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Cellulose
Published in: Cellulose 1/2014

01-02-2014 | Original Paper

A morphological interpretation of water chemical exchange and mobility in cellulose materials derived from proton NMR T2 relaxation

Authors: Roger Ibbett, Franz Wortmann, Ksenija Varga, K. Christian Schuster

Published in: Cellulose | Issue 1/2014

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Abstract

Proton T2 relaxation times of water in cellulosic fibres have been interpreted using a 3-term average model. Motional and chemical exchange contributions to relaxation show opposing temperature behaviour, enabling the use of Arrhenius analysis to determine proton exchange rates and water rotational correlation times. Both parameters vary dramatically with extent of hydration, with chemical exchange dominating relaxation at saturated water contents. Interpretations are based on a morphological model with two types of accessible cellulose, at void surfaces and internally within the cellulose phase. In native cellulose fibres, the presence of crystalline fibrils with low internal accessibility leads to rapid proton exchange at low moisture contents. Regenerated cellulose fibres typically have lower crystallinity and higher internal accessibility, which results in slower exchange as result of migration of water between void and internal environments. Exchange behaviour in regenerated fibres is highly dependent on structural organisation, which depends on the manufacturing process.
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Metadata
Title
A morphological interpretation of water chemical exchange and mobility in cellulose materials derived from proton NMR T2 relaxation
Authors
Roger Ibbett
Franz Wortmann
Ksenija Varga
K. Christian Schuster
Publication date
01-02-2014
Publisher
Springer Netherlands
Published in
Cellulose / Issue 1/2014
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-013-0106-1

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