Skip to main content
Top
Published in: Journal of Materials Science 16/2017

26-04-2017 | Chemical routes to materials

A new soft template-oriented method for the preparation of hollow analcime microspheres with nanosheets-assembled shells

Authors: Pengyu Gong, Baoshan Li, Xianglong Kong, Ning Wang, Jianjun Liu, Shengli Zuo

Published in: Journal of Materials Science | Issue 16/2017

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

This paper highlights a controlled synthesis of two-dimensional analcime nanosheets templated by organic additives and an impressive strategy that hollow hierarchical analcime microspheres with layered shells can be assembled by taking advantage of the intrinsic growth law of material. Specifically, ultrathin analcime nanosheets were initially obtained by precisely manipulating the amounts of cetyltrimethylammonium cation (CTA+) and ethylenediaminetetraacetate (EDTA4−) in the synthesis system. As building blocks, these nanosheets then self-assembled layer by layer from outside to inside driven by the reversed crystal growth mechanism of analcime, resulting in a hollow structure with lamellar shells and enhanced specific surface area of 722.3 m2 g−1. Series of experiments were carried out in order to explore the influence of CTA+ and EDTA4− on the formation of analcime nanosheets. The results indicated that CTA+ was the micro-mesoporogen of hierarchical analcime and synergistically collaborated with EDTA4− in directing analcime nanosheets. The effect of hydrothermal temperature was discussed and a surfactant packing parameter (g = V/a 0 l) was cited to explain the behavior of organics. In addition, the investigation of hydrothermal process clearly revealed the crystallization and self-assembly process of hollow structure. And the UV Raman results unraveled that four-membered rings (4MRs) as the active building units for analcime framework were firstly formed in the synthesis gel, followed by reconstruction and self-assembly which lead to the formation of 6MRs and 8MRs.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Appendix
Available only for authorised users
Literature
1.
go back to reference Shi Y, Zhang B (2016) Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction. Chem Soc Rev 45:1529–1541CrossRef Shi Y, Zhang B (2016) Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction. Chem Soc Rev 45:1529–1541CrossRef
2.
go back to reference Li X, Zhu J, Wei B (2016) Hybrid nanostructures of metal/two-dimensional nanomaterials for plasmon-enhanced applications. Chem Soc Rev 45:3145–3187CrossRef Li X, Zhu J, Wei B (2016) Hybrid nanostructures of metal/two-dimensional nanomaterials for plasmon-enhanced applications. Chem Soc Rev 45:3145–3187CrossRef
3.
go back to reference Ariga K, Ji Q, Hill JP, Bando Y, Aono M (2012) Forming nanomaterials as layered functional structures toward materials nanoarchitectonics. NPG Asia Mater 4:e17CrossRef Ariga K, Ji Q, Hill JP, Bando Y, Aono M (2012) Forming nanomaterials as layered functional structures toward materials nanoarchitectonics. NPG Asia Mater 4:e17CrossRef
4.
5.
go back to reference Hu Y, Wei J, Liang Y, Zhang H, Zhang X, Shen W, Wang H (2016) Zeolitic imidazolate framework/graphene oxide hybrid nanosheets as seeds for the growth of ultrathin molecular sieving membranes. Angew Chem 55:2048–2052CrossRef Hu Y, Wei J, Liang Y, Zhang H, Zhang X, Shen W, Wang H (2016) Zeolitic imidazolate framework/graphene oxide hybrid nanosheets as seeds for the growth of ultrathin molecular sieving membranes. Angew Chem 55:2048–2052CrossRef
6.
go back to reference Liu P, Zhao Y, Qin R, Mo S, Chen G, Gu L, Chevrier DM, Zhang P, Guo Q, Zang D, Wu B, Fu G, Zheng N (2016) Photochemical route for synthesizing atomically dispersed palladium catalysts. Science 352:797–801CrossRef Liu P, Zhao Y, Qin R, Mo S, Chen G, Gu L, Chevrier DM, Zhang P, Guo Q, Zang D, Wu B, Fu G, Zheng N (2016) Photochemical route for synthesizing atomically dispersed palladium catalysts. Science 352:797–801CrossRef
7.
go back to reference Zhang K, Ostraat ML (2016) Innovations in hierarchical zeolite synthesis. Catal Today 264:3–15CrossRef Zhang K, Ostraat ML (2016) Innovations in hierarchical zeolite synthesis. Catal Today 264:3–15CrossRef
8.
go back to reference Corma A, Fornes V, Pergher SB, Maesen TLM, Buglass JG (1998) Delaminated zeolite precursors as selective acidic catalysts. Nature 396:353–356CrossRef Corma A, Fornes V, Pergher SB, Maesen TLM, Buglass JG (1998) Delaminated zeolite precursors as selective acidic catalysts. Nature 396:353–356CrossRef
9.
go back to reference Xu W-Q, Yin Y-G, Suib SL, Edwards JC, O’Young C-L (1996) Modification of non-template synthesized ferrierite/ZSM-35 forn-Butene skeletal isomerization to isobutylene. J Catal 163:232–244CrossRef Xu W-Q, Yin Y-G, Suib SL, Edwards JC, O’Young C-L (1996) Modification of non-template synthesized ferrierite/ZSM-35 forn-Butene skeletal isomerization to isobutylene. J Catal 163:232–244CrossRef
10.
go back to reference Zanardi S, Alberti A, Cruciani G, Corma A, Fornés V, Brunelli M (2004) Crystal structure determination of zeolite Nu-6(2) and its layered precursor Nu-6(1). Angew Chem 116:5041–5045CrossRef Zanardi S, Alberti A, Cruciani G, Corma A, Fornés V, Brunelli M (2004) Crystal structure determination of zeolite Nu-6(2) and its layered precursor Nu-6(1). Angew Chem 116:5041–5045CrossRef
11.
go back to reference Roth WJ, Nachtigall P, Morris RE, Wheatley PS, Seymour VR, Ashbrook SE, Chlubná P, Grajciar L, Položij M, Zukal A, Shvets O, Čejka J (2013) A family of zeolites with controlled pore size prepared using a top-down method. Nat Chem 5:628–633CrossRef Roth WJ, Nachtigall P, Morris RE, Wheatley PS, Seymour VR, Ashbrook SE, Chlubná P, Grajciar L, Položij M, Zukal A, Shvets O, Čejka J (2013) A family of zeolites with controlled pore size prepared using a top-down method. Nat Chem 5:628–633CrossRef
12.
go back to reference Choi M, Na K, Kim J, Sakamoto Y, Terasaki O, Ryoo R (2009) Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts. Nature 461:246–249CrossRef Choi M, Na K, Kim J, Sakamoto Y, Terasaki O, Ryoo R (2009) Stable single-unit-cell nanosheets of zeolite MFI as active and long-lived catalysts. Nature 461:246–249CrossRef
13.
go back to reference Park W, Yu D, Na K, Jelfs KE, Slater B, Sakamoto Y, Ryoo R (2011) Hierarchically structure-directing effect of multi-ammonium surfactants for the generation of MFI zeolite nanosheets. Chem Mater 23:5131–5137CrossRef Park W, Yu D, Na K, Jelfs KE, Slater B, Sakamoto Y, Ryoo R (2011) Hierarchically structure-directing effect of multi-ammonium surfactants for the generation of MFI zeolite nanosheets. Chem Mater 23:5131–5137CrossRef
14.
go back to reference Teng Z, Wang S, Su X, Chen G, Liu Y, Luo Z, Luo W, Tang Y, Ju H, Zhao D, Lu G (2014) Facile synthesis of yolk-shell structured inorganic-organic hybrid spheres with ordered radial mesochannels. Adv Mater 26:3741–3747CrossRef Teng Z, Wang S, Su X, Chen G, Liu Y, Luo Z, Luo W, Tang Y, Ju H, Zhao D, Lu G (2014) Facile synthesis of yolk-shell structured inorganic-organic hybrid spheres with ordered radial mesochannels. Adv Mater 26:3741–3747CrossRef
15.
go back to reference Yang P, Gai S, Lin J (2012) Functionalized mesoporous silica materials for controlled drug delivery. Chem Soc Rev 41:3679–3698CrossRef Yang P, Gai S, Lin J (2012) Functionalized mesoporous silica materials for controlled drug delivery. Chem Soc Rev 41:3679–3698CrossRef
16.
go back to reference Jin D, Park K-W, Lee JH, Song K, Kim J-G, Seo ML, Jung JH (2011) The selective immobilization of curcumin onto the internal surface of mesoporous hollow silica particles by covalent bonding and its controlled release. J Mater Chem 21:3641CrossRef Jin D, Park K-W, Lee JH, Song K, Kim J-G, Seo ML, Jung JH (2011) The selective immobilization of curcumin onto the internal surface of mesoporous hollow silica particles by covalent bonding and its controlled release. J Mater Chem 21:3641CrossRef
17.
go back to reference Teng Z, Zheng G, Dou Y, Li W, Mou CY, Zhang X, Asiri AM, Zhao D (2012) Highly ordered mesoporous silica films with perpendicular mesochannels by a simple Stober-solution growth approach. Angew Chem 51:2173–2177CrossRef Teng Z, Zheng G, Dou Y, Li W, Mou CY, Zhang X, Asiri AM, Zhao D (2012) Highly ordered mesoporous silica films with perpendicular mesochannels by a simple Stober-solution growth approach. Angew Chem 51:2173–2177CrossRef
18.
go back to reference Dong F, Guo W, Park S-S, Ha C-S (2011) Uniform and monodisperse polysilsesquioxane hollow spheres: synthesis from aqueous solution and use in pollutant removal. J Mater Chem 21:10744CrossRef Dong F, Guo W, Park S-S, Ha C-S (2011) Uniform and monodisperse polysilsesquioxane hollow spheres: synthesis from aqueous solution and use in pollutant removal. J Mater Chem 21:10744CrossRef
19.
go back to reference Chen M, Wu L, Zhou S, You B (2006) A method for the fabrication of monodisperse hollow silica spheres. Adv Mater 18:801–806CrossRef Chen M, Wu L, Zhou S, You B (2006) A method for the fabrication of monodisperse hollow silica spheres. Adv Mater 18:801–806CrossRef
20.
go back to reference Yang W, Li B (2014) A novel liquid template corrosion approach for layered silica with various morphologies and different nanolayer thicknesses. Nanoscale 6:2292–2298CrossRef Yang W, Li B (2014) A novel liquid template corrosion approach for layered silica with various morphologies and different nanolayer thicknesses. Nanoscale 6:2292–2298CrossRef
21.
go back to reference Yang W, Li B (2013) Facile fabrication of hollow silica nanospheres and their hierarchical self-assemblies as drug delivery carriers through a new single-micelle-template approach. J Mater Chem B 1:2525CrossRef Yang W, Li B (2013) Facile fabrication of hollow silica nanospheres and their hierarchical self-assemblies as drug delivery carriers through a new single-micelle-template approach. J Mater Chem B 1:2525CrossRef
22.
go back to reference Wang Y, Tang C, Deng Q, Liang C, Ng DH, Kwong FL, Wang H, Cai W, Zhang L, Wang G (2010) A versatile method for controlled synthesis of porous hollow spheres. Langmuir 26:14830–14834CrossRef Wang Y, Tang C, Deng Q, Liang C, Ng DH, Kwong FL, Wang H, Cai W, Zhang L, Wang G (2010) A versatile method for controlled synthesis of porous hollow spheres. Langmuir 26:14830–14834CrossRef
23.
go back to reference Cho W, Lee YH, Lee HJ, Oh M (2011) Metal oxide particles: multi ball-in-ball hybrid metal oxides. Adv Mater 23:1687CrossRef Cho W, Lee YH, Lee HJ, Oh M (2011) Metal oxide particles: multi ball-in-ball hybrid metal oxides. Adv Mater 23:1687CrossRef
24.
go back to reference Ndoni S, Vigild ME, Berg RH (2003) Nanoporous materials with spherical and gyroid cavities created by quantitative etching of polydimethylsiloxane in polystyrene-polydimethylsiloxane block copolymers. J Am Chem Soc 125:13366–13367CrossRef Ndoni S, Vigild ME, Berg RH (2003) Nanoporous materials with spherical and gyroid cavities created by quantitative etching of polydimethylsiloxane in polystyrene-polydimethylsiloxane block copolymers. J Am Chem Soc 125:13366–13367CrossRef
25.
go back to reference Li W, Deng Y, Wu Z, Qian X, Yang J, Wang Y, Gu D, Zhang F, Tu B, Zhao D (2011) Hydrothermal etching assisted crystallization: a facile route to functional yolk–shell titanate microspheres with ultrathin nanosheets-assembled double shells. J Am Chem Soc 133:15830–15833CrossRef Li W, Deng Y, Wu Z, Qian X, Yang J, Wang Y, Gu D, Zhang F, Tu B, Zhao D (2011) Hydrothermal etching assisted crystallization: a facile route to functional yolk–shell titanate microspheres with ultrathin nanosheets-assembled double shells. J Am Chem Soc 133:15830–15833CrossRef
26.
go back to reference Teng Z, Su X, Zheng Y, Zhang J, Liu Y, Wang S, Wu J, Chen G, Wang J, Zhao D, Lu G (2015) A facile multi-interface transformation approach to monodisperse multiple-shelled periodic mesoporous organosilica hollow spheres. J Am Chem Soc 137:7935–7944CrossRef Teng Z, Su X, Zheng Y, Zhang J, Liu Y, Wang S, Wu J, Chen G, Wang J, Zhao D, Lu G (2015) A facile multi-interface transformation approach to monodisperse multiple-shelled periodic mesoporous organosilica hollow spheres. J Am Chem Soc 137:7935–7944CrossRef
27.
go back to reference Chen H, Liu X, Ma X (2015) Confined synthesis of silicalite-1 hollow spheres with a lamellar shell. Scr Mater 95:31–34CrossRef Chen H, Liu X, Ma X (2015) Confined synthesis of silicalite-1 hollow spheres with a lamellar shell. Scr Mater 95:31–34CrossRef
28.
go back to reference Wiersema GS, Thompson RW (1996) Nucleation and crystal growth of analcime from clear aluminosilicate solutions. J Mater Chem 6:1693CrossRef Wiersema GS, Thompson RW (1996) Nucleation and crystal growth of analcime from clear aluminosilicate solutions. J Mater Chem 6:1693CrossRef
29.
go back to reference Liu BS, Tang DC, Au CT (2005) Fabrication of analcime zeolite fibers by hydrothermal synthesis. Microporous Mesoporous Mater 86:106–111CrossRef Liu BS, Tang DC, Au CT (2005) Fabrication of analcime zeolite fibers by hydrothermal synthesis. Microporous Mesoporous Mater 86:106–111CrossRef
30.
go back to reference Shamspur T, Sheikhshoaie I, Mashhadizadeh MH (2005) Flame atomic absorption spectroscopy (FAAS) determination of iron(III) after preconcentration on to modified analcime zeolite with 5-((4-nitrophenylazo)-N-(2′,4′-dimethoxyphenyl))salicylaldimine by column method. J Anal At Spectrom 20:476–478CrossRef Shamspur T, Sheikhshoaie I, Mashhadizadeh MH (2005) Flame atomic absorption spectroscopy (FAAS) determination of iron(III) after preconcentration on to modified analcime zeolite with 5-((4-nitrophenylazo)-N-(2′,4′-dimethoxyphenyl))salicylaldimine by column method. J Anal At Spectrom 20:476–478CrossRef
31.
go back to reference Chen Qiao, Xie Fan, Zhou He (2007) Self-construction of core−shell and hollow zeolite analcime icositetrahedra: a reversed crystal growth process via oriented aggregation of nanocrystallites and recrystallization from surface to core. J Am Chem Soc 129:13305–13312CrossRef Chen Qiao, Xie Fan, Zhou He (2007) Self-construction of core−shell and hollow zeolite analcime icositetrahedra: a reversed crystal growth process via oriented aggregation of nanocrystallites and recrystallization from surface to core. J Am Chem Soc 129:13305–13312CrossRef
32.
go back to reference Naser Azizi S, Yousefpour M (2009) Synthesis of aluminum-rich analcime using an ethylene diamine derivative as template. Z anorg allg Chem 635:1654–1658CrossRef Naser Azizi S, Yousefpour M (2009) Synthesis of aluminum-rich analcime using an ethylene diamine derivative as template. Z anorg allg Chem 635:1654–1658CrossRef
33.
34.
go back to reference Atta AY, Jibril BY, Aderemi BO, Adefila SS (2012) Preparation of analcime from local kaolin and rice husk ash. Appl Clay Sci 61:8–13CrossRef Atta AY, Jibril BY, Aderemi BO, Adefila SS (2012) Preparation of analcime from local kaolin and rice husk ash. Appl Clay Sci 61:8–13CrossRef
35.
go back to reference Samadi-Maybodi A, Pourali SM (2014) Microwave-assisted hydrothermal green synthesis of analcime icositetrahedra: insight into intermediates formed in the reversed crystal growth process. Eur J Inorg Chem 2014:1204–1210CrossRef Samadi-Maybodi A, Pourali SM (2014) Microwave-assisted hydrothermal green synthesis of analcime icositetrahedra: insight into intermediates formed in the reversed crystal growth process. Eur J Inorg Chem 2014:1204–1210CrossRef
36.
go back to reference Park SH, Kim J-H, Chung C-B, Seo G (2015) Fine control of particle size by seeding and ageing under agitation in the synthesis of analcime zeolite. Korean J Chem Eng 32:2512–2518CrossRef Park SH, Kim J-H, Chung C-B, Seo G (2015) Fine control of particle size by seeding and ageing under agitation in the synthesis of analcime zeolite. Korean J Chem Eng 32:2512–2518CrossRef
37.
go back to reference Yuan J, Yang J, Ma H, Liu C, Zhao C (2016) Hydrothermal synthesis of analcime and hydroxycancrinite from K-feldspar in Na2SiO3 solution: characterization and reaction mechanism. RSC Adv 6:54503–54509CrossRef Yuan J, Yang J, Ma H, Liu C, Zhao C (2016) Hydrothermal synthesis of analcime and hydroxycancrinite from K-feldspar in Na2SiO3 solution: characterization and reaction mechanism. RSC Adv 6:54503–54509CrossRef
38.
go back to reference Zhou W (2010) Reversed crystal growth: implications for crystal engineering. Adv Mater 22:3086–3092CrossRef Zhou W (2010) Reversed crystal growth: implications for crystal engineering. Adv Mater 22:3086–3092CrossRef
39.
go back to reference Padervand M, Vossoughi M, Janfada B (2015) A novel efficient magnetic core–zeolitic shell nanocatalyst system: preparation, characterization and activity. Chem Pap 69:856–863CrossRef Padervand M, Vossoughi M, Janfada B (2015) A novel efficient magnetic core–zeolitic shell nanocatalyst system: preparation, characterization and activity. Chem Pap 69:856–863CrossRef
40.
go back to reference A Corma, M Navarro, JP Pariente (1994) Synthesis of an ultralarge pore titanium silicate isomorphous to MCM-41 and its application as a catalyst for selective oxidation of hydrocarbons. J Chem Soc Chem Commun 2:147–148CrossRef A Corma, M Navarro, JP Pariente (1994) Synthesis of an ultralarge pore titanium silicate isomorphous to MCM-41 and its application as a catalyst for selective oxidation of hydrocarbons. J Chem Soc Chem Commun 2:147–148CrossRef
41.
go back to reference Round CI, Williams CD, Latham K, Duke CVA (2001) Ni-ZSM-5 and Cu-ZSM-5 synthesized directly from aqueous fluoride gels. Chem Mater 13:468–472CrossRef Round CI, Williams CD, Latham K, Duke CVA (2001) Ni-ZSM-5 and Cu-ZSM-5 synthesized directly from aqueous fluoride gels. Chem Mater 13:468–472CrossRef
42.
go back to reference Huo Q, Margolese DI, Stucky GD (1996) Surfactant control of phases in the synthesis of mesoporous silica-based materials. Chem Mater 8:1147–1160CrossRef Huo Q, Margolese DI, Stucky GD (1996) Surfactant control of phases in the synthesis of mesoporous silica-based materials. Chem Mater 8:1147–1160CrossRef
43.
go back to reference Auvray X, Petipas C, Anthore R, Rico I, Lattes A (1989) X-ray diffraction study of mesophases of cetyltrimethylammonium bromide in water, formamide, and glycerol. J Phys Chem 93:7458–7464CrossRef Auvray X, Petipas C, Anthore R, Rico I, Lattes A (1989) X-ray diffraction study of mesophases of cetyltrimethylammonium bromide in water, formamide, and glycerol. J Phys Chem 93:7458–7464CrossRef
44.
go back to reference Chen X, Huang L, Li Q (1997) Hydrothermal transformation and characterization of porous silica templated by surfactants. J Phys Chem B 101:8460–8467CrossRef Chen X, Huang L, Li Q (1997) Hydrothermal transformation and characterization of porous silica templated by surfactants. J Phys Chem B 101:8460–8467CrossRef
45.
go back to reference Huo Q, Leon R, Petroff PM, Stucky GD (1995) Mesostructure design with gemini surfactants: supercage formation in a three-dimensional hexagonal array. Science 268:1324–1327CrossRef Huo Q, Leon R, Petroff PM, Stucky GD (1995) Mesostructure design with gemini surfactants: supercage formation in a three-dimensional hexagonal array. Science 268:1324–1327CrossRef
46.
go back to reference Tolbert SH, Landry CC, Stucky GD, Chmelka BF, Norby P, Hanson JC, Monnier A (2001) Phase transitions in mesostructured silica/surfactant composites: surfactant packing and the role of charge density matching†. Chem Mater 13:2247–2256CrossRef Tolbert SH, Landry CC, Stucky GD, Chmelka BF, Norby P, Hanson JC, Monnier A (2001) Phase transitions in mesostructured silica/surfactant composites: surfactant packing and the role of charge density matching†. Chem Mater 13:2247–2256CrossRef
47.
go back to reference Firouzi A, Kumar D, Bull L, Besier T, Sieger P, Huo Q, Walker S, Zasadzinski J, Glinka C, Nicol J et al (1995) Cooperative organization of inorganic-surfactant and biomimetic assemblies. Science 267:1138–1143CrossRef Firouzi A, Kumar D, Bull L, Besier T, Sieger P, Huo Q, Walker S, Zasadzinski J, Glinka C, Nicol J et al (1995) Cooperative organization of inorganic-surfactant and biomimetic assemblies. Science 267:1138–1143CrossRef
48.
go back to reference Monnier A, Schuth F, Huo Q, Kumar D, Margolese D, Maxwell RS, Stucky GD, Krishnamurty M, Petroff P, Firouzi A, Janicke M, Chmelka BF (1993) Cooperative formation of inorganic-organic interfaces in the synthesis of silicate mesostructures. Science 261:1299–1303CrossRef Monnier A, Schuth F, Huo Q, Kumar D, Margolese D, Maxwell RS, Stucky GD, Krishnamurty M, Petroff P, Firouzi A, Janicke M, Chmelka BF (1993) Cooperative formation of inorganic-organic interfaces in the synthesis of silicate mesostructures. Science 261:1299–1303CrossRef
49.
go back to reference Ghobarkar H, Franke W (1986) The morphology of analcime. Cryst Res Technol 21:1071–1075CrossRef Ghobarkar H, Franke W (1986) The morphology of analcime. Cryst Res Technol 21:1071–1075CrossRef
50.
go back to reference Liu J, Jiang G, Liu Y, Di J, Wang Y, Zhao Z, Sun Q, Xu C, Gao J, Duan A, Liu J, Wei Y, Zhao Y, Jiang L (2014) Hierarchical macro-meso-microporous ZSM-5 zeolite hollow fibers with highly efficient catalytic cracking capability. Sci Rep 4:7276CrossRef Liu J, Jiang G, Liu Y, Di J, Wang Y, Zhao Z, Sun Q, Xu C, Gao J, Duan A, Liu J, Wei Y, Zhao Y, Jiang L (2014) Hierarchical macro-meso-microporous ZSM-5 zeolite hollow fibers with highly efficient catalytic cracking capability. Sci Rep 4:7276CrossRef
51.
go back to reference Boistelle R, Astier JP (1988) Crystallization mechanisms in solution. J Cryst Growth 90:14–30CrossRef Boistelle R, Astier JP (1988) Crystallization mechanisms in solution. J Cryst Growth 90:14–30CrossRef
52.
go back to reference Knops-Gerrits P-P, De Vos DE, Feijen EJP, Jacobs PA (1997) Raman spectroscopy on zeolites. Microporous Mater 8:3–17CrossRef Knops-Gerrits P-P, De Vos DE, Feijen EJP, Jacobs PA (1997) Raman spectroscopy on zeolites. Microporous Mater 8:3–17CrossRef
53.
go back to reference Iyoki K, Itabashi K, Chaikittisilp W, Elangovan SP, Wakihara T, Kohara S, Okubo T (2014) Broadening the applicable scope of seed-directed, organic structure-directing agent-free synthesis of zeolite to zincosilicate components: a case of VET-type zincosilicate zeolites. Chem Mater 26:1957–1966CrossRef Iyoki K, Itabashi K, Chaikittisilp W, Elangovan SP, Wakihara T, Kohara S, Okubo T (2014) Broadening the applicable scope of seed-directed, organic structure-directing agent-free synthesis of zeolite to zincosilicate components: a case of VET-type zincosilicate zeolites. Chem Mater 26:1957–1966CrossRef
54.
go back to reference Best DF, Larson RW, Angell CL (1973) Infrared spectroscopic investigation of zeolites and adsorbed molecules. VII. Hydroxyl groups of erionite. J Phys Chem 77:2183–2185CrossRef Best DF, Larson RW, Angell CL (1973) Infrared spectroscopic investigation of zeolites and adsorbed molecules. VII. Hydroxyl groups of erionite. J Phys Chem 77:2183–2185CrossRef
Metadata
Title
A new soft template-oriented method for the preparation of hollow analcime microspheres with nanosheets-assembled shells
Authors
Pengyu Gong
Baoshan Li
Xianglong Kong
Ning Wang
Jianjun Liu
Shengli Zuo
Publication date
26-04-2017
Publisher
Springer US
Published in
Journal of Materials Science / Issue 16/2017
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1092-8

Other articles of this Issue 16/2017

Journal of Materials Science 16/2017 Go to the issue

Premium Partners