrossRef

A. Brenner, Electrodeposition of Alloys: Principles and Practice, Academic Press, New York, 1963

N. Eliaz and E. Gileadi, Induced Codeposition of Alloys of Tungsten, Molybdenum and Rhenium with Transition Metals, Modern Aspects of Electrochemistry, C.G. Vayenas, R.E. White, and M.E. Gamboa-Aldeco, Ed., Springer, New York, 2008, p 191–301 CrossRef

N.V. Krstajić, V.D. Jović, L. Gajić-Krstajić, B.M. Jović, A.L. Antozzi, and G.N. Martelli, Electrodeposition of Ni-Mo Alloy Coatings and Their Characterization as Cathodes for Hydrogen Evolution in Sodium Hydroxide Solution, Int. J. Hydrogen Energy, 2008, 33(14), p 3676–3687CrossRef

J.R. McKone, E.L. Warren, M.J. Bierman, S.W. Boettcher, B.S. Brunschwig, N.S. Lewis, and H.B. Gray, Evaluation of Pt, Ni, and Ni-Mo Electrocatalysts for Hydrogen Evolution on Crystalline Si Electrodes, Energy Environ. Sci., 2011, 4(9), p 3573–3583CrossRef

H. Ataee-Esfahani, L. Wang, Y. Nemoto, and Y. Yamauchi, Synthesis of Bimetallic Au@ Pt Nanoparticles with Au Core and Nanostructured Pt Shell Toward Highly Active Electrocatalysts, Chem. Mater., 2010, 22(23), p 6310–6318CrossRef

H. Wang, S. Ishihara, K. Ariga, and Y. Yamauchi, All-Metal Layer-by-Layer Films: Bimetallic Alternate Layers with Accessible Mesopores for Enhanced Electrocatalysis, J. Am. Chem. Soc., 2012, 134(26), p 10819–10821CrossRef

10.

T.-L. Wee, B.D. Sherman, D. Gust, A.L. Moore, T.A. Moore, Y. Liu, and J.C. Scaiano, Photochemical Synthesis of a Water Oxidation Catalyst Based on Cobalt Nanostructures, J. Am. Chem. Soc., 2011, 133(42), p 16742–16745CrossRef

11.

I.J. Godwin and M.E.G. Lyons, Enhanced Oxygen Evolution at Hydrous Nickel Oxide Electrodes via Electrochemical Ageing in Alkaline Solution, Electrochem. Commun., 2013, 32, p 39–42CrossRef

12.

M. Gong, Y. Li, H. Wang, Y. Liang, J.Z. Wu, J. Zhou, J. Wang, T. Regier, F. Wei, and H. Dai, An Advanced Ni-Fe Layered Double Hydroxide Electrocatalyst for Water Oxidation, J. Am. Chem. Soc., 2013, 135(23), p 8452–8455CrossRef

13.

T. Takashima, K. Hashimoto, and R. Nakamura, Inhibition of Charge Disproportionation of MnO₂ Electrocatalysts for Efficient Water Oxidation Under Neutral Conditions, J. Am. Chem. Soc., 2012, 134(44), p 18153–18156CrossRef

14.

X. Li, F.C. Walsh, and D. Pletcher, Nickel Based Electrocatalysts for Oxygen Evolution in High Current Density, Alkaline Water Electrolysers, PCCP, 2011, 13(3), p 1162–1167CrossRef

15.

R.D. Smith, M.S. Prévot, R.D. Fagan, S. Trudel, and C.P. Berlinguette, Water Oxidation Catalysis: Electrocatalytic Response to Metal Stoichiometry in Amorphous Metal Oxide Films Containing Iron, Cobalt, and Nickel, J. Am. Chem. Soc., 2013, 135(31), p 11580–11586CrossRef

16.

S. Nagalingam, G.B. Teh, R.-F. Louh, and K.T. Chee, Cyclic Voltammetry Studies of Cadmium Zinc Sulfide Aqueous Solution, Int. J. Phys. Sci., 2011, 6(31), p 7166–7170

17.

L. Zhu, O. Younes, N. Ashkenasy, Y. Shacham-Diamand, and E. Gileadi, STM/AFM Studies of the Evolution of Morphology of Electroplated Ni/W Alloys, Appl. Surf. Sci., 2002, 200(1–4), p 1–14CrossRef

18.

Y. Ullal and A.C. Hegde, Electrodeposition and Electro-catalytic Study of Nanocrystalline Ni-Fe Alloy, Int. J. Hydrogen Energy, 2014, 39(20), p 10485–10492CrossRef

19.

N. Parthasaradhy, Practical Electroplating Handbook (Retroactive Coverage), Prentice-Hall, Inc., Upper Saddle River, 1996, p 1444–1989

20.

M. Bratoeva and N. Atanasov, Effect of Sulfamate-Citrate Electrolyte pH on the Ni-W Alloy Electrodeposition, Russ. J. Electrochem., 2000, 36(1), p 60–63CrossRef

21.

Z.S. Ma, Y.C. Zhou, S.G. Long, and C. Lu, On the Intrinsic Hardness of a Metallic Film/Substrate System: Indentation Size and Substrate Effects, Int. J. Plast, 2012, 34, p 1–11CrossRef

22.

Z. Ma, S. Long, Y. Pan, and Y. Zhou, Indentation Depth Dependence of the Mechanical Strength of Ni Films, J. Appl. Phys., 2008, 103(4), p 043512CrossRef

23.

M. Zemanová, R. Kurinec, V. Jorík, and M. Kadlečíová, Ni-W Alloy Coatings Deposited from a Citrate Electrolyte, Chem. Pap., 2012, 66(5), p 492–501CrossRef

24.

I. Herraiz-Cardona, E. Ortega, J.G. Antón, and V. Pérez-Herranz, Assessment of the Roughness Factor Effect and the Intrinsic Catalytic Activity for Hydrogen Evolution Reaction on Ni-Based Electrodeposits, Int. J. Hydrogen Energy, 2011, 36(16), p 9428–9438CrossRef

25.

A. Kellenberger, N. Vaszilcsin, W. Brandl, and N. Duteanu, Kinetics of Hydrogen Evolution Reaction on Skeleton Nickel and Nickel-Titanium Electrodes Obtained by Thermal arc Spraying Technique, Int. J. Hydrogen Energy, 2007, 32(15), p 3258–3265CrossRef

26.

F. Rosalbino, D. Maccio, E. Angelini, A. Saccone, and S. Delfino, Electrocatalytic Properties of Fe-R (R = Rare Earth Metal) Crystalline Alloys as Hydrogen Electrodes in Alkaline Water Electrolysis, J. Alloys Compd., 2005, 403(1), p 275–282CrossRef

27.

E. Navarro-Flores, Z. Chong, and S. Omanovic, Characterization of Ni, NiMo, NiW and NiFe Electroactive Coatings as Electrocatalysts for Hydrogen Evolution in an Acidic Medium, J. Mol. Catal. A, 2005, 226(2), p 179–197CrossRef

28.

C. Lupi, A. Dell’Era, and M. Pasquali, Nickel-Cobalt Electrodeposited Alloys for Hydrogen Evolution in Alkaline Media, Int. J. Hydrogen Energy, 2009, 34(5), p 2101–2106CrossRef

29.

M.E. Lyons, The Oxygen Evolution Reaction on Passive Oxide Covered Transition Metal Electrodes in Aqueous Alkaline Solution. Part 1—Nickel, Int. J. Electrochem. Sci., 2008, 3, p 1386–1424

30.

K. Jüttner, Oxygen reduction Electrocatalysis by Underpotential Deposited Metal Atoms at Different Single Crystal Faces of Gold and Silver, Electrochim. Acta, 1984, 29(11), p 1597–1604CrossRef

31.

P. Peeters, G.V.D. Hoorn, T. Daenen, A. Kurowski, and G. Staikov, Properties of Electroless and Electroplated Ni-P and Its Application in Microgalvanics, Electrochim. Acta, 2001, 47(1), p 161–169CrossRef

32.

J. Kubisztal and A. Budniok, Study of the Oxygen Evolution Reaction on Nickel-Based Composite Coatings in Alkaline Media, Int. J. Hydrogen Energy, 2008, 33(17), p 4488–4494CrossRef

Titel: Electrolytic Synthesis and Characterization of Electrocatalytic Ni-W Alloy
verfasst von: Liju Elias
Keith Scott
A. Chitharanjan Hegde
Publikationsdatum: 11.09.2015
Verlag: Springer US
Erschienen in: Journal of Materials Engineering and Performance / Ausgabe 11/2015
Print ISSN: 1059-9495
Elektronische ISSN: 1544-1024
DOI: https://doi.org/10.1007/s11665-015-1710-z

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