Skip to main content
Top
Published in: Cellulose 2/2018

12-01-2018 | Communication

A new bio-material with 3D lightweight network for energy and advanced applications

Authors: Dan Belosinschi, Bogdan-Marian Tofanica

Published in: Cellulose | Issue 2/2018

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

A novel approach to modifying native cellulosic fibers by phosphorylation, glycerol grafting and further cross-linking by citric acid had been successfully investigated. The conductivity of the resulting cellulose-based material was measured to be 3 × 10−3 S cm−1, approximately 105 times as large as that in the initial fibers, while the volumetric mass density was 0.40 ± 0.03 g cm−3, similar with wood and wood products. These special properties and the capability to assemble these modified fibers into a paper sheet-like structure without altering the fiber morphology would boost the application of this new bio-based material, including its potential use as a conductive polymer for energy devices.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literature
go back to reference Demitri C, Del Sole R, Scalera F, Sannino A, Vasapollo G, Maffezzoli A, Ambrosio L, Nicolais L (2008) Novel superabsorbent cellulose-based hydrogels crosslinked with citric acid. J Appl Polym Sci 110:2453–2460CrossRef Demitri C, Del Sole R, Scalera F, Sannino A, Vasapollo G, Maffezzoli A, Ambrosio L, Nicolais L (2008) Novel superabsorbent cellulose-based hydrogels crosslinked with citric acid. J Appl Polym Sci 110:2453–2460CrossRef
go back to reference Farris S, Mora L, Capretti G, Piergiovanni L (2011) Charge density quantification of polyelectrolyte polysaccharides by conductometric titration: an analytical chemistry experiment. J Chem Educ 89:121–124CrossRef Farris S, Mora L, Capretti G, Piergiovanni L (2011) Charge density quantification of polyelectrolyte polysaccharides by conductometric titration: an analytical chemistry experiment. J Chem Educ 89:121–124CrossRef
go back to reference Ganster J, Fink H-P (2003) Physical constants of cellulose. In: Brandrup J, Immergut EH, Grulke EA (eds) Polymer handbook. Wiley, New York, pp V/135–V/157 Ganster J, Fink H-P (2003) Physical constants of cellulose. In: Brandrup J, Immergut EH, Grulke EA (eds) Polymer handbook. Wiley, New York, pp V/135–V/157
go back to reference Jabbour L, Bongiovanni R, Chaussy D, Gerbaldi C, Beneventi D (2013) Cellulose-based Li-ion batteries: a review. Cellulose 20:1523–1545CrossRef Jabbour L, Bongiovanni R, Chaussy D, Gerbaldi C, Beneventi D (2013) Cellulose-based Li-ion batteries: a review. Cellulose 20:1523–1545CrossRef
go back to reference Kazemi F, Massah AR, Javaherian M (2007) Chemoselective and scalable preparation of alkyl tosylates under solvent-free conditions. Tetrahedron 63:5083–5087CrossRef Kazemi F, Massah AR, Javaherian M (2007) Chemoselective and scalable preparation of alkyl tosylates under solvent-free conditions. Tetrahedron 63:5083–5087CrossRef
go back to reference Nourry G, Belosinschi D, Boutin MP, Brouillette F, Zerrouki R (2016) Hydrophobization of phorylated cellulosic fibers. Cellulose 23:3511–3520CrossRef Nourry G, Belosinschi D, Boutin MP, Brouillette F, Zerrouki R (2016) Hydrophobization of phorylated cellulosic fibers. Cellulose 23:3511–3520CrossRef
go back to reference Shi Y, Belosinschi D, Brouillette F, Belfkira A, Chabot B (2014) Phosphorylation of Kraft fibers with phosphate esters. Carbohydr Polym 106:121–127CrossRef Shi Y, Belosinschi D, Brouillette F, Belfkira A, Chabot B (2014) Phosphorylation of Kraft fibers with phosphate esters. Carbohydr Polym 106:121–127CrossRef
go back to reference Shi Y, Belosinschi D, Brouillette F, Belfkira A, Chabot B (2015) The properties of phosphorylated kraft fibers. BioResources 10:4375–4390 Shi Y, Belosinschi D, Brouillette F, Belfkira A, Chabot B (2015) The properties of phosphorylated kraft fibers. BioResources 10:4375–4390
go back to reference Tracy DJ, Reierson RL (2002) Commercial synthesis of monoalkyl phosphates. J Surfactants Deterg 5:169–172CrossRef Tracy DJ, Reierson RL (2002) Commercial synthesis of monoalkyl phosphates. J Surfactants Deterg 5:169–172CrossRef
Metadata
Title
A new bio-material with 3D lightweight network for energy and advanced applications
Authors
Dan Belosinschi
Bogdan-Marian Tofanica
Publication date
12-01-2018
Publisher
Springer Netherlands
Published in
Cellulose / Issue 2/2018
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-018-1652-3

Other articles of this Issue 2/2018

Cellulose 2/2018 Go to the issue