Emergence of Ferromagnetic State Due to Structural Disorder in Pseudo-binary Ce(Fe0.9Co0.1)2 Compound

The changes in magnetic properties of Ce(Fe_0.9Co_0.1)₂ compound with increasing disorder are discussed in the paper. Homogeneous alloys are known to undergo the phase transition from ferromagnetic to antiferromagnetic state accompanied by the structural distortion of the cubic Laves C15 phase into the rhombohedral one. Various stimuli, like the structural disorder, or applied magnetic field, can force the emergence of ferromagnetism at low temperatures. We initially introduced the structural disorder using rapid quenching. Further changes were made by severe plastic deformation. The presence of a ferromagnetic phase in a low-temperature region is reported here and accompanies the deterioration of a first-order phase transition. We show, based on electronic calculations, that the structural motifs arising from various distortions of the initial MgCu₂-type structure, caused by the partial replacement of Fe with Co atoms, are characterized by stable antiferromagnetic order. This neglects simple structural distortions as the source of ferromagnetism. The presence of a strongly defective structure understood as a topologically disordered volume reduced the fraction transformed from a ferromagnetic to an antiferromagnetic state. Therefore, a strong reduction of isothermal entropy changes was also observed, as it decreased from 1.94 and − 1.43 J kg⁻¹ K⁻¹ (Δμ₀H = 4 T) to 0.30 and − 0.96 J kg⁻¹ K⁻¹ for antiferromagnetic–ferromagnetic and ferromagnetic–paramagnetic transition, respectively.